EXERCISE 8

VISCOSITY OF PURE LIQUIDS AND SOLUTIONS

Sample Calculations
Section: 1L, Group 1

A. Effect of concentration (sample: 1-propanol)

1. Calibration constants A and B
( )

Plotted values:

water

acetone

ethyl acetate

Using linear regression analysis:

Slope:

y-int:
r2 = 0.930167989

2. Calculation of ρsolution

3. Calculation of ƞ

( )( )

1|Chem 111.1 Exercise 8 Sample Calculations (Section 1L, Group 1)

 B. Effect of temperature (sample: 1-propanol)
1. Calculation of ƞ

( )( )

2. Calculation of ̅
̅ ( )
̅

( )( )
( ) ( )
( )( )

3. Determination of ̅ and ̅
̅ ̅ ̅

Plotted values:
,K ̅ , J/mol
293.15 53986.56052
298.15 54562.89921
303.15 55188.07577
308.15 55761.19665
313.15 56396.7653
318.15 57015.61803
323.15 57629.16984

Using linear regression analysis:

Slope: ̅

y-int: ̅

r2 = 0.999835163

C. Polymer (sample: NaCMC)

1. Calculation of ƞsp

2|Chem 111.1 Exercise 8 Sample Calculations (Section 1L, Group 1)

 2a. [ƞ] from ƞred
Plotted values:
, g/dL
1.00 3.285714286
0.75 2.476190476
0.50 1.392857143
0.25 2.071428571
0.10 3.303571429
0.05 2.142857143

Using linear regression:

y-int: [ ]
r2 = 0.049484093

2b. [ƞ] from ƞinh

Plotted values:

, g/dL ( )
1.00 1.455287233
0.75 1.399762833
0.50 1.057050402
0.25 1.669198263
0.10 2.854474347
0.05 2.035653886

Using linear regression:

y-int: [ ]
r2 = 0.432083309

3a. ̅ from ƞred

[ ] ̅
̅
̅

3b. ̅ from ƞinh

[ ] ̅
̅
̅

4a. s from ƞred

̅

( )( )

3|Chem 111.1 Exercise 8 Sample Calculations (Section 1L, Group 1)

 4b. s from ƞinh
̅

( )( )

5a. r from ƞred

⁄
( )
⁄
( )
( )

5b. r from ƞinh

⁄
( )
⁄
( )
( )

⁄
6a. from ƞred
[ ]̅ ⁄
⁄
[ ]
⁄
( )( )
⁄
[ ]

⁄
6b. from ƞinh
[ ]̅ ⁄
⁄
[ ]
⁄
( )( )
⁄
[ ]

4|Chem 111.1 Exercise 8 Sample Calculations (Section 1L, Group 1)