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This Safety Data Sheet has been prepared in accordance with the Preparation of Safety Data Sheets for Hazardous Chemicals
Code of Practice (Safe Work Australia, December 2011)
SECTION 1: Identification
1.1. Product identifier
3M (TM) Scotchgard (TM) Protector for Fabric & Upholstery
Recommended use
Fabric and upholstery protector for consumer use.
Refer to Section 14 of this Safety Data Sheets for product Dangerous Goods Classification.
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3M (TM) Scotchgard (TM) Protector for Fabric & Upholstery
Signal word
DANGER!
Symbols
Flame | Health Hazard |
Pictograms
Hazard statements
H222 Extremely flammable aerosol.
Precautionary statements
General:
P102 Keep out of reach of children.
P103 Read label before use.
P101 If medical advice is needed, have product container or label at hand.
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Do not pierce or burn, even after use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P270 Do not eat, drink or smoke when using this product.
P264 Wash thoroughly after handling.
Response:
P307 + P311 IF exposed: Call a POISON CENTRE or doctor/physician.
Storage:
P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50ºC.
P405 Store locked up.
Disposal:
P501 Dispose of contents/container in accordance with applicable
local/regional/national/international regulations.
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3M (TM) Scotchgard (TM) Protector for Fabric & Upholstery
Inhalation
Remove person to fresh air. Get medical attention.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary.
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3M (TM) Scotchgard (TM) Protector for Fabric & Upholstery
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3M (TM) Scotchgard (TM) Protector for Fabric & Upholstery
mg/m3(800 ppm)
Butane 106-97-8 ACGIH STEL:1000 ppm
Natural gas 106-97-8 ACGIH Limit value not established:
Hydrotreated heavy naphtha 64742-48-9 Manufacturer TWA:100 ppm
(petroleum) (c11-c13) determined
Propane 74-98-6 Australia OELs Limit value not established: Explosion hazard,
asphyxiant
Propane 74-98-6 ACGIH Limit value not established:
Natural gas 75-28-5 ACGIH Limit value not established:
Isobutane 75-28-5 ACGIH STEL:1000 ppm
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
Australia OELs : Australia. Adopted National Exposure Standards for Atmospheric Contaminants in the Occupational Environment
CMRG : Chemical Manufacturer's Recommended Guidelines
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
Sen: Sensitiser
Sk: Absorption through the skin may be a significant source of exposure.
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Safety glasses with side shields.
Select and use eye protection in accordance with AS/NZS 1336. Eye protection should comply with the performance
specifications of AS/NZS 1337.
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Fluoroelastomer
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece supplied-air respirator.
For questions about suitability for a specific application, consult with your respirator manufacturer.
Select and use respirators according to AS/NZS 1715. Respirators should comply with AS/NZS 1716 performance
specifications. For information about respirators, call 3M on 1800 024 464.
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3M (TM) Scotchgard (TM) Protector for Fabric & Upholstery
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3M (TM) Scotchgard (TM) Protector for Fabric & Upholstery
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation
Intentional concentration and inhalation may be harmful or fatal. Simple asphyxiation: Signs/symptoms may include
increased heart rate, rapid respirations, drowsiness, headache, incoordination, altered judgement, nausea, vomiting, lethargy,
seizures, coma, and may be fatal. May cause target organ effects after inhalation.
Skin contact
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Eye contact
Contact with the eyes during product use is not expected to result in significant irritation.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
May cause target organ effects after ingestion.
Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Ingestion No data available; calculated ATE >5,000
mg/kg
Hydrotreated heavy naphtha Inhalation-Vapour (4 LC50 estimated to be 20 - 50 mg/l
(petroleum) (c11-c13) hours)
Hydrotreated heavy naphtha Dermal Rabbit LD50 > 5,000 mg/kg
(petroleum) (c11-c13)
Hydrotreated heavy naphtha Ingestion Rat LD50 > 5,000 mg/kg
(petroleum) (c11-c13)
Propane Inhalation-Gas (4 Rat LC50 > 200,000 ppm
hours)
Isobutane Inhalation-Gas (4 Rat LC50 276,000 ppm
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3M (TM) Scotchgard (TM) Protector for Fabric & Upholstery
hours)
Butane Inhalation-Gas (4 Rat LC50 277,000 ppm
hours)
Ethylbenzene Dermal Rabbit LD50 15,433 mg/kg
Ethylbenzene Inhalation-Vapour (4 Rat LC50 17.4 mg/l
hours)
Ethylbenzene Ingestion Rat LD50 4,769 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Hydrotreated heavy naphtha (petroleum) (c11-c13) Rabbit Mild irritant
Propane Rabbit Minimal irritation
Isobutane Professional judgement No significant irritation
Butane Professional judgement No significant irritation
Ethylbenzene Rabbit Mild irritant
Skin Sensitisation
Name Species Value
Hydrotreated heavy naphtha (petroleum) (c11-c13) Guinea pig Not sensitizing
Ethylbenzene Human Not sensitizing
Respiratory Sensitisation
Name Species Value
Carcinogenicity
Name Route Species Value
Hydrotreated heavy naphtha Not specified. Not available Not carcinogenic
(petroleum) (c11-c13)
Ethylbenzene Inhalation Multiple animal Carcinogenic.
species
Reproductive Toxicity
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3M (TM) Scotchgard (TM) Protector for Fabric & Upholstery
Hydrotreated heavy Not specified. Not toxic to male Rat NOAEL NA 28 days
naphtha (petroleum) reproduction
(c11-c13)
Hydrotreated heavy Not specified. Not toxic to Rat NOAEL NA during gestation
naphtha (petroleum) development
(c11-c13)
Ethylbenzene Inhalation Some positive Rat NOAEL 4.3 premating & during
developmental data mg/l gestation
exist, but the data are
not sufficient for
classification
Target Organ(s)
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3M (TM) Scotchgard (TM) Protector for Fabric & Upholstery
Isobutane Inhalation kidney and/or Some positive Rat NOAEL 4,500 13 weeks
bladder data exist, but the ppm
data are not
sufficient for
classification
Butane Inhalation kidney and/or Some positive Rat NOAEL 4,489 90 days
bladder data exist, but the ppm
data are not
sufficient for
classification
Butane Inhalation blood All data are Rat NOAEL 4,489 90 days
negative ppm
Ethylbenzene Inhalation kidney and/or Some positive Rat NOAEL 1.1 2 years
bladder data exist, but the mg/l
data are not
sufficient for
classification
Ethylbenzene Inhalation liver Some positive Mouse NOAEL 1.1 103 weeks
data exist, but the mg/l
data are not
sufficient for
classification
Ethylbenzene Inhalation hematopoietic Some positive Rat NOAEL 3.4 28 days
system data exist, but the mg/l
data are not
sufficient for
classification
Ethylbenzene Inhalation auditory system Some positive Rat NOAEL 2.4 5 days
data exist, but the mg/l
data are not
sufficient for
classification
Ethylbenzene Inhalation endocrine Some positive Mouse NOAEL 3.3 103 weeks
system data exist, but the mg/l
data are not
sufficient for
classification
Ethylbenzene Inhalation bone, teeth, All data are Multiple NOAEL 4.2 90 days
nails, and/or negative animal species mg/l
hair | muscles
Ethylbenzene Inhalation heart | immune All data are Multiple NOAEL 3.3 2 years
system | negative animal species mg/l
respiratory
system
Ethylbenzene Ingestion liver | kidney Some positive Rat NOAEL 680 6 months
and/or bladder data exist, but the mg/kg/day
data are not
sufficient for
classification
Aspiration Hazard
Name Value
Hydrotreated heavy naphtha (petroleum) (c11-c13) Aspiration hazard
Ethylbenzene Aspiration hazard
Exposure Levels
Refer Section 8.1 Control Parameters of this Safety Data Sheet.
Interactive Effects
Not determined.
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3M (TM) Scotchgard (TM) Protector for Fabric & Upholstery
12.1. Toxicity
Material CAS Number Organism Type Exposure Test endpoint Test result
Hydrotreated 64742-48-9 Data not
heavy naphtha available or
(petroleum) insufficient for
(c11-c13) classification
Propane 74-98-6 Data not
available or
insufficient for
classification
Butane 106-97-8 Data not
available or
insufficient for
classification
Isobutane 75-28-5 Data not
available or
insufficient for
classification
Ethylbenzene 100-41-4 Rainbow trout Experimental 96 hours LC50 4.2 mg/l
Ethylbenzene 100-41-4 Water flea Experimental 24 hours EC50 1.81 mg/l
Ethylbenzene 100-41-4 Green Algae Experimental 96 hours EC50 3.6 mg/l
Material CAS Number Test type Duration Study Type Test result Protocol
Propane 74-98-6 Experimental Photolytic half- 27.5 days (t Other methods
Photolysis life (in air) 1/2)
Butane 106-97-8 Experimental Photolytic half- 12.3 days (t Other methods
Photolysis life (in air) 1/2)
Isobutane 75-28-5 Experimental Photolytic half- 13.7 days (t Other methods
Photolysis life (in air) 1/2)
Ethylbenzene 100-41-4 Experimental Photolytic half- 4.26 days (t Other methods
Photolysis life (in air) 1/2)
Hydrotreated 64742-48-9 Data not N/A N/A N/A N/A
heavy naphtha available or
(petroleum) insufficient for
(c11-c13) classification
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3M (TM) Scotchgard (TM) Protector for Fabric & Upholstery
Material CAS Number Test type Duration Study Type Test result Protocol
Propane 74-98-6 Data not N/A N/A N/A N/A
available or
insufficient for
classification
Isobutane 75-28-5 Experimental Bioaccumulati 1.97 Other methods
BCF - Other on factor
Ethylbenzene 100-41-4 Experimental Bioaccumulati 15 Other methods
BCF - Other on factor
Hydrotreated 64742-48-9 Data not N/A N/A N/A N/A
heavy naphtha available or
(petroleum) insufficient for
(c11-c13) classification
Butane 106-97-8 Experimental Log Kow 2.89 Other methods
Bioconcentrati
on
Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. As a disposal
alternative, utilize an acceptable permitted waste disposal facility.
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3M (TM) Scotchgard (TM) Protector for Fabric & Upholstery
Poison Schedule:This product meets the aerosol exemption requirements of the Standard for the Uniform Scheduling of Medicines and
Poisons.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our
knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use
(except as required by law). The information may not be valid for any use not referred to in this Safety Data Sheet or use of
the product in combination with other materials. For these reasons, it is important that customers carry out their own test to
satisfy themselves as to the suitability of the product for their own intended applications.
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