Professional Documents
Culture Documents
BME111
Design
of
Biomaterials
Spring
2015
April
14
Lecture
5
Slide
1
Last Time
20 mers 16 mers
10 mers
Ni
• Number average molecular weight: M n = ∑ xi M i xi =
i
∑ Ni i
BME111
Design
of
Biomaterials
Spring
2015
April
14
Lecture
5
Slide
3
Step growth polymerization
Reaction between functional groups (between monomers, or between
monomer and growing chain, or between two growing chains)
BME111
Design
of
Biomaterials
Spring
2015
April
14
Lecture
5
Slide
4
Step growth (cont’d)
• Formation of polymer requires more than 1 functional group on each
monomer
BME111
Design
of
Biomaterials
Spring
2015
April
14
Lecture
5
Slide
5
Copolymers
• Homopolymer – one type of monomer or repeating unit
• Copolymer – more than one type of species
BME111
Design
of
Biomaterials
Spring
2015
April
14
Lecture
5
Slide
6
Polymer microstructure
secondary
bonding
BME111
Design
of
Biomaterials
Spring
2015
April
14
Lecture
5
Slide
7
Crystallinity
• Ordered atomic arrangements
involving molecular chains
• Crystal structures in terms of
unit cells
• Example shown
– polyethylene unit cell
BME111
Design
of
Biomaterials
Spring
2015
April
14
Lecture
5
Slide
8
Lamellar regions of crystallinity
• Crystalline regions
– thin platelets or lamella with chain folds at faces
– Chain folded structure
10 nm
BME111
Design
of
Biomaterials
Spring
2015
April
14
Lecture
5
Slide
9
Semi-crystalline polymeric materials
crystalline
Polymers rarely 100% crystalline region
• Difficult for all regions of all chains to
become aligned
• Rate of cooling and polymer structure
determine crystallinity
amorphous
region
Adapted from Fig. 14.11, Callister 6e.
BME111
Design
of
Biomaterials
Spring
2015
April
14
Lecture
5
Slide
10
Percent crystallinity
Degree of crystallinity expressed as % crystallinity and can be
described in terms of the density of the material.
BME111
Design
of
Biomaterials
Spring
2015
April
14
Lecture
5
Slide
11
Spherulites
• Some semicrystalline
polymers form spherulite
structures
• Nucleation and growth
process
• Alternating chain-folded
crystallites and amorphous
regions
• Spherulite structure for
relatively rapid growth rates
BME111 Design of Biomaterials Spring 2015 April 14 Lecture 5 Slide 12