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Aim :
To study the determination of the lattice energy of an ionic compound using a Born-Haber
cycle.
Learning Outcomes :
2. draw and use a Born-Haber cycle to determine the lattice energy of an ionic
compound.
3. list the factors that affect the lattice energy of an ionic compound.
5. relate the solubility of an ionic compound with its standard enthalpy change of
solution.
Underlying Principles
Questions in the student notes are designed to enable all students to complete the activity.
The pop-up answers are provided for the students to view when they have considered their
responses. Worksheet questions include questions that require recall, understanding and
application of the new concepts learned.
Development of Lesson :
1. Lattice energy.
1.1 a. Lattice energy is the heat released when 1 mole of a solid ionic compound is
formed from its gaseous ions.
3.1 a. Hydration energy is the energy liberated when 1 mol of gaseous ions become
hydrated at infinite dilution.
c.
Hsolution
NaCl(s) Na+(aq) + Cl-(aq)
Na+(g) + Cl-(g)
c. The size of the Cl- ions is bigger than that of the F- ion. The lattice energy of
CaCl2 is less than that of CaF2. The enthalpy change of hydration of CaCl2 is
also less than that of CaF2. For both CaCl2 and CaF2, the enthalpy change of
hydration is greater than the lattice energy but the difference is bigger for
CaCl2. Hence, CaCl2 is more soluble.
b. Born-Haber cycle
Mg2+(g) + O2-(g)
IE EA2
Mg+(g) + O-(g)
IE EA1
Mg(g) + O(g)
Hlattice
Energy
Hatom Hatom
1
Mg(s) + O2(g)
2
Hf
MgO(s)