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Table 1—Initial Moles*

Exp. KI Volume Moles Na2 S2 O3 Volume Moles H2 O2 Volume Moles

mol
KI(L) mol
Number ( ) (KI) ( ) Na2 S2 O3 𝐍𝐚𝟐 𝐒𝟐 𝐎𝟑 (mol) H2 O2 𝐇 𝟐 𝐎𝟐
L L L

(L) (L)

1 1 0.004 0.004 0.04 0.01 0.0004 0.2 0.01 0.002

2 1 0.008 0.008 0.04 0.01 0.0004 0.2 0.01 0.002

3 1 0.012 0.012 0.04 0.01 0.0004 0.2 0.01 0.002

4 1 0.012 0.012 0.04 0.01 0.0004 0.2 0.02 0.004

5 1 0.012 0.012 0.04 0.01 0.0004 0.2 0.04 0.008

FORMULA: (Volume of Reactant) (Molarity of Reactant) = Number of Moles


1. Calculate number of moles of KI for experiment 1,
mol
(0.004L KI)(1.0 KI) = 0.004 mol KI
L

2. Calculate number of moles of KI for experiment 2,


mol
(0.008L KI)(1.0 KI) = 0.004 mol KI
L

3. Calculate number of moles of KI for experiment 3-5,


mol
(0.012L KI)(1.0 KI) = 0.012 mol KI
L

4. Calculate number of moles of Na2 S2 O3 for experiment 1-5,


mol
(0.01L KI)(0.04 Na2 S2 O3 ) = 0.0004 mol 𝐍𝐚𝟐 𝐒𝟐 𝐎𝟑
L

5. Calculate number of moles of H2 O2 for experiment 1-3,


mol
(0.01L KI)(0.2 H2 O2 ) = 0.002 mol H2 O2
L

6. Calculate number of moles of 𝐻2 𝑂2 for experiment 4,


mol
(0.02L KI)(0.2 𝐻2 𝑂2) = 0.004 mol 𝐻2 𝑂2
L

7. Calculate number of moles of 𝐻2 𝑂2 for experiment 4,


mol
(0.04L KI)(0.2 𝐻2 𝑂2) = 0.004 mol 𝐻2 𝑂2
L
Table 2–Initial Molarity

Exp. initial [𝐊𝐈]𝟎 Initial [𝐍𝐚𝟐 𝐒𝟐 𝐎𝟑 ]𝟎 Initial [𝐇𝟐 𝐎𝟐 ]𝟎


moles KI 𝐦𝐨𝐥
moles 𝐦𝐨𝐥
moles 𝐦𝐨𝐥
Number ( ) ( ) ( )
𝐋 𝐋 𝐋
Na2 S2 O3 H2 O2

1 0.004 0.02 0.0004 0.002 0.002 0.01

2 0.008 0.04 0.0004 0.002 0.002 0.01

3 0.012 0.06 0.0004 0.002 0.002 0.01

4 0.012 0.06 0.0004 0.002 0.004 0.02

5 0.012 0.06 0.0004 0.002 0.008 0.04

FORMULA: Initial number of Moles/Total Volume of Reactant = Rate Law

Initial number of Moles calculated in Table 1

Total volume of solution (mL) = 200 mL or 0.2L

1. Calculate rate law of KI in experiment 1,

0.04mol
= 0.02𝐦𝐨𝐥⁄𝐋
0.2L

2. Calculate rate law of KI in experiment 2,

0.08mol
= 0.04𝐦𝐨𝐥⁄𝐋
0.2L

3. Calculate rate law of KI in experiment 3-5,

0.012mol
= 0.06𝐦𝐨𝐥⁄𝐋
0.2L
4. Calculate rate law of Na2 S2 O3 in experiment 1-5,

0.0004mol
= 0.002𝐦𝐨𝐥⁄𝐋
0.2L

5. Calculate rate law of H2 O2 in experiment 1-3,

0.02mol
= 0.01𝐦𝐨𝐥⁄𝐋
0.2L

6. Calculate rate law of H2 O2 in experiment 4,

0.004mol
= 0.02𝐦𝐨𝐥⁄𝐋
0.2L

7. Calculate rate law of H2 O2 in experiment 5,

0.008mol
= 0.04𝐦𝐨𝐥⁄𝐋
0.2L

Table 3—Initial Rates

Exp. Moles Volume [𝐇𝟐 𝐎𝟐 ] Time Rate

Number 𝐇 𝟐 𝐎𝟐 H2 O2 Used (s) (M/s)**

Used (L)* 𝐦𝐨𝐥


( )
𝐋

1 0.0002 0.2 0.001 300 𝟑. 𝟑𝟑𝟑𝟑𝒙𝟏𝟎−𝟔

2 0.0002 0.2 0.001 275 𝟑. 𝟔𝟑𝟔𝟑𝒙𝟏𝟎−𝟔

3 0.0002 0.2 0.001 270 𝟑. 𝟕𝟎𝟑𝟕𝒙𝟏𝟎−𝟔

4 0.0002 0.2 0.001 145 𝟔. 𝟖𝟗𝟔𝟔𝒙𝟏𝟎−𝟔

5 0.0002 0.2 0.001 18 𝟓. 𝟓𝟓𝟓𝟔𝒙𝟏𝟎−𝟓

1. Calculate the moles of H2 O2 used from experiment 1- 5,

1 mol H2 O2
moles of H2 O2 used = Initial moles S2 O2−
3 x (2molS 2− )
2 O3

1 mol H2 O2
= 0.0004moles x (2molS 2− )
2 O3

moles of H2 O2 used=0.0002moles
2. Calculate the rate law of H2 O2 used from experiment 1- 5,

FORMULA: moles of H2 O2 used/volume of H2 O2 = rate law of H2 O2

0.0002moles
= = 0.001 of 𝐇𝟐 𝐎𝟐 𝒎𝒐𝒍⁄𝑳
0.2L

3. Calculate rate of experiment 1,

∆[H2 o2 ] 0.001𝑀
FORMULA: Rate= = =3.3333x𝟏𝟎−𝟔 M/s
∆t 300𝑠

4. Calculate rate of experiment 2,

∆[H2 o2 ] 0.001𝑀
Rate= = =3.6363x𝟏𝟎−𝟔 M/s
∆t 275𝑠

5. Calculate rate of experiment 3,

∆[H2 o2 ] 0.001𝑀
Rate= = =3.7037x𝟏𝟎−𝟔 M/s
∆t 270𝑠

6. Calculate rate of experiment 4,

∆[H2 o2 ] 0.001𝑀
Rate= = =6.8966x𝟏𝟎−𝟔 M/s
∆t 145𝑠

7. Calculate rate of experiment 5,

∆[H2 o2 ] 0.001𝑀
Rate= = =5.5556x𝟏𝟎−𝟓 M/s
∆t 18𝑠

Table 4 –Logarithms

Exp. log(rate) [𝐻2 𝑂2 ]0 log [𝑰− ]𝟎 log[𝑰− ]𝟎


[𝑯𝟐 𝑶𝟐 ]𝟎
Number

1 -5.4771 0.01 -2 0.004 -2.3979

2 -5.4393 0.01 -2 0.004 -2.3979

3 -5.4314 0.01 -2 0.004 -2.3979

4 -5.1614 0.02 -1.6989 0.008 -2.0969

5 -4.2563 0.04 -1.3979 0.016 -1.7959


1. Calculate log (rate) of experiment 1,

Log (3.3333x10−6) = -5.4771

2. Calculate log (rate) of experiment 2,

Log (3.6363x10−6) = -5.4393

3. Calculate log (rate) of experiment 3,

Log (3.7037x10−6) = -5.4314

4. Calculate log (rate) of experiment 4,

Log (6.8966x10−6) = -5.1614

5. Calculate log (rate) of experiment 5,

Log (5.5556x10−5) = -4.2563

6. Calculate log [𝐻2 𝑂2 ]0 of experiment 1-3,

Log (0.01) = -2

7. Calculate log [𝐻2 𝑂2 ]0 of experiment 4,

Log (0.02) = -1.6989

8. Calculate log [𝐻2 𝑂2 ]0 of experiment 5,

Log (0.04) = -1.3979

9. Calculate log [𝐼 − ]0 of experiment 1-3,

10. Calculate log [𝐼 − ]0 of experiment 4,

11. Calculate log [𝐼 − ]0 of experiment 5,


Table 5– Rate Constants

Exp. [𝐻2 𝑂2 ]𝑜∗ [𝐻2 𝑂2 ]𝑜𝑚 [𝐼 − ]𝑜∗ [𝐼 − ]𝑜𝑛 initial rate k

(M/s)

1 0.002 1.9669x𝟏𝟎−𝟒 0.004 3.5927x𝟏𝟎−𝟓 3.25x𝟏𝟎−𝟔 459.9177

2 0.002 1.9669x𝟏𝟎−𝟒 0.004 3.5927x𝟏𝟎−𝟓 3.25x𝟏𝟎−𝟔 459.9177

3 0.002 1.9669x𝟏𝟎−𝟒 0.004 3.5927x𝟏𝟎−𝟓 3.25x𝟏𝟎−𝟔 459.9177

4 0.004 7.1062x𝟏𝟎−𝟒 0.008 1.2983x𝟏𝟎−𝟒 1.1753x𝟏𝟎−𝟓 127.3902

5 0.008 2.5673x𝟏𝟎−𝟑 0.016 4.6918x𝟏𝟎−𝟒 4.2457x𝟏𝟎−𝟓 35.2479

Value of m (2 sig fig) = 1.8531 Value of n (2 sig fig) = 1.8535

average value of k =308.47

standard deviation of k =8.5929x𝟏𝟎𝟏𝟎


Table 6– k at Different Temperatures

Reaction T (°C)* T (K)** time rate k ln k 1/T


conditions (s)*
(M/s) (K-1)

hot bath 1 25.7 298.7 24 4.1667x𝟏𝟎−𝟓 420410.969 12.9490 3.3478x1𝟎−𝟑 𝐊 −𝟏

hot bath 2 25.9 298.9 23 4.3478x𝟏𝟎−𝟓 438683.5651 12.9915 3.34561𝟎−𝟑 𝐊 −𝟏

room 25 298 270 𝟑. 𝟕𝟎𝟑𝟕𝐱𝟏𝟎−𝟔 37369.52758 10.5286 3.3557x1𝟎−𝟑 𝐊 −𝟏


temp (part 2
data)

cold bath 25.2 298.2 87 1.1494x𝟏𝟎−𝟓 115971.9605 11.6611 3.3534x1𝟎−𝟑 𝐊 −𝟏


1

cold bath 25 298 106 9.4339x𝟏𝟎−𝟔 95185.99947 11.4643 3.3557x1𝟎−𝟑 𝐊 −𝟏


2

Ea =1.75x𝟏𝟎𝟔 J/mol.K A=

1. Calculate rate of hot bath 1,

ΔH2 O2 0.001M
Rate= = = 𝟒. 𝟏𝟔𝟔𝟕𝐱𝟏𝟎−𝟓 𝐌⁄𝐬
∆t 24s

2. Calculate rate of hot bath 2,

ΔH2 O2 0.001M
Rate= = = 𝟒. 𝟑𝟒𝟕𝟖𝐱𝟏𝟎−𝟓 𝐌⁄𝐬
∆t 23s

3. Calculate rate at room temp,

ΔH2 O2 0.001M
Rate= = = 𝟑. 𝟕𝟎𝟑𝟕𝐱𝟏𝟎−𝟔 𝐌⁄𝐬
∆t 270s

4. Calculate rate of cold bath 1,

ΔH2 O2 0.001M
Rate= ∆t
= 87s
= 𝟏. 𝟏𝟒𝟗𝟒𝐱𝟏𝟎−𝟓 𝐌⁄𝐬
5. Calculate rate of cold bath 2,

ΔH2 O2 0.001M
Rate= = = 𝟗. 𝟒𝟑𝟑𝟗𝐱𝟏𝟎−𝟓 𝐌⁄𝐬
∆t 106s

6. Calculate k of hot bath 1,

initial rate 4.1667x10−5 M/s


k=[H −
= 1.8531 [0.004]1.8535
= 𝟒𝟐𝟎𝟒𝟏𝟎. 𝟗𝟔𝟗
2 O2 ] ͫ [I ] ⁿ [0.001]

7. Calculate k of hot bath 2,

initial rate 4.3478x10−5 M/s


k=[H −
= 1.8531 [0.004]1.8535
= 𝟒𝟑𝟖𝟔𝟖𝟑. 𝟓𝟔𝟓𝟏
2 O2 ] ͫ [I ] ⁿ [0.001]

8. Calculate k at room temp,

initial rate 3.7037x10−6 M⁄s


k=[H −
= = 𝟑𝟕𝟑𝟔𝟗. 𝟓𝟐𝟕𝟓𝟖
]
2 O2 ͫ [I ] ⁿ [0.001]1.8531 [0.004]1.8535

9. Calculate k of cold bath 1,

initial rate 1.1494x10−5 M/s


k=[H −
= 1.8531 [0.004]1.8535
= 𝟏𝟏𝟓𝟗𝟕𝟏. 𝟗𝟔𝟎𝟓
2 O2 ] ͫ [I ] ⁿ [0.001]

10. Calculate k of cold bath 2,

initial rate 9.4339x10−6 M/s


k=[H −
= 1.8531 [0.004]1.8535
= 𝟗𝟓𝟏𝟖𝟓. 𝟗𝟗𝟗𝟒𝟕
2 O2 ] ͫ [I ] ⁿ [0.001]

11. Calculate ln k of hot bath 1,

lnk = ln(420410.969) = 12.9490

12. Calculate ln k of hot bath 2,

lnk = ln(438683.5651) = 12.9915

13. Calculate ln k at room temp,

lnk = ln(37369.52758) = 10.5286

14. Calculate ln k of cold bath 1,

lnk = ln(115971.9605) = 11.6611

15. Calculate ln k of cold bath 2,

lnk = ln(95185.99947) = 11.6611


16. Calculate 1/T of hot bath 1,

1/T = 1/298.7K = 3.3478x1𝟎−𝟑 𝐊 −𝟏

17. Calculate 1/T of hot bath 2,

1/T = 1/298.9K = 3.34561𝟎−𝟑 𝐊 −𝟏

18. Calculate 1/T at room temp,

1/T = 1/298K = 3.3557x1𝟎−𝟑 𝐊 −𝟏

19. Calculate 1/T of cold bath 1,

1/T = 1/298.2K = 3.3534x1𝟎−𝟑 𝐊 −𝟏

20. Calculate 1/T of cold bath 2,

1/T = 1/298.7K = 3.3557x1𝟎−𝟑 𝐊 −𝟏

21. Get slope and y-intercept (regression),

slope = m = 717.6688

y-intercept = b = -210568.5744

22. Calculate value of Ea,

Ea = -mR

= - (-210568.5744) (8.314 J/mol.K)

Ea = 1.75x𝟏𝟎𝟔 J/mol.K

23. Calculate value of A,

A = 𝑒𝑏= 𝑒

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