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Agenda
Andreas Rost
● Tensile: Rm
Toughness
● Empiric Min. Requirements
● Charpy-V Noch, Bead on Plate Test
● Pellini DWT Test
● Fracture Mechanics
● Standards:
DIN EN 10002
ASTM E8
- Automatic measurement of
prismatic tensile specimen
- portal handling system
- direct data transfer for certification
Load 1,200 kN
certification
specimen
Load 100 kN
System
Result:
Elongation in Z - direction
Equipment:
Transition temperature
Charpy – V notch Shear area
Lateral Expansion
200
Toughness in Joule
150
good
100
50
27
bad
● Standards:
DIN EN 10045
ASTM E23
● Test Equipment: PW 75 / 30
Impact Testing System
Energy: 750 Joule
● Test Equipment:
PW 75 / 30, PW 30 / 15
- N2 cooling up to -196°C
certification
● Test Equipment:
TE – Temperature Unit
- temperature unit
+300 < T ≤ -190°C
- digital temperature
controlling system
● Standards:
DIN EN ISO 6506, 6507, 6508
ASTM
Load 250 kg
Result:
● o.k. / not o. k.
(Crack behavior at a bending radius of 60°)
Standards:
• ISO 12135
• ESIS P2
• ASTM E 1820
• BS 7448
1350
S1100QL
1200
S960QL
Minimum yield (MPa)
1050
S890QL1
900
S690QL1
750
X100
600
StE460 X80
450 St52 X70/S460ML
St37 X60/S420ML
300
X52/S355ML
● TM - Steels
Mirco alloying of Nb, V, Ti Re up to 550 MPa
● Q&T Steels
Alloying of C, Mn, Re up to 1100 MPa
Mikrolegierung
Mn Ar3
Ar1
Haspeln beschleunigte
Abkühlung
Time
S355J2G3 S355M
C 0.18 % Re 429MPa C 0.08 % Re 420MPa
Si 0.35 % Rm 568MPa Si 0.35 % Rm568MPa
Toughness Re/CEV
500
200 400
100 300
-100 - 50 0 ]a
[n
M
p
ize
rckg
tS
0,34 0,38 0,42 0,46 0,50
TM Steels N Steels
Heavy Plate Symposium 2008
Heat treatment: Normalizing
Ac3
Ac1
2. Fast cooling
Austenit Martensit
IMPROVEMENT OF LIFETIME
HARDNESS CARBIDES
BRINAR® 400, 450 BRINAR® 400 Cr
BRINAR® 500
Chemical composition:
C = 0,18 Si = 0,40 Mn = 1,60
Water-quenching equipment:
- state-of-the-art facility, one of the most modern
facilities worldwide
- patented water distribution
Steel grades:
- high-tensile steels
MAXIL® 500 Q, QL, QL 1 to MAXIL® 1.100 Q
- wear-resistant steels
BRINAR® 400, BRINAR® 500
Plate dimensions:
Thickness: 5 - 80 mm
Quality performance
Product development
- Low temperature steels
- High ambient temperature steels
- Sour gas resistant steels
- Steels supposed for extended PWHT
- Stainless steels
Conditions:
Largely unchangeable chemical contents, production processes,
properties ….
Improved properties
Process optimisation
Cost reduction
Quality improvement
Actual 2010
Improvement of thickness
180
150
120
90
Improvement of Dimensions
Blech-
dicke Röhrengüten
TM/IK-gew alzt
in mm < XX80
70 X80 X100
2007
=60
2007
=50
=40
2007
=30
=25
=12
Nickel-alloy
Nickel-alloysteels
steelsfor
for
liquid ethylene tanks
liquid ethylene tanks
Case
Casehardened
hardened
nickel-alloy
nickel-alloysteels
steels
Sour
Sourgas
gasresistant
resistant
vessel plates
vessel plates
Case
Casehardened
hardenedheat
heat
resistant steels
resistant steels
Steels
Steelswith
with modified
modified
elastic limits
elastic limits
Chrome-Molybdenum steel
13 CrMo 44
10 CrMo 910
A387 Gr 11 /12 /22
570
550
530
510
490
470
450
Rt0,5 S
S: PWHT 6,6 h
430
Rm S
at 610°C
Mpa
410
Rt0,5 U
390
370
Rm U U: without PWHT
350
330
310
290
270
250
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
35 40
35
30
30
25
25
20
approx. 40Joule
Häufigkeit
Häufigkeit
20
15
15
10
10
5
5
0 0
1
0
42
59
77
94
53
68
83
99
er
er
11
12
14
16
18
19
21
23
11
12
14
15
17
19
20
22
öß
öß
gr
gr
d
d
un
un
Klasse Klasse
Rp0,2 640°C
Rp0,2
Tensile Test after PWHT 640 °C and 620 °C Rm 640 °C Tensile Test after PWHT 610°C
Rm
Rp0,2 min
Rp0,2 min
650 Rm min 650
Rm min
Rm max
Rm max
Rp0,2 620 °C
600 Rm 620 °C 600
550 550
500 500
Rp0,2 / Rm (MPa)
Rp0,2 / Rm (MPa)
450 450
400 400
350 350
300 300
250 250
200 200
175 175
150 150
KV (J)
KV (J)
125 125
100 100
75 75
50 50
25 25
Influenced by:
Chemical composition
Strength level
Microstructure
H2S S
S
Corrosive Gas
H2S S H2S Reduction of hydrosulphide
H H2S → S + 2H
H H H
Dislocation H Collection of hydrogen atoms in structural
Flaw
Steel H Non-metallic flaws
enclosure Grain boundary
H H
H2
Compounding of molecular hydrogen
(= recombination) at enclosures and flaws
Steel plant:
- Adjustment of defined components and ratios in the heat (e.g. S, P, H, C)
- Vacuum degassing
- CaSi – treatment
- Avoiding brittle structures, (carbide strings, enclosures)
- Avoiding central segregation (C, Mn, P, casting conditions)
Rolling:
- Homogenous, fine-grain structure (low tolerances of the rolling
parameters)
- High durability
- Low hardening when subject to cold
b
25mm 50mm 75mm
a
b
www.ilsenburger-grobblech.de
Salzgitter AG
and
Salzgitter Steel
Salzgitter AG Group
External Sales cons.: € 10.2 billion Employees: 23,107
Internal Sales: € 3.6 billion
• Total Sales: • Total Sales: • Total Sales: • Total Sales: • Total Sales:
€ 4.0 billion € 2.6 billion € 5.0 billion € 1.2 billion € 0.6 billion
(H2 2007)
Salzgitter AG (Holding)
Steel Röhren
Tubes Trading Services Technology
Salzgitter Stahl GmbH Mannesmannröhren-
Werke GmbH
simplified structure
Heavy Plate Symposium 2008
Steel Division - Overview
Steel Division
Crude steel production 2007: 5.7 m tons
Rolled steel production 2007: 5.5 m tons
Coking Plant:
2 batteries: total of 108 coke ovens, each with 46.0 m3
3 Blast Furnaces:
Hearth diameter: 11.2 m, 11.2 m and 8.2 m
Steel Works:
Primary Metallurgy: 3 * 210 t LD Converter
Secondary Metallurgy: vacuum degassing, ladle
furnace and alloying
3 Continuous Casters:
1 Strand
210 - 250 mm thick, 1,100 – 2,000 mm wide
1 Strand
210 - 250 mm thick, 1,900 – 2,600 mm wide
1 Strand
Electro-Galvanising
Surface Coating
Large Diameter Pipes
Profile Sheets
Peine
Ilsenburg
Heavy Section Mill
Heavy Plate Mill Universal Medium Section Mill
Key Facts
Ilsenburger Grobblech GmbH
Facts:
Headquarters Ilsenburg:
• Heavy Plate Mill with adjustment line and dispatch area
• Supply with slabs mainly from Salzgitter, computer controlled production
scheduling, Quality Management
• Main supplier of heavy plates in the Salzgitter group
• Investments of more than 115 Mill. Euros during the last 15 years
Benefits: improving the plant, plate quality and logistics
Fine
Finegrain
grainstructural
structural
steel
steel
HIC-resistant
HIC-resistant
General
Generalstructural
structural steel
steel
steel
steel
Shipbuilding
Shipbuilding
Corrosion-,
Corrosion-,acid-
acid- steel
and heat steel
and heat
resistant
resistantsteel
steel
Nickel
Nickelalloyed
alloyed TMCP-/SZ-
TMCP-/SZ-
low temperature
low temperature steel
steel
steel
steel
Stainless
Stainless Pressure
Pressure
Abrasion
Abrasionresistant
resistant
Employees
(31/12/2005) 756 742 742
As of: March 31, 2008
Heavy Plate Symposium 2008
Current Production Program
Thickness: 5 – 125 mm
(5 – 80 mm for ASTM)
Width: max. 3.500 mm
Length: 4.000 – 24.000 mm
Max. plate weight : 15,1 t > 2.500 mm
20,5 t < 2.500 mm
Water-quenching equipment
- state-of-the-art facility, one of the most modern
facilities worldwide
- patented water distribution
Brands
- BRINAR® 400, 450 and 500
- MAXIL® 500 up to 1100
Plate dimensions
Thickness: 5 - 80 mm
Width: up to 3,500 mm
Length: max. 13,5 m
Offshore Grades
e.g. 355 EM/ EMZ, API-2 H, S 355 M1/ 2/ 3 /4. S 420 G1/2, S 460 G1/2 …
Boiler Plates
e.g. P 265/ 295GH, 16 Mo 3, 13 CrMo 4-5, SA 516 Gr. 60/ 65/ 70 (HIC), SA 387 Gr. 11 cl.2
Thickness: 5 – 120 mm
(5 - 80 mm for ASTM)
Pipe Steels
e.g. A, B, X 52 – X 70, Sour gas X 65/70, L 360MB – L485MB
Thickness: 5 – 120 mm
MAXIL® 500, MAXIL® 620, MAXIL® 690, MAXIL® 890, MAXIL® 960, MAXIL® 1100
Water-quenched
abrasion-resistant steels
BRINAR® 400
BRINAR® 450
BRINAR® 500
Chromium-alloyed
abrasion-resistant steels
BRINAR® 325 Cr
BRINAR® 400 Cr
Development,
Sales Policy
and
Customer Relationship
Germany - Machinery
T
21.000 20.190
14.000
11.320
7.190
6.680
6.180
7.000
4.520 4.790
4.370
3.780
3.120 3.050