Soda lime

Soda lime is a mixture of chemicals, used in granular form in closed breathing

environments, such as general anaesthesia, submarines, rebreathers and
recompression chambers, to remove carbon dioxide from breathing gases to
prevent CO2 retention and carbon dioxide poisoning.[1][2]

It is made by treating slaked lime with concentrated sodium hydroxide

solution.

Contents
1 Chemical components
2 Anaesthetic use
3 Rebreather use
4 Chemical reaction
5 Analogy with the alkali-silica reaction
6 See also Drägersorb® Soda Lime
7 References
8 External links

Chemical components
The main components of soda lime are

Calcium hydroxide, Ca(OH)2 (about 75%)

Water, H2O (about 20%)
Sodium hydroxide, NaOH (about 3%)
Potassium hydroxide, KOH (about 1%).

Anaesthetic use
During the administration of general anaesthesia, the gases expired by a patient, which contain carbon dioxide, are passed through an
anaesthetic machine breathing circuit filled with soda lime granules.[1] Medical-grade soda lime includes an indicating dye that
changes color when the soda lime reaches its carbon dioxide absorbing capacity
.

To ensure that a soda lime canister (CO2 absorber) is functioning properly, it should not be used if the indicating dye is activated.
Standard anaesthesia machines typically contain up to 2 kg of soda lime granules.

Lithium hydroxide (LiOH) is the alkali hydroxide with the lowest molecular weight (24 g/mol; Li: 7 g/atom gram) and is therefore
used as CO2 absorbent in space flights since the Apollo programme to spare weight at launch. During Apollo 13 flight, the crew
sheltered in the lunar module started suffering from high CO2 levels and had to adapt spare absorbent cartridges from the Apollo
capsule to the LEM system.
Recent generation of CO2 absorbents have been developed to reduce the risk of formation of toxic by-products as a result of the
interaction between the absorbent and inhaled anesthetics. Some absorbents made from lithium hydroxide (LiOH) are also available
for this purpose.

Rebreather use
Exhaled gas must be passed through a "carbon dioxide scrubber" where the carbon dioxide is absorbed before the gas is made
available to be breathed again. Inrebreathers the scrubber is a part of the breathing loop.[2][3] Color indicating dye was removed from
US Navy fleet use in 1996 when it was suspected of releasing chemicals into the circuit.[4] In larger environments, such as
.[2]
recompression chambers or submarines, a fan is used to maintain the flow of gas through the scrubbing canister

Chemical reaction
The overall reaction is:

CO2 + Ca(OH)2 → CaCO3 + H2O + heat (in the presence of water)

Each mole of CO2 (44 g) reacting with calcium hydroxide produces one mole of water (18 g).

The reaction can be considered as a strong-base-catalysed, water

-facilitated reaction.

The reaction mechanism of carbon dioxide with soda lime can be decomposed in three elementary steps:

1) CO2 (g) → CO2 (aq) (CO2 dissolves in water - slow and rate-determining)

2) CO2 (aq) + NaOH → NaHCO3 (bicarbonate formation at high pH)

3) NaHCO3 + Ca(OH)2 → CaCO3 + H2O + NaOH ((NaOH recycled to step 2) - hence a

catalyst)

This sequence of reactions explains the catalytic role played by sodium hydroxide in the system and why soda lime is faster in
chemical reactivity than calcium hydroxide alone. It reacts much more quickly and so contributes to a faster elimination of the CO2
from the rebreathing circuit. The formation of water and the moisture from the respiration also act as a solvent for the reaction.
Reactions in aqueous phase are generally faster than between a dry gas and a dry solid.

Analogy with the alkali-silica reaction

A quite didactic parallelism can be drawn between the catalytic role of sodium hydroxide in the process of carbonation of soda lime
and the role of sodium hydroxide played in the alkali-silica reaction, a slow degration process causing the swelling and the cracking
of concrete containing aggregates rich in reactive amorphous silica. In a very similar way, NaOH greatly facilitates the dissolution of
the amorphous silica. The produced sodium silicate then reacts with the calcium hydroxide (portlandite) present in the hardened
cement paste to form calcium silicate hydrate (abbreviated as C-S-H in the cement chemist notation). This silicification reaction of
Ca(OH)2 on its turn continuously releases again sodium hydroxide in solution, maintaining a high pH, and the cycle continues up to
the total disappearance of portlandite or reactive silica in the exposed concrete. Without the catalysis of this reaction by sodium or
potassium soluble hydroxides the alkali-silica reaction would not proceed or would be limited to a very slow
pozzolanic reaction. The
alkali silica reaction can be written like the soda lime reaction, by simply substituting CO2 by SiO2 in the reactions mentioned here
above as follows:

reaction SiO2 + NaOH

→ NaHSiO3 (silica dissolution by NaOH: high pH)
1:
reaction NaHSiO3 + CaSiO3 + H2O + (C-S-H precipitation and regeneration of
→
2: Ca(OH)2 NaOH NaOH)
 sum SiO2 + → CaSiO3 + H2O (global reaction = Pozzolanic reaction
(1+2): Ca(OH)2 catalysed by NaOH)

See also
Carbon dioxide scrubber
Alkali-silica reaction (ASR)

References
1. J. Jeff Andrews (1 September 2005). "Anesthesia Systems". In Paul G. Barash; Bruce F . Cullen; Robert K. Stoelting.
Clinical Anesthesia (http://www.isbnlib.com/isbn/0781757452/Clinical-Anesthesia-Clinical-Anesthesia--Barash)(5th
ed.). United States: Lippincott Williams & Wilkins. p. 1584.ISBN 0-7817-5745-2. Retrieved 1 July 2010.
2. Brubakk, Alf O.; Tom S. Neuman (2003).Bennett and Elliott's physiology and medicine of diving, 5th Rev ed
. United
States: Saunders Ltd. p. 800.ISBN 0-7020-2571-2.
3. Richardson, Drew; Menduno, Michael; Shreeves, Karl (eds). (1996)."Proceedings of Rebreather Forum 2.0."(http://
archive.rubicon-foundation.org/7555). Diving Science and Technology Workshop. Diving Science and Technology:
286. Retrieved 2009-03-18.
4. Lillo RS, Ruby A, Gummin DD, Porter WR, Caldwell JM (March 1996)."Chemical safety of U.S. Navy Fleet soda
lime" (http://archive.rubicon-foundation.org/2238). Undersea Hyperb Med. 23 (1): 43–53. PMID 8653065 (https://ww
w.ncbi.nlm.nih.gov/pubmed/8653065). Retrieved 2009-03-18.

External links
Sofnolime MSDS Example of a commercial soda lime product that is used in diving and medicine
Publications on sodalime in diving operations
An Introduction to Sofnolime (Technical Article)

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