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A. Objection
1. Student can prepare acid standard solution
2. Student can determine the normality of the acid / base using a standard
solution
3. Student can determine the equivalence point using titration curve
B. Theoretical Background
An aqueous solution is acidic, neutral, or basic depends on the
hydronium-ion concentration. You can quantitatively describe the acidity
by giving the hydronium-ion concentration. But because these
concentration values may be very small, it is often more convenient to
give the acidity in terms of pH, which is defined as the negative of the
logarithm of the molar hydronium-ion concentration[ CITATION Ebb09 \l
1057 ].
A convenient way to measure the approximate pH of a solution is by
using
1. indicator paper
a strip of paper coated with a combination of indicators. Indicator
paper turns a specific color for each pH value.
2. pH meter
A pH meter contains a probe that is very sensitive to the [ H +] in a
solution. When the probe is inserted into a solution, the [H +] in the
solution produces a voltage that appears as a pH reading on the
meter. Because a pH meter can determine the pH value of a
solution so quickly and accurately, these devices are now used
almost universally.
D. Procedure
1. Preparation of primary standart solution of H2C2O4(COOH)2.
2H2O
(V.N)NaOH = (VN)HCl
E. Observation
a. Mass of oxalic acid = 1.2607 gr
Volume of solution = 100.00 mL
Molarity of oxalic acid = 0.1M
Normality of oxalic acid = 0.2N
1. 0 1 1. 0 4
2. 1 1 2. 1 4
3. 2 2 3. 2 4
4. 3 2 4. 3 4
5. 4 2 5. 4 5
6. 5 3 6. 5 5
7. 6 4 7. 6 5
8. 7 6 8. 7 6
9. 8 10 9. 8 6
10. 9 10 10. 9 7
11. 10 10 11. 10 10
12. 11 10 12. 11 10
13. 12 10 13. 12 10
14. 13 10 14. 13 10
F. Calculation
= 0.1 M
= 0.1 . 2 = 0.2 N
2
MNaOH =
18. 1 0 ml
MNaOH = 0.11 M
c. Volume of HCl = 10 mL
0, 11 M. 9.25 ml = MHCl . 10 ml
MHCl = 0.10175 M
Reaction :
m 0.11 1 - -
HCl H+ + Cl-
0.89 mmol 0.89 mmol 0.89 mmol
0,89mmol
[ H+] =
10
= 0.081 M
pH = - log [ H+]
= 3 - log 81
= 3 – 1.91
= 1.09
Reaction :
V total = 12 ml
m 0.22 1 - -
HCl H+ + Cl-
0.78 mmol
[ H+] =
12
= 0.065 M
pH = - log [ H+]
= 2 - log 6.5
= 2 –0.81
= 1.19
V total = 13 ml
m 0.33 1 - -
HCl H+ + Cl-
0.69mmol
[ H+] =
13
= 0.053 M
pH = - log [ H+]
= 2 – 0.72
= 1.28
V total = 14 ml
m 0.44 1 - -
HCl H+ + Cl-
0.56 mmol
[ H+] =
14
= 0.04 M
pH = - log [ H+]
= - log 4. 10-2
= 2 - log 4
=2 – 0.6
= 1.4
V total = 15 ml
m 0.55 1.00 - -
HCl H+ + Cl-
0.45mmol
[ H+] =
15
= 0.03 M
pH = - log [ H+
= - log (0.03)
= 1.52
V total = 16 ml
NaOH + HCl NaCl + H2O
m 0.66 1.00 - -
HCl H+ + Cl-
0.34 mmol
[ H+] =
16
= 0.021 M
pH = - log [ H+]
= - log (0.021)
= 1.7
V total = 17 ml
m 0.77 1.00 - -
HCl H+ + Cl-
= 0.014 M
pH = - log [ H+]
= - log (0.014)
= 1.85
V total = 18 ml
m 0.88 1.00 - -
HCl H+ + Cl-
0.12mmol
[ H+] =
18
= 0.007 M
pH = - log [ H+]
= - log (0.007)
= 2.15
V total = 19 ml
m 1.1 1.00 - -
HCl H+ + Cl-
0.01mmol
[ H+] =
19
= 0.0005 M
pH = - log [ H+]
= - log (0.0005)
= 3.3
10. Titration between 10 ml HCl 0,1 M with 10 ml NaOH 0.11 M
V total = 20 ml
M 1.10 1.00 - -
0.10 mmol
[ OH-] =
20
= 0.005 M
= - log (0.005)
= 2.3
pH = 14 – 2.3
= 11.7
11. Titration between 10 ml HCl 0,1 M with 11 ml NaOH 0,11 M
V total = 21 ml
M 1.21 1.00 - -
0.21mmol
[ OH-] =
21
= 0.01 M
= - log (0.01)
=2
pH = 14 – 2
= 12
V total = 22 ml
0.32mmol
[ OH-] =
22
= 0.014 M
= - log (0.014)
= 1.85
pH = 14 – pOH
= 14 – 1.85
= 12.15
V total = 23 ml
m 1.43 1.00 - -
r 1.00 1.00 1.00 1.00
0.43mmol
[ OH-] =
23
= 0.019 M
= - log (0.019)
= 1.72
pH = 14 – pOH
= 14 – 1.72 = 12.28
V total = 24 ml
m 1.54 1.00 - -
= 0.0225 M
= - log (0.0225)
= 1.65
pH = 14 – pOH
= 14 – 1.65
= 12.35
V total = 25 ml
m 1.65 1.00 - -
0.65mmol
[ OH-] =
25
= 0.026 M
= - log (0.026)
= 1.58
pH = 14 – pOH
= 14 – 1.58
= 12.42
Based on calculation
The relationship between adding of NaOH to pH
12
10
8
pH
6
4
2
0
0 2 4 6 8 10 12 14 16
Based on practicum
1. Adding 1 ml of NaOH
+¿¿ na +¿¿
H = .Ka pH = - log H
¿ ng ¿
0.89
= . 1.8 .10-5 = -log14.58 .10-5
0.11
= 3.83
2. Adding 2 ml of NaOH
+¿¿ na +¿¿
H = .Ka pH = - log H
¿ ng ¿
0.78
= . 1.8.10-5 = -log 6.38.10-5
0.22
= 4.2
3. Adding 3 ml of NaOH
0.67
= . 1.8 .10-5 = -log 3.65.10-5
0.33
= 4.44
4. Adding 4 ml of NaOH
+¿¿ na +¿¿
H = .Ka pH = - log H
¿ ng ¿
0.54
= . 1.8 .10-5 = -log 2.21.10-5
0.44
= 4.66
5. Adding 5 ml of NaOH
+¿¿ na +¿¿
H = .Ka pH = - log H
¿ ng ¿
0.45
= . 1.8.10-5 = -log 1.47 .10-5
0.55
= 4.8
6. Adding 6 ml of NaOH
0.340
= . 1.8.10-5 = -log 0.93.10-5
0.660
= 5.0
7. Adding 7 ml of NaOH
+¿¿ na +¿¿
H = .Ka pH = - log H
¿ ng ¿
0.23
= . 1,8.10-5 = -log 0.54.10-5
0.77
= 5.23
8. Adding 8 ml of NaOH
+¿¿ na +¿¿
H = .Ka pH = - log H
¿ ng ¿
0.12
= . 1.8 .10-5 = -log 0.25.10-5
0.88
= 5.6
9. Adding 9 ml of NaOH
+¿¿ na +¿¿
H = .Ka pH = - log H
¿ ng ¿
0.10
= . 1.8 .10-5 = -log 0.182.10-5
0.99
= 5.7
n −¿
[ NaOH ] = OH ¿ = a.
V . tot ¿
[ NaOH ]
0.010
= = 1. 0.005 M
20
n −¿
[ NaOH ] = OH ¿ = a.
V . tot ¿
[ NaOH ]
0.21
= = 1. 0.01 M
21
−¿ ¿
pOH = - log OH pH = 14 - pOH
¿
= - log 10-2 = 14 – 2
= 3-log 4 = 2.39 = 12
n −¿
[ NaOH ] = OH ¿ = a. [ NaOH ]
V . tot ¿
0.32
= = 1. 0.014 M
22
−¿ ¿
pOH = - log OH pH = 14 - pOH
¿
= 3-log 14 = 12.15
= 1.85
n −¿
[ NaOH ] = OH ¿ = a.
V . tot ¿
[ NaOH ]
0.43
= = 1. 0.019 M
23
= 0.019 M = 0.019 M
=19.10-3 M
−¿ ¿
pOH = - log OH pH = 14 - pOH
¿
= 3-log 19 = 12.28
= 1.72
0.54
= = 1. 0.0225 M
24
= 0.0225 M = 0.0225 M
= 22.5 .10-3 M
−¿ ¿
pOH = - log OH pH = 14 - pOH
¿
= 1.65
n −¿
[ NaOH ] = OH ¿ = a. [ NaOH ]
V . tot ¿
0.65
= = 1. 0.026M
25
= 0.026 M = 0.026 M
= 26 .10-3 M
−¿ ¿
pOH = - log OH pH = 14 - pOH
¿
= 3-log 26 = 12.42
= 1.58
Based on calculation
12
10
6
pH
4
0
0 2 4 6 8 10 12 14 16
Based on practicum
G. Discussion
First, we dissolve oxalic acid crystal with distilled water in a
100 mL volumetric flask. We use oxalic acid as primary standard
solution that have concentration 0,1 M and normality 0,2 N. This
concentration is used to determine the concentration of NaOH.
Same with the previous experiment, we stop the titration not when it
was pink, but when the color become purple. And it’s affected by the
condition of buret that not good.
At the last experiment, we do titration for NaOH-HCl and
NaOH-CH3COOH. We add 1 mL of NaOH, then drop the solution into
pallete and observation the pH of it continuously until 15 mL. The pH
from last addition of NaOH is higher than the pH at the first addition.
It’s causes by the acid solution is neutralized with the base solution.
NaOH is strong base, HCl is strong acid, and CH 3COOH is weak acid,
it’s make difference between the NaOH-HCl titration with the NaOH-
CH3COOH titration. Theoretically, the equivalent point of strong base-
strong acid is 7, but the equivalent point of strong base-weak acid is
more than 7. In this experiment, we hard to get the real pH with the
universal indicator. Because there are some color that not match with
the color on universal indicator.
H. Summary
Based on this experiment, we can conclude that :
1. With titration, the acid standard solution can used to determine the
concentration of base solution.
2. The molarity of NaOH usedis 0.11 M with normality 0.11 M. The
molarity of HCl usedis 0,10175 M and its normality is 0,10175 N
3. The pH of equivalent point of titration between strong acid and strong
base is 7, while for a weak acid and strong base is more than 7.
Suggestion
1. Practicioner should be understand the experiment
2. Practicioner have to manage time as well as possible
3. Practicioner should to measure pH carefully
I. Reference
Ebbing, D.D., Gammon, S.D.. 2009. General Chemistry 9th Edition.
Boston: Houghton Mifflin Company.
DeCoste, D.J., Zumdahl, S.L., Zumdahl, S.S.. 2007. World of Chemistry.
Boston: Houghton Mifflin Company.
Anonymous. “Acid-base Titration”. April 14th 2016.http://en.wikipedia
.org/wiki/Acid-base_titration
J. Question
1. Determine the Molarity of Oxalic Acid as primary standard
solution!
2. Determine the Molarity of NaOH solution!
3. Determine the Molarity of HCl solution!
4. Based on the data d above, draw a titration curve on graph paper by
plotting pH and volume of NaOH added.
5. From HCl-NaOH titration curve, what is the pH of the mixture
empirical / graphics equivalent?
6. From the titration curve of acetic acid-NaOH, determine Ka of
acetic acid Ka ?
7. What is the approximate pH of the mixture equivalence CH3COOH
– NaOH graphically / empirical ?
8. What is pH from CH3COOH-NaOH mixture equivalent
theoretically, if Ka CH3COOH = 1,8 x 10-5 .
Answer
1. m = 1.2607 gram
Mr = 126.07
V = 100 mL
Val =2
m 1000
M= x
Mr V
1.2607 1000
¿ x
126.07 100
¿ 0.01 x 10
M = 0.1 M
N = M x Val
= 0.1 x 2
= 0.2 N
2. Molarity of NaOH
2
MNaOH =
18. 1 0 ml
MNaOH = 0.11 M
3. Molarity of HCl
0, 11 M. 9.25 ml = MHCl . 10 ml
MHCl = 0.10175 M
4. HCl-NaOH
Based on calculation
Based on practicum
CH3COOH-NaOH
Based on calculation
12
10
6
pH
4
0
0 2 4 6 8 10 12 14 16
Based on practicum
5. pH = 7
6. pH =4
pH = 14 – pOH
pOH = 10
pOH = - log [OH-]
10 = - log [OH-]
[OH-] = 10-10
[OH-] =
√Kw
Ka
x[M ]
10-10 =
√10−14
Ka
10−15
x 0,1
10-20 =
Ka
Ka = 10-5
7. pH =9
8. [OH-] =
√Kw
Ka
x[M ]
√
−14
10
[OH-] = −5
x 0,1
1,8 x 10
= 7,45 x 10-6
pOH = - log [OH-]
= - log 7,45 x 10-6
= 5,127
pH = 14 – 5,127
= 8,87
K. Appendix