Professional Documents
Culture Documents
Aggressive Environment
Synopsis
3. Mechanical properties 6
3.1 Compressive strength 6
3.2 Splitting tensile strength 8
3.3 Modulus of elasticity 9
6. Chloride testing 16
6.1 NT BUILD 492 16
6.2 NT BUILD 443 19
6.3 General discussion of chloride diffusion coefficient measurements 22
7. Conclusions 23
8. References 24
Appendices:
Appendix A Concrete mix designs and fresh concrete properties
Appendix B Compressive strength
Appendix C Splitting tensile strength
Appendix D Modulus of elasticity
Appendix E Freeze/thaw testing according to SS137244 and analysis of thin sections
Appendix F Chloride testing according to NT BUILD 492
Appendix G Chloride testing according to NT BUILD 443
Appendix H Adiabatic heat development
Appendix I Chloride profiles according to NT BUILD 443
Appendix J Data for materials used
1
Introduction
Concrete possesses a wide range of exceptional pro- On this background, an experimental programme was
perties, making it a unique building material. The most conducted to determine the strength and durability
obvious advantages of concrete are its formability and properties of white concrete. The mix designs included
excellent strength. An extra dimension is added when in the investigation were chosen to match state-of-the-
it is also possible to decide the colour. White cement art grey concretes. For comparison purposes, reference
can contribute to freedom of choice with respect to concretes with powder compositions similar to those
concrete colour. used to build the Great Belt Bridge and Tunnel and the
Oresund Link in Denmark were used. White silica fume
Presently, white concrete has many applications, e.g. in powder and light-coloured blast furnace slag were used
facade elements and surface coverings, but white or co- as pozzolans in the white concretes. As dirt repelling
loured concrete is only used to a very limited extent for properties can also be a problem with white concretes,
constructions that are cast in-situ in aggressive environ- mix designs containing hydrophobic admixtures were
ments. There is, however, increasing interest in using also investigated.
white or coloured concrete in such environments. The
purpose of this report is to document the properties of
white concrete in order to allow its use in aggressive
environments.
3
2
Concrete mix designs and fresh concrete properties
Concretes were prepared in two series with water/ • one concrete based on 100% Aalborg White (AW)
powder ratios of 0.36 and 0.45 respectively. Reference with no other powder;
concretes were prepared with powder compositions • one concrete based on 95% AW and 5% silica
corresponding to those used to build the Great Belt fume;
Bridge and Tunnel (Ref. A) and the Oresund Link (Ref. • one concrete based on 100% AW with 2 kg zinc
B), see Table 2. The durability and other properties stearate per m3 concrete;
of white concretes in aggressive environments were • one concrete based on 95% AW and 5% silica fume
compared with those of the reference concretes, which with 2 kg zinc stearate per m3 concrete;
were assumed to be well-known, well-testet, highly • one concrete based on 70% AW and 30% blast
durable concretes. furnace slag.
The paste composition of the concretes are shown in An additional reference concrete (Ref. C) was included
Table 1. For all concretes, the weight-percentage com- in series 2. Apart from having a higher water/powder
position of aggregates was 38% pit sand 0/2 class E, ratio, Ref. C was identical to Ref. A in series 1. The
13% crushed granite 2/8 class E, and 49% crushed gra- designations and powder combinations of all concretes
nite 8/16 class A; aggregate classes according to Danish included in the investigation are shown in Table 2.
Standard. The concretes had constant ratios between
paste volume, aggregate skeleton and water content. The concretes had a slump of 150±30 mm and an air
Workability was adjusted by the addition of plasticiser content of 5.9-7.0%. It should be noted that there was
and super-plasticiser to achieve a target slump of 150 no great effect of powder composition on slump or
mm. The target air content was 6%. air content. However, it was necessary to double or
triple the quantity of air-entraining agent used in the
Besides the reference concretes, each series contained mix designs containing zinc stearate (i.e. hydrophobic
concretes with the following powder combinations: agent). *
Super-plasticiser 0.5-0.8 -
(% of powder weight)
White Blast
30 30
furnace slag (%)
Zinc stearate(kg/m3) 2 2 2 2
* Zinc stearate is just one type of hydrophobic agent among a large selection on the market.
4
Concrete mix designs and fresh concrete properties
2.1 Components
Table 3 lists the components used to formulate the
concretes investigated. Further documentation of sev-
eral of the materials can be found in Appendix J.
Sand, pit sand Nørre Halne 0-2 mm See Appendix J for further details.
Stone, crused granite Espevig 2-8 mm See Appendix J for further details.
Espevig 8-16 mm See Appendix J for further details.
Air-entraining agent Conplast 316 AEA 1:1 Air-entraining agent based on Vinsol and tenside.
Supplied by Fosroc®.
5
3
Mechanical properties
The development of compressive strength, tensile strength A), based on low-alkaline, sulphate-resistant cement.
and modulus of elasticity is shown in Appendices B-D where Furthermore, the figure shows that white concretes (Mix
each value is the average of measurements made on three 1, Mix 2, Mix 3 and Mix 4) possessed strengths after 2
concrete cylinders. Results for compressive strength are shown days that were higher than the strength achieved by the
both as actual values and values adjusted to an air content of reference concrete after 7 days. Concretes containing
6% (it was assumed that a 1% difference in air content results zinc stearate (Mix 3 and Mix 4) had marginally lower
in a 4% difference in compressive strength). compressive strengths than corresponding concretes
without zinc stearate (Mix 1 and Mix 2). Addition of
Compressive strength was measured for all concretes blast furnace slag (Mix 5) reduced initial compressive
at 1, 2, 7, 14, 28 and 90 days’ maturity. Splitting tensile strength in relation to the other AW-based concretes,
strength and modulus of elasticity were measured on but initial compressive strength was still higher than
Ref. A, Mix 1, Mix 2 and Mix 3 at 1, 2, 7, 14 and 28 the reference. Generally, strength develops more
days’ maturity. slowly in concretes incorporating blast furnace slag
than in concretes based solely on Portland cement (5).
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6
Mechanical properties
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7
Mechanical properties
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8
Mechanical properties
Modulus of elasticity
Modulus of elasticity was determined in �
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accordance with Danish Standard DS 423.25. ������� ����
Measurements are performed by mounting
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concrete cylinders in a compressometer ca- D�
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pable of recording deformation. The cylinders
are then deformed by loading, and curves �
relating load values to the corresponding ��������
relative deformation, or strain as it is also ��������
known (∆l/l), are generated. The modulus of
elasticity is then determined as the tangent to � �
the initial slope of the generated curve.
9
4
Adiabatic heat development
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Adiabatic heat development
11
Adiabatic heat development
Similar final heat levels were found for Mix 6, Mix 7, Mix ��
8, Mix 9, Ref. B and Ref. C. The final heat level for Mix
10 was lower than for the other concretes. �
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12
5
Freeze/thaw testing and air void analysis
13
Freeze/thaw testing and air void analysis
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ratio of 0.36 in freeze/thaw resistance
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tests.
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14
Freeze/thaw testing and air void analysis
Table 7: Thin section analysis results for concretes with a water/powder ratio of 0.36.
Parameter Ref. A Mix 1 Mix 2 Mix 3 Mix 4 Mix 5
Specific surface mm-1 23.7 25.7 15.4 32.1 29.0 19.3
Spacing factor mm 0.19 0.17 0.27 0.14 0.16 0.24
Paste air content % 17.0 18.3 20.5 16.9 17.5 15.7
Air content % 5.7 6.1 6.8 5.5 5.7 5.1
Table 8: Thin section analysis results for concretes with a water/powder ratio of 0.45.
Parameter Ref. B Ref. C Mix 6 Mix 7 Mix 8 Mix 9 Mix 10
Specific surface mm-1 30.3 29.4 33.3 33.8 34.0 39.8 32.4
Spacing factor mm 0.13 0.13 0.13 0.13 0.15 0.11 0.14
Paste air content % 21.4 23.0 17.6 17.9 13.7 19.8 17.9
Air content % 7.0 7.8 5.6 5.7 4.2 5.8 5.7
15
6
Chloride testing
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Table 9: Limits used for evaluating the degree of chloride penetration resistance
of concrete on the basis of results obtained from tests using the CTH method.
Diffusion coefficient Resistance to chloride penetration
< 2 x 10-12 m2/s Very good
2 - 8 x 10-12 m2/s Good
8 - 16 x 10-12 m2/s Acceptable
> 16 x 10 -12
m /s
2
Unacceptable
16
Chloride testing
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17
Chloride testing
The diffusion coefficients of AW-based concretes with Substituting 30% of the cement with blast furnace slag
5% silica fume (Mix 6 and Mix 8) were lower than that (Mix 10) slightly reduced the diffusion coefficient in
of Ref. B, supporting the theory that acceptable resi- relation to pure AW (Mix 7).
stance to chloride penetration can be achieved by the
addition of silica fume to AW-based concretes. In con- In relation to the limits described in Table 9, white con-
cretes without silica fume (Mix 7 and Mix 9) diffusion cretes with silica fume showed good resistance to ch-
coefficients were higher than that of Ref. B. loride penetration at 28 days’ maturity. The resistance
to chloride penetration for all other concretes, with the
The addition of zinc stearate (Mix 8 and Mix 9) appa- exception of Mix 9, could be characterised as accepta-
rently resulted in slightly higher diffusion coefficients ble. As found for concretes with a water/powder ratio
than in the corresponding concretes without zinc stea- of 0.36, resistance was improved at increased maturity.
rate (Mix 6 and Mix 7). It should be noted that the ef- For Mix 6 and Mix 10, diffusion coefficients were sig-
fect of zinc stearate was the opposite in concretes with nificantly reduced at increased maturity, while the dif-
a water/powder ratio of 0.36. fusion coefficient of Mix 7 was only marginally lower at
day 56 than at day 28.
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Chloride testing
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19
Chloride testing
The diffusion coefficients for concretes containing The diffusion coefficient of the concrete in which 30%
silica fume (Mix 1 and Mix 3) were comparable with of the AW cement was replaced by blast furnace slag
that of Ref. A. The diffusion coefficients of white (Mix 5) was lower than that of the pure AW concrete
concretes containing no silica fume (Mix 2 and Mix 4) (Mix 2) but higher than that of Ref. A. As previously
were considerably higher than that of Ref. A, and thus mentioned, blast furnace slag increases the binding of
also than those of white concretes containing silica chloride ions in the binder phase.
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Chloride testing
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� coefficients of concretes with a
water/powder ratio of 0.45 as
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measured using NT Build 443.
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Chloride testing
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7
Conclusions
1. The ultimate strength of white concretes was similar The overall conclusion of the examination is:
to that of the reference concretes at both investi-
gated water/powder ratios. Concrete based on AALBORG WHITE® cement and
silica fume has at least as good properties in respect
2. The initial strength of white concretes was higher to strength and durability as concrete normally used in
than that of the reference concretes. constructions placed in an aggressive environment.
23
8
References
24
Appendix A: Concrete mix designs and fresh concrete properties
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Appendix F: Chloride testing according to NT Build 492 (CTH method)
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Appendix H: Adiabatic heat development
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Appendix I: Chloride profiles according to NT BUILD 443 - 28/35
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Bottom 3.6
Total 404.2
Initial weight 404.0
Deviation % 0.0
Appendix J: Data for materials used - Stone 2-8 mm
Bottom 3.6
Total 454.2
Initial weight 454.1
Deviation % 0.0
Appendix J: Data for materials used - Stone 8-16 mm
Bottom 27.2
Total 590.9
Initial weight 590.4
Deviation % 0.0
Appendix J: Data for materials used - White silica fume
Producer: Elkem
Si02 min. 98 %
C max. 0.4 %
Fe203 max. 0.05 %
AI203 max. 0.3 %
Ca0 max. 0.3 %
Mg0 max. 0.1 %
K20 max. 0.25 %
Na20 max. 0.05 %
P205 max. 0.1 %
S03 max. 0.2 %
CI max. 0.01 %
H20 max. 0.3 %
Si02 % 48.75
AI203 % 25.85
Fe203 % 7.41
Ca0 % 4.46
Fri CaO % 0.15
S03 % 0.81
CI- % 0.070
Na20 eqv. % 2.59
Activity index:
28 days % 89.7
90 days % 103.0
Appendix J: Data for materials used - White Blast Furnace Slag
Si02 % 38.34
AI203 % 5.94
Fe203 % 0.43
Ca0 % 39.85
Mg0 % 12.40
LECO S03 % 1.41
Grav. S03 % 0.49
S2- % 0.37
CI- % 0.06
Mn0 % 0.01
Mn % 0.01
K20 tot % 0.49
Na20 tot % 0.48
Na20 eqv. % 0.80
Ti02 % 0.25
P205 % 0.05
L.O.I % 0.62
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