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3.2. Mixture
Quartz (14808-60-7)
Croatia GVI (granična vrijednost izloženosti) (mg/m³) 0,1 mg/m³
0,1 mg/m³ (regulated under Quartz sand-
respirable dust)
Czech Republic Expoziční limity (PEL) (mg/m³) 0,1 mg/m³ (dust)
Denmark Grænseværdie (langvarig) (mg/m³) 0,3 mg/m³ (total)
0,1 mg/m³ (respirable)
Estonia OEL TWA (mg/m³) 0,1 mg/m³ (respirable dust)
Finland HTP-arvo (8h) (mg/m³) 0,05 mg/m³ (respirable)
France VME (mg/m³) 0,1 mg/m³ (restrictive limit-alveolar fraction)
Hungary AK-érték 0,15 mg/m³ (respirable)
Ireland OEL (8 hours ref) (mg/m³) 0,1 mg/m³ (respirable dust)
Ireland OEL (15 min ref) (mg/m3) 0,3 mg/m³ (calculated-respirable dust)
Lithuania IPRV (mg/m³) 0,1 mg/m³ (Silicon dioxide variation-respirable
fraction)
Netherlands Grenswaarde TGG 8H (mg/m³) 0,075 mg/m³ (respirable dust)
Poland NDS (mg/m³) 2 mg/m³ (>50% free crystalline silica-inhalable
fraction)
0,3 mg/m³ (>50% free crystalline silica-
respirable fraction)
4,0 mg/m³ (2% to 50% free crystalline silica-
inhalable fraction)
1,0 mg/m³ (2% to 50% free crystalline silica-
respirable fraction)
Portugal OEL TWA (mg/m³) 0,025 mg/m³ (respirable fraction)
Romania OEL TWA (mg/m³) 0,1 mg/m³ (respirable fraction, dust)
Slovakia NPHV (priemerná) (mg/m³) 0,1 mg/m³ (in Cristobalite or Tridymite-total
aerosol)
Slovenia OEL TWA (mg/m³) 0,15 mg/m³ (respirable fraction)
Spain VLA-ED (mg/m³) 0,05 mg/m³ (reclassified IARC group 2A to group
1-respirable fraction)
Sweden nivågränsvärde (NVG) (mg/m³) 0,1 mg/m³ (respirable dust)
United Kingdom WEL TWA (mg/m³) 0,1 mg/m³ (respirable)
United Kingdom WEL STEL (mg/m³) 0,3 mg/m³ (calculated-respirable)
Norway Grenseverdier (AN) (mg/m³) 0,3 mg/m³ (Dust containing .alpha.-Quartz,
Cristobalite and/or Tridymite is evaluated by
summation formula-total dust)
0,1 mg/m³ (Dust containing .alpha.-Quartz,
Cristobalite and/or Tridymite is evaluated by
summation formula-respirable dust)
Norway Grenseverdier (Korttidsverdi) (mg/m3) 0,3 mg/m³ (Dust containing .alpha.-Quartz,
Cristobalite and/or Tridymite is evaluated by
summation formula-total dust)
0,1 mg/m³ (Dust containing .alpha.-Quartz,
Cristobalite and/or Tridymite is evaluated by
summation formula-respirable dust)
Switzerland VME (mg/m³) 0,15 mg/m³ (respirable dust)
Australia TWA (mg/m³) 0,1 mg/m³ (respirable dust)
Canada (Quebec) VEMP (mg/m³) 0,1 mg/m³ (respirable dust)
USA - ACGIH ACGIH TWA (mg/m³) 0,025 mg/m³ (respirable fraction)
USA - IDLH US IDLH (mg/m³) 50 mg/m³ (respirable dust)
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SAFETY DATA SHEET
Revision nr : 1.0
Issue date : 07/07/2015
Supersedes :
PSX 60 Part A
Quartz (14808-60-7)
USA - NIOSH NIOSH REL (TWA) (mg/m³) 0,05 mg/m³ (respirable dust)
Methanol (67-56-1)
EU IOELV TWA (mg/m³) 260 mg/m³
EU IOELV TWA (ppm) 200 ppm
Austria MAK (mg/m³) 260 mg/m³
Austria MAK (ppm) 200 ppm
Austria MAK Short time value (mg/m³) 1040 mg/m³
Austria MAK Short time value (ppm) 800 ppm
Belgium Limit value (mg/m³) 266 mg/m³
Belgium Limit value (ppm) 200 ppm
Belgium Short time value (mg/m³) 333 mg/m³
Belgium Short time value (ppm) 250 ppm
Bulgaria OEL TWA (mg/m³) 260,0 mg/m³
Bulgaria OEL TWA (ppm) 200 ppm
Croatia GVI (granična vrijednost izloženosti) (mg/m³) 260 mg/m³
Croatia GVI (granična vrijednost izloženosti) (ppm) 200 ppm
Cyprus OEL TWA (mg/m³) 260 mg/m³
Cyprus OEL TWA (ppm) 200 ppm
Czech Republic Expoziční limity (PEL) (mg/m³) 250 mg/m³
Denmark Grænseværdie (langvarig) (mg/m³) 260 mg/m³
Denmark Grænseværdie (langvarig) (ppm) 200 ppm
Estonia OEL TWA (mg/m³) 260 mg/m³
Estonia OEL TWA (ppm) 200 ppm
Estonia OEL STEL (mg/m³) 350 mg/m³
Estonia OEL STEL (ppm) 250 ppm
Finland HTP-arvo (8h) (mg/m³) 270 mg/m³
Finland HTP-arvo (8h) (ppm) 200 ppm
Finland HTP-arvo (15 min) 330 mg/m³
Finland HTP-arvo (15 min) (ppm) 250 ppm
France VME (mg/m³) 260 mg/m³ (restrictive limit)
France VME (ppm) 200 ppm (restrictive limit)
France VLE (mg/m³) 1300 mg/m³
France VLE (ppm) 1000 ppm
Germany TRGS 900 Occupational exposure limit value 270 mg/m³ (The risk of damage to the embryo or
(mg/m³) fetus can be excluded when AGW and BGW
values are observed)
Germany TRGS 900 Occupational exposure limit value 200 ppm (The risk of damage to the embryo or
(ppm) fetus can be excluded when AGW and BGW
values are observed)
Germany TRGS 903 (BGW) 30 mg/l (Medium: urine - Time: end of shift -
Parameter: Methanol)
30 mg/l (Medium: urine - Time: end of several
shifts - Parameter: Methanol (for long-term
exposures)
Gibraltar OEL TWA (mg/m³) 260 mg/m³
Gibraltar OEL TWA (ppm) 200 ppm
Greece OEL TWA (mg/m³) 260 mg/m³
Greece OEL TWA (ppm) 200 ppm
Page : 7 / 16
SAFETY DATA SHEET
Revision nr : 1.0
Issue date : 07/07/2015
Supersedes :
PSX 60 Part A
Methanol (67-56-1)
Greece OEL STEL (mg/m³) 325 mg/m³
Greece OEL STEL (ppm) 250 ppm
Hungary AK-érték 260 mg/m³
Ireland OEL (8 hours ref) (mg/m³) 260 mg/m³
Ireland OEL (8 hours ref) (ppm) 200 ppm
Ireland OEL (15 min ref) (mg/m3) 780 mg/m³ (calculated)
Ireland OEL (15 min ref) (ppm) 600 ppm (calculated)
Italy OEL TWA (mg/m³) 260 mg/m³
Italy OEL TWA (ppm) 200 ppm
Latvia OEL TWA (mg/m³) 260 mg/m³
Latvia OEL TWA (ppm) 200 ppm
Lithuania IPRV (mg/m³) 260 mg/m³
Lithuania IPRV (ppm) 200 ppm
Luxembourg OEL TWA (mg/m³) 260 mg/m³
Luxembourg OEL TWA (ppm) 200 ppm
Malta OEL TWA (mg/m³) 260 mg/m³
Malta OEL TWA (ppm) 200 ppm
Netherlands Grenswaarde TGG 8H (mg/m³) 133 mg/m³
Netherlands Grenswaarde TGG 8H (ppm) 100 ppm
Poland NDS (mg/m³) 100 mg/m³
Poland NDSCh (mg/m³) 300 mg/m³
Portugal OEL TWA (mg/m³) 260 mg/m³ (indicative limit value)
Portugal OEL TWA (ppm) 200 ppm (indicative limit value)
Portugal OEL STEL (ppm) 250 ppm
Romania OEL TWA (mg/m³) 260 mg/m³
Romania OEL TWA (ppm) 200 ppm
Romania OEL STEL (ppm) 5 ppm
Slovakia NPHV (priemerná) (mg/m³) 260 mg/m³
Slovakia NPHV (priemerná) (ppm) 200 ppm
Slovenia OEL TWA (mg/m³) 260 mg/m³
Slovenia OEL TWA (ppm) 200 ppm
Spain VLA-ED (mg/m³) 266 mg/m³ (indicative limit value)
Spain VLA-ED (ppm) 200 ppm (indicative limit value)
Sweden nivågränsvärde (NVG) (mg/m³) 250 mg/m³
Sweden nivågränsvärde (NVG) (ppm) 200 ppm
Sweden kortidsvärde (KTV) (mg/m³) 350 mg/m³
Sweden kortidsvärde (KTV) (ppm) 250 ppm
United Kingdom WEL TWA (mg/m³) 266 mg/m³
United Kingdom WEL TWA (ppm) 200 ppm
United Kingdom WEL STEL (mg/m³) 333 mg/m³
United Kingdom WEL STEL (ppm) 250 ppm
Norway Grenseverdier (AN) (mg/m³) 130 mg/m³
Norway Grenseverdier (AN) (ppm) 100 ppm
Page : 8 / 16
SAFETY DATA SHEET
Revision nr : 1.0
Issue date : 07/07/2015
Supersedes :
PSX 60 Part A
Methanol (67-56-1)
Norway Grenseverdier (Korttidsverdi) (mg/m3) 130 mg/m³
Norway Grenseverdier (Korttidsverdi) (ppm) 100 ppm
Switzerland VME (mg/m³) 260 mg/m³
Switzerland VME (ppm) 200 ppm
Switzerland VLE (mg/m³) 1040 mg/m³
Switzerland VLE (ppm) 800 ppm
Australia TWA (mg/m³) 262 mg/m³
Australia TWA (ppm) 200 ppm
Australia STEL (mg/m³) 328 mg/m³
Australia STEL (ppm) 250 ppm
Canada (Quebec) VECD (mg/m³) 328 mg/m³
Canada (Quebec) VECD (ppm) 250 ppm
Canada (Quebec) VEMP (mg/m³) 262 mg/m³
Canada (Quebec) VEMP (ppm) 200 ppm
USA - ACGIH ACGIH TWA (ppm) 200 ppm
USA - ACGIH ACGIH STEL (ppm) 250 ppm
USA - IDLH US IDLH (ppm) 6000 ppm
USA - NIOSH NIOSH REL (TWA) (mg/m³) 260 mg/m³
USA - NIOSH NIOSH REL (TWA) (ppm) 200 ppm
USA - NIOSH NIOSH REL (STEL) (mg/m³) 325 mg/m³
USA - NIOSH NIOSH REL (STEL) (ppm) 250 ppm
USA - OSHA OSHA PEL (TWA) (mg/m³) 260 mg/m³
USA - OSHA OSHA PEL (TWA) (ppm) 200 ppm
Colour : Black.
Odour : slight. epoxy-like.
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point/freezing point : No data available
Freezing point : No data available
Initial boiling point and boiling range : No data available
Flash point : > 200 °C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Non flammable
Vapour pressure : < 1 mmHg (20 °C)
Vapour density : ≈ 1 (Air = 1.0)
Relative density : No data available
Solubility : No data available.
Water: Negligible
Partition coefficient n-octanol/water : No data available
Kinematic viscosity : No data available
Dynamic viscosity : 600000 - 400000 cP (@25°C)
Explosive properties : Not applicable.
Oxidising properties : Not applicable.
Explosive limits : No data available
9.2. Other information
No data available
:
Page : 12 / 16
SAFETY DATA SHEET
Revision nr : 1.0
Issue date : 07/07/2015
Supersedes :
PSX 60 Part A
IMDG
Transport hazard class(es) (IMDG) : 9
Danger labels (IMDG) : 9
IATA
Transport hazard class(es) (IATA) : 9
Hazard labels (IATA) : 9
ADN
Transport hazard class(es) (ADN) : 9
Danger labels (ADN) : 9
RID
Transport hazard class(es) (RID) : 9
Danger labels (RID) : 9
- Overland transport
Classification code (ADR) : M6
Special Provisions : 274, 335, 601
Limited quantities (ADR) : 5l
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P001, IBC03, LP01, R001
Special packing provisions (ADR) : PP1
Mixed packing provisions (ADR) : MP19
Portable tank and bulk container : T4
instructions (ADR)
Portable tank and bulk container special : TP1, TP29
provisions (ADR)
Tank code (ADR) : LGBV
Vehicle for tank carriage : AT
Transport category (ADR) : 3
Special provisions for carriage - Packages : V12
(ADR)
Special provisions for carriage - Loading, : CV13
unloading and handling (ADR)
Hazard identification number (Kemler No.) : 90
Orange plates :
- Transport by sea
Special provisions (IMDG) : 274, 335
Limited quantities (IMDG) : 5L
Excepted quantities (IMDG) : E1
Packing instructions (IMDG) : P001, LP01
Special packing provisions (IMDG) : PP1
IBC packing instructions (IMDG) : IBC03
Tank instructions (IMDG) : T4
Tank special provisions (IMDG) : TP2, TP29
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-F
Stowage category (IMDG) : A
- Air transport
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y964
PCA limited quantity max net quantity : 30kgG
(IATA)
PCA packing instructions (IATA) : 964
PCA max net quantity (IATA) : 450L
CAO packing instructions (IATA) : 964
Page : 14 / 16
SAFETY DATA SHEET
Revision nr : 1.0
Issue date : 07/07/2015
Supersedes :
PSX 60 Part A
- Rail transport
Classification code (RID) : M6
Special provisions (RID) : 274, 335, 601
Limited quantities (RID) : 5L
Excepted quantities (RID) : E1
Packing instructions (RID) : P001, IBC03, LP01, R001
Special packing provisions (RID) : PP1
Mixed packing provisions (RID) : MP19
Portable tank and bulk container : T4
instructions (RID)
Portable tank and bulk container special : TP1, TP29
provisions (RID)
Tank codes for RID tanks (RID) : LGBV
Transport category (RID) : 3
Special provisions for carriage – Packages : W12
(RID)
Special provisions for carriage - Loading, : CW13, CW31
unloading and handling (RID)
Colis express (express parcels) (RID) : CE8
Hazard identification number (RID) : 90
Carriage prohibited (RID) : No
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Code: IBC : No data available.
3.b. Substances or mixtures fulfilling the criteria for any of the following hazard classes or PSX 60 Part A - Phenol, polymer with
categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, formaldehyde, glycidyl ether - Quartz - dibutyltin
3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than di(acetate) - Siloxane, dimethyl, methoxyphenyl
narcotic effects, 3.9 and 3.10 with phenyl silsesquioxane methoxy-terminated
- Methanol
3.c. Substances or mixtures fulfilling the criteria for any of the following hazard classes or PSX 60 Part A - Phenol, polymer with
categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard class 4.1 formaldehyde, glycidyl ether - dibutyltin
di(acetate)
40. Substances classified as flammable gases category 1 or 2, flammable liquids categories Methanol
1, 2 or 3, flammable solids category 1 or 2, substances and mixtures which, in contact with
water, emit flammable gases, category 1, 2 or 3, pyrophoric liquids category 1 or pyrophoric
solids category 1, regardless of whether they appear in Part 3 of Annex VI to Regulation
(EC) No 1272/2008 or not.
Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances
Germany
VwVwS Annex reference : Water hazard class (WGK) 3, severe hazard to waters (Classification according to
VwVwS, Annex 4)
12th Ordinance Implementing the Federal : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Immission Control Act - 12.BImSchV
Netherlands
SZW-lijst van kankerverwekkende stoffen : Quartz is listed
SZW-lijst van mutagene stoffen : None of the components are listed
NIET-limitatieve lijst van voor de : None of the components are listed
voortplanting giftige stoffen – Borstvoeding
NIET-limitatieve lijst van voor de : None of the components are listed
voortplanting giftige stoffen –
Vruchtbaarheid
NIET-limitatieve lijst van voor de : Methanol is listed
voortplanting giftige stoffen – Ontwikkeling
Denmark
Classification remarks : Emergency management guidelines for the storage of flammable liquids must be
followed
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
Chemical safety assessments for substances in this mixture were not carried out.
Sources of key data used to compile the : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF
datasheet THE COUNCIL of 16 December 2008 on classification, labelling and packaging of
substances and mixtures, amending and repealing Directives 67/548/EEC and
1999/45/EC, and amending Regulation (EC) No 1907/2006.
Other information : None.
Page : 16 / 16
SAFETY DATA SHEET
Revision nr : 1.0
Issue date : 07/07/2015
Supersedes :
PSX 60 Part A
The contents and format of this SDS are in accordance with EEC Commission Directive 1999/45/EC, 67/548/EC, 1272/2008/EC
and EEC Commission Regulation 1907/2006/EC (REACH) Annex II.
DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the
information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling,
storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we
do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected
with the handling, storage, use or disposal of the product. This SDS was prepared and is to be used only for this product. If the
product is used as a component in another product, this SDS information may not be applicable.