Un ácido débil monoprótico tiene una constante de

pKa=3,7587. Determinar su diagrama pCpH cuand

acuífero generando las siguientes concentraciones
a) 0,87 M
b) 0,66 M
c) 0,5 M
d)0,1 M
e) 0,01M
f)0,001 M
Ka 0.0001743

pKa 3.7587

[HA]o 0.87 0.66 0.5 0.1 0.01 0.001 M

[A-] 0.0122 0.0107 0.0093 0.0042 0.0013 0.0004 M

p[A-] 1.9127 1.9696 2.0298 2.3793 2.8784 3.3701
[H+] 0.0122 0.0107 0.0093 0.0042 0.0013 0.0004 M

pH 1.9127 1.9696 2.0298 2.3793 2.8784 3.3701

[HA] 0.8578 0.6493 0.4907 0.0958 0.0087 0.0006 M

p[HA] 0.0666279 0.187572 0.3092157 1.01852501 2.0616356 3.2414613
Ka 0.000174301
[HA]o 0.87 0.66 0.5
Serie 1 Serie 2 Serie 3
pH p[A-]
0 3.8192564388 3.9392317558 4.0598056871
1 2.8199370683 2.9399123853 3.0604863166
2 1.8266853313 1.9466606483 2.0672345795
3 0.8889601961 1.0089355132 1.1295094444
4 0.2574082153 0.3773835324 0.4979574636
5 0.0847085537 0.2046838708 0.325257802
6 0.0629652615 0.1829405785 0.3035145097
7 0.0607298394 0.1807051564 0.3012790877
8 0.060505663 0.1804809801 0.3010549113
9 0.060483239 0.1804585561 0.3010324873
10 0.0604809965 0.1804563136 0.3010302448
11 0.0604807723 0.1804560894 0.3010300206
12 0.0604807499 0.1804560669 0.3010299982
13 0.0604807476 0.1804560647 0.3010299959
14 0.0604807474 0.1804560645 0.3010299957

Diagrama pCpH
8

5
p[A-]

0
0 2 4 6 8 10

pH
 0.1 0.01 0.001
Serie 4 Serie 5 Serie 6
p[A-]
4.7587756914 5.7587756914 6.7587756914
3.7594563209 4.7594563209 5.7594563209
2.7662045839 3.7662045839 4.7662045839
1.8284794487 2.8284794487 3.8284794487
1.1969274679 2.1969274679 3.1969274679
1.0242278063 2.0242278063 3.0242278063
1.0024845141 2.0024845141 3.0024845141
1.000249092 2.000249092 3.000249092
1.0000249156 2.0000249156 3.0000249156
1.0000024916 2.0000024916 3.0000024916
1.0000002492 2.0000002492 3.0000002492
1.0000000249 2.0000000249 3.0000000249
1.0000000025 2.0000000025 3.0000000025
1.0000000002 2.0000000002 3.0000000002
1 2 3

ma pCpH

Col umn B
Col umn C
Col umn D
Col umn E
Col umn F
Col umn G

10 12 14 16
Ka 0.000174301
[HA]o 0.87 0.66 0.5
Serie 1 Serie 2 Serie 3
pH p[HA]
0 0.0605564388 0.1805317558 0.3011056871
1 0.0612370683 0.1812123853 0.3017863166
2 0.0679853313 0.1879606483 0.3085345795
3 0.1302601961 0.2502355132 0.3708094444
4 0.4987082153 0.6186835324 0.7392574636
5 1.3260085537 1.4459838708 1.566557802
6 2.3042652615 2.4242405785 2.5448145097
7 3.3020298394 3.4220051564 3.5425790877
8 4.301805663 4.4217809801 4.5423549113
9 5.301783239 5.4217585561 5.5423324873
10 6.3017809965 6.4217563136 6.5423302448
11 7.3017807723 7.4217560894 7.5423300206
12 8.3017807499 8.4217560669 8.5423299982
13 9.3017807476 9.4217560647 9.5423299959
14 10.3017807474 10.4217560645 10.5423299957

Diagrama pCpH
14

12

10

8
p[HA]

0
0 2 4 6 8 10 12

pH
 0.1 0.01 0.001
Serie 4 Serie 5 Serie 6
p[HA]
1.0000756914 2.0000756914 3.0000756914
1.0007563209 2.0007563209 3.0007563209
1.0075045839 2.0075045839 3.0075045839
1.0697794487 2.0697794487 3.0697794487
1.4382274679 2.4382274679 3.4382274679
2.2655278063 3.2655278063 4.2655278063
3.2437845141 4.2437845141 5.2437845141
4.241549092 5.241549092 6.241549092
5.2413249156 6.2413249156 7.2413249156
6.2413024916 7.2413024916 8.2413024916
7.2413002492 8.2413002492 9.2413002492
8.2413000249 9.2413000249 10.2413000249
9.2413000025 10.2413000025 11.2413000025
10.2413000002 11.2413000002 12.2413000002
11.2413 12.2413 13.2413

ma pCpH

Col umn B
Col umn C
Col umn D
Col umn E
Col umn F
Col umn G

10 12 14 16