S1401 Epoxy primer
DS-S1401-REV8-0309

Description: S1401 primer is a specially formulated 100% volume solids (solvent

less) two component epoxy

Recommended use: As an epoxy primer in a 3 layer polyethylene coating system for

superior corrosion protection of field welded joints of steel pipes. S1401
can be used with Covalence Raychem* 3 layer coating systems:
HTLP80, HTLP60, DIRAX-60E, and HTLP-PP as the initial anti-
corrosion layer or as wear cones in the PPS120 and DIRAX-PP system.
For HTLP80, DIRAX-60E, HTLP-PP the epoxy primer needs to be
applied on the steel surface only. For HTLP60 the epoxy needs to be
applied onto the steel surface AND onto the line coating, when this line
coating is PE, FBE or CTE.
S1401 can also be used as repair coating for PP and FBE line coatings.

Colour: Grey

Volume solids: 100%

Weight solids: 100%

Mixing ratio: (by volume): 5 parts of base (part A) to 1 part of hardener (part B)
(by weight) : 100 parts of base (part A) to 12 parts of hardener (part B)

Typical coverage: 2 sq.m/litre (21.52 sq.ft/litre) or 6.6 sq.m/US gallon (70.7 sq.ft/US
gallon). This coverage is based on 300 microns or 12 mils average wet
film thickness.

Specific gravity: Base: 1.8

Hardener: 1

Typical thickness: 300 microns (12mils)

Pot life: 20 min at 23°C (73°F)

Shelf life: 2 years 23°C (73°F), out of direct sunlight. Shelf life will be lesser at
higher temperatures.

Flash point: Part A (Base): 252°C (485.6°F)

Part B (Hardener): 257°C (494.6°F)

Thinner: Do not dilute

Application 1. Prepare the pipe surface as recommended in the product

application guide
2. Pour hardener into base as per mixing ratio. Stir the mixture for
approximately 1 minute to ensure a homogeneous mixture.
3. Carefully apply mixed epoxy primer as indicated in the product
application guide.


  S1401 Epoxy primer
DS-S1401-REV8-0309

Curing Chart:

S1401 0°C 10°C 20°C 30°C 40°C 50°C 60°C

Pot Life 34 minutes 25 minutes 12 minutes 8 minutes 4 minutes 2 minutes 2 minutes
Gel Time 45 minutes 30 minutes 15 minutes 14 minutes 12 minutes 10 minutes 7 minutes
Dry time 9 hours 4 hours 1 hour 48 minutes 30 minutes 28 minutes 20 minutes
Shore D 70 9 hours 4 hours 2 hours 1hour 30min. 1hour 10min. 1 hour 50 minutes

Ordering info: Epoxy kit: S1401-KIT-0.5L-0.13GAL/WA(C10)

This kit only includes measured quantities of base resin and hardener.
Order quantity should be multiples of 10.
Epoxy accessories to mix and apply the epoxy should be ordered
separately.
Bulk Epoxy:
Base : S1401-PART-A-18L-4.75GAL
Hardener: S1401-PART-B-18L-4.75GAL
Always order in multiples of 5 pails of part A by 1 pail of part B

Epoxy accessories to mix and apply the epoxy should be ordered

separately.
 SAFETY DATA SHEET
Based on Regulation (EC) No 1907/2006 (REACH) Article 31 and Annex II

S1401 PART A

1. Identification of the substance/preparation and of the company/undertaking

1.1 Identification of the substance or preparation:
Product name : S1401 PART A
Synonyms : none
CAS No. : N.A.
EC index No. : N.A. NFPA code : N.D.
EINECS No. : N.A. Molecular weight : N.A.
RTECS No. : N.A. Formula : N.A.
1.2 Use of the substance/preparation:
- Epoxy resin
1.3 Company/undertaking identification:
Berry Plastics BVBA
Nieuwlandlaan B15
B-3200 Aarschot
Tel: +32 16 55 36 00
Fax: +32 16 55 36 74
e-mail address: cpge@berryplastics.com
1.4 Emergency telephone:
+32 14 58 45 45 (24h/24h)
Information centre on dangerous goods (BIG)
Technische Schoolstraat 43A, B-2440 Geel, Belgium

2. Hazards identification
- Irritating to eyes and skin
- May cause sensitisation by skin contact
- Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment

3. Composition/information on ingredients

Hazardous ingredients CAS No. Conc. (%) Hazards Hazard

symbol
EINECS/ELINCS No. (R-phrases)
reaction product: bisphenol-A- 25068-38-6 >10 36/38-43-51/53 (1) Xi;N
(epichlorhydrin); epoxy resin
(number average molecular 500-033-5
weight <=700)
phenol/formaldehyde/glycidyl 28064-14-4 >10 36/38-43-51/53 (1) Xi;N
ether, polymer
-
(1) For R-phrases in full: see heading 16
(2) Substance with a Community workplace exposure limit
(3) PBT-substance

4. First aid measures

4.1 After inhalation:
- Remove the victim into fresh air
- Respiratory problems: consult a doctor/medical service
4.2 Skin contact:
- Wash immediately with lots of water
- Soap may be used
- Do not apply (chemical) neutralizing agents
- Take victim to a doctor if irritation persists

Printing date : 07-2009 1/9

Compiled by : Brandweerinformatiecentrum voor Gevaarlijke Stoffen vzw (BIG)
Technische Schoolstraat 43 A, B-2440 Geel
 +32 14 58 45 47 http://www.big.be e-mail address: info@big.be

Date of issue : 09-06-2008 Revision : 10-06-2008

Reference number : BIG\40160GB Revision number : 004
Reason for revision : 15.2
 S1401 RESIN
4.3 Eye contact:
- Rinse immediately with plenty of water
- Do not apply neutralizing agents
- Take victim to an ophtalmologist if irritation persists
4.4 After ingestion:
- Rinse mouth with water
- Consult a doctor/medical service if you feel unwell

5. Fire-fighting measures

5.1 Suitable extinguishing media:

- Polyvalent foam
- BC powder
- Carbon dioxide
5.2 Unsuitable extinguishing media:
- No data available
5.3 Special exposure hazards:
- Not easily combustible
- Upon combustion CO and CO2 are formed
5.4 Instructions:
- No specific firefighting instructions required
5.5 Special protective equipment for fire-fighters:
- Heat/fire exposure: compressed air/oxygen apparatus
- Protective clothing

6. Accidental release measures

6.1 Personal precautions:

See heading 8.2/13
6.2 Environmental precautions:
- Prevent soil and water pollution
- Prevent spreading in sewers
- Contain released substance, pump into suitable containers
- Plug the leak, cut off the supply
- Dam up the solid spill
6.3 Methods for cleaning up:
- Scoop solid spill into closing containers
- Carefully collect the spill/leftovers
- Clean contaminated surfaces with an excess of water
- Wash clothing and equipment after handling

7. Handling and storage

7.1 Handling:
- Observe very strict hygiene - avoid contact
- Do not discharge the waste into the drain
- Avoid shock and friction
- Remove contaminated clothing immediately
- Clean contaminated clothing
7.2 Storage:
- Keep container tightly closed
- Store at ambient temperature
- Store in a dry area
- Keep container in a well-ventilated place
- Keep away from: heat sources, oxidizing agents, acids, bases, amines,
water/moisture

Printing date : 07-2009 2/9

 S1401 RESIN
Storage temperature : 2/40 °C
Quantity limits : N.D. kg
Storage life : N.D. days
Materials for packaging :
- suitable : no data available
- to avoid : no data available

7.3 Specific use(s):

- See information supplied by the manufacturer for the identified use(s)

8. Exposure controls/Personal protection

8.1 Exposure limit values:

8.1.1 Occupational exposure:
TLV-TWA : not listed
TLV-STEL : not listed
TLV-Ceiling : not listed
WEL-LTEL : not listed
WEL-STEL : not listed
MAK : not listed

MAC-TGG 8 h : not listed

MAC-TGG 15 min. : not listed
MAC-Ceiling : not listed

VME-8 h : not listed

VLE-15 min. : not listed

GWBB-8 h : not listed

GWK-15 min. : not listed
Momentary value : not listed

EC : not listed
EC-STEL : not listed

8.1.2 Sampling methods:

- NO DATA AVAILABLE
8.2 Exposure controls:
8.2.1 Occupational exposure controls:
- Work under local exhaust/ventilation
Personal protective equipment:
a) Respiratory protection:
- Insufficient ventilation: wear respiratory protection
- Gas mask with filter type A
b) Hand protection:
- Gloves
Suitable materials: No data available
- Breakthrough time: N.D.
c) Eye protection:
- Face shield
d) Skin protection:
- Protective clothing
Suitable materials: No data available
8.2.2 Environmental exposure controls: see headings 6.2, 6.3 and 13

Printing date : 07-2009 3/9

 S1401 RESIN

9. Physical and chemical properties

9.1 General information:

Appearance (at 20°C) : Paste
Odour : Characteristic
Colour : Light grey
9.2 Important health, safety and environmental information:
pH value (at %) : 5
Boiling point/boiling range : N.D. °C
Flash point/flammability : 252 °C
Explosion limits (explosive properties) : N.D. vol%
Oxidising properties :
Vapour pressure (at 20°C) : N.D. hPa
Vapour pressure (at 50°C) : N.D. hPa
Relative density (at 20°C) : 1.8
Water solubility : Insoluble
Soluble in : N.D.
Relative vapour density : N.D.
Viscosity (at °C) : N.D. Pa.s
Partition coefficient n-octanol/water : N.D.
Evaporation rate
ratio to butyl acetate : N.D.
ratio to ether : N.D.
9.3 Other information:
Melting point/melting range : N.D. °C
Auto-ignition temperature : N.D. °C 3
Saturation concentration : N.D. g/m
Specific conductivity : N.D. pS/m

10. Stability and reactivity

10.1 Conditions to avoid:

- Stable under normal conditions
10.2 Materials to avoid:
- Keep away from: heat sources, oxidizing agents, acids, bases, amines,
water/moisture
10.3 Hazardous decomposition products:
- Upon combustion CO and CO2 are formed

Printing date : 07-2009 4/9

 S1401 RESIN

11. Toxicological information

11.1 Acute toxicity:

LD50 oral rat : N.D. mg/kg

LD50 dermal rat : N.D. mg/kg
LD50 dermal rabbit : N.D. mg/kg
LC50 inhalation rat : N.D. mg/l/4 h
LC50 inhalation rat : N.D. ppm/4 h

11.2 Chronic toxicity:

EC carc. cat. : not listed

EC muta. cat. : not listed
EC repr. cat. : not listed
Carcinogenicity (TLV) : not listed
Carcinogenicity (MAC) : not listed
Carcinogenicity (VME) : not listed
Carcinogenicity (GWBB) : not listed
Carcinogenicity (MAK) : not listed
Mutagenicity (MAK) : not listed
Teratogenicity (MAK) : not listed
IARC classification : not listed

11.3 Routes of exposure: ingestion, inhalation, eyes and skin

11.4 Acute effects/symptoms:
- AFTER SKIN CONTACT
- Tingling/irritation of the skin
- AFTER EYE CONTACT
- Irritation of the eye tissue
11.5 Chronic effects:
- May cause sensitization by skin contact
- ON CONTINUOUS/REPEATED EXPOSURE/CONTACT:
- Skin rash/inflammation

Printing date : 07-2009 5/9

 S1401 RESIN

12. Ecological information

12.1 Ecotoxicity:
reaction product: bisphenol-A-(epichlorhydrin); epoxy resin (number average
molecular weight <=700):
- LC50 (96 h) : 1.5/7.7 mg/l (SALMO GAIRDNERI/ ONCORHYNCHUS MYKISS)
- EC50 (24 h) : 1.1/3.6 mg/l (DAPHNIA MAGNA)
- EC50 (96 h) : 220 mg/l (CHLOROPHYTA)

- Effect on waste water purification : no data available

12.2 Mobility:
- Volatile organic compounds (VOC): N.D.%
- Insoluble in water
- Substance sinks in water
For other physicochemical properties see heading 9

12.3 Persistence and degradability:

- biodegradation BOD5 : N.D. % ThOD
- water : - N.D.

- soil : T ½: N.D. days

12.4 Bioaccumulative potential:

- log Pow : N.D.
- BCF : N.D.
12.5 Results of PBT assessment:
- Not applicable, based on available data.

12.6 Other adverse effects:

- WGK : 2 (Classification based on the components in compliance
with Verwaltungsvorschrift wassergefährdender Stoffe
(VwVwS) of 17 May 1999)
- Effect on the ozone layer : Not dangerous for the ozone layer
(1999/45/EC)
- Greenhouse effect : no data available

13. Disposal considerations

13.1 Provisions relating to waste:

- Waste material code (75/442/EEC, Council Decision 2001/118/EC, O.J. L47 of
16/2/2001): 07 02 99 (wastes not otherwise specified)
- Hazardous waste (91/689/EEC)

13.2 Disposal methods:

- Recycle/reuse
- Dehydrate to obtain a solid sludge
- Allow waste to solidify
- Remove to an authorized dump (Class I)
- Do not discharge into drains or the environment

13.3 Packaging/Container:
- Waste material code packaging (91/689/EEC, Council Decision 2001/118/EC,
O.J. L47 of 16/2/2001): 15 01 10* (packaging containing residues of or
contaminated by dangerous substances)

Printing date : 07-2009 6/9

 S1401 RESIN

14. Transport information

14.1 Classification of the substance in compliance with UN Recommendations

UN number : 3082
CLASS : 9
SUB RISKS : -
PACKING GROUP : III
14.2 ADR (transport by road)
CLASS : 9
PACKING GROUP : III
CLASSIFICATION CODE : M6
DANGER LABEL TANKS : 9
DANGER LABEL PACKAGES : 9
PROPER SHIPPING NAME :
Environmentally hazardous substance, liquid, n.o.s.
(reaction product: bisphenol-A-(epichlorhydrin); epoxy resin (number average
molecular weight <=700); phenol/formaldehyde/glycidyl ether, polymer)
14.3 RID (transport by rail)
CLASS : 9
PACKING GROUP : III
CLASSIFICATION CODE : M6
DANGER LABEL TANKS : 9
DANGER LABEL PACKAGES : 9
PROPER SHIPPING NAME :
Environmentally hazardous substance, liquid, n.o.s.
(reaction product: bisphenol-A-(epichlorhydrin); epoxy resin (number average
molecular weight <=700); phenol/formaldehyde/glycidyl ether, polymer)
14.4 ADNR (transport by inland waterways)
CLASS : 9
PACKING GROUP : III
CLASSIFICATION CODE : M6
DANGER LABEL TANKS : 9
DANGER LABEL PACKAGES : 9
14.5 IMDG (maritime transport)
CLASS : 9
SUB RISKS : -
PACKING GROUP : III
MFAG : -
EMS : F-A, S-F
MARINE POLLUTANT : P
14.6 ICAO (air transport)
CLASS : 9
SUB RISKS : -
PACKING GROUP : III
PACKING INSTRUCTIONS PASSENGER AIRCRAFT : 914/Y914
PACKING INSTRUCTIONS CARGO AIRCRAFT : 914
14.7 Special precautions : none
14.8 Limited quantities (LQ) :
When substances and their packaging meet the conditions established by
ADR/RID/ADNR in chapter 3.4, only the following prescriptions shall be
complied with:
each package shall display a diamond-shaped figure with the following
inscription:
- ‘UN 3082'
or, in the case of different goods with different identification numbers
within a single package:
- the letters 'LQ'

Printing date : 07-2009 7/9

 S1401 RESIN

15. Regulatory information

15.1 EU legislation:
Classification according to directives 67/548/EEC and 1999/45/EC

Irritant Dangerous for the

environment

contains: phenol/formaldehyde/glycidyl ether, polymer; reaction product:

bisphenol-A-(epichlorhydrin); epoxy resin (number average
molecular weight <=700). See information supplied by the
manufacturer.
R36/38 : Irritating to eyes and skin
R43 : May cause sensitisation by skin contact
R51/53 : Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment

S(02) : (Keep out of reach of children)

S24 : Avoid contact with skin
S28 : After contact with skin, wash immediately with plenty
of water and soap
S37/39 : Wear suitable gloves and eye/face protection
S(46) : (If swallowed, seek medical advice immediately and show
this container or label)
S61 : Avoid release to the environment. Refer to special
instructions/safety data sheets.

15.2 National provisions:

The Netherlands:
Waterbezwaarlijkheid: 6
Germany:
WGK : 2 (Classification based on the components in compliance
with Verwaltungsvorschrift wassergefährdender Stoffe
(VwVwS) of 17 May 1999)

16. Other information

Users are advised that they may have additional disclosure obligations under other national and local
laws. Users are advised to ensure that this information is brought to the attention of all employees,
agents, and contractors handling this product. Users of Berry Plastics BVBA products should make their
own evaluation to determine the suitability of each such product for the specific application and to
establish safe handling and installation procedures. Distributors of this product are advised to
forward this document, or the information contained herein, to every purchaser of this product.

Berry Plastics BVBA makes no warranties as to the accuracy or completeness of this information and
disclaims any liability in connection with its use. Berry Plastics BVBA obligations shall be only as
set forth in Berry Plastics BVBA standard terms and conditions of sale for this product. In no case
will Berry Plastics BVBA be liable for any incidental, indirect or consequential damages arising out
of the sale, resale, use or misuse of this product.

N.A. = NOT APPLICABLE

N.D. = NOT DETERMINED
(*) = INTERNAL CLASSIFICATION (NFPA)

PBT-substances = persistent, bioaccumulative and toxic substances

Printing date : 07-2009 8/9

 S1401 RESIN
Exposure limits:
TLV : Threshold Limit Value - ACGIH USA
WEL : Workplace Exposure Limits - United Kingdom
TRGS 900 : Technische Regel für Gefahrstoffe 900 (Arbeitsplatzgrenzwerte) - Germany
MAK : Maximale Arbeitsplatzkonzentrationen - Germany
MAC : Maximale aanvaarde concentratie - The Netherlands
VME : Valeurs limites de Moyenne d’Exposition - France
VLE : Valeurs limites d’Exposition à court terme - France
GWBB : Grenswaarde beroepsmatige blootstelling - Belgium
GWK : Grenswaarde kortstondige blootstelling - Belgium
EC : Indicative occupational exposure limit values - directive 2000/39/EC

Chronic toxicity:
K : List of the carcinogenic substances and processes - The Netherlands

Full text of any R phrases referred to under headings 2 and 3:

R36/38 : Irritating to eyes and skin

R43 : May cause sensitisation by skin contact
R51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment

Printing date : 07-2009 9/9

 SAFETY DATA SHEET
Based on Regulation (EC) No 1907/2006 (REACH) Article 31 and Annex II

S1401 PART B

1. Identification of the substance/preparation and of the company/undertaking

1.1 Identification of the substance or preparation:
Product name : S1401 PART B
Synonyms : none
CAS No. : N.A.
EC index No. : N.A. NFPA code : N.D.
EINECS No. : N.A. Molecular weight : N.A.
RTECS No. : N.A. Formula : N.A.
1.2 Use of the substance/preparation:
- Epoxy resin: Hardener
1.3 Company/undertaking identification:
Berry Plastics BVBA
Nieuwlandlaan B15
B-3200 Aarschot
Tel: +32 16 55 36 00
Fax: +32 16 55 36 74
e-mail address: cpge@berryplastics.com
1.4 Emergency telephone:
+32 14 58 45 45 (24h/24h)
Information centre on dangerous goods (BIG)
Technische Schoolstraat 43A, B-2440 Geel, Belgium

2. Hazards identification
- Harmful by inhalation, in contact with skin and if swallowed
- Causes burns
- May cause sensitisation by skin contact
- Possible risk of irreversible effects

3. Composition/information on ingredients

Hazardous ingredients CAS No. Conc. (%) Hazards Hazard

symbol
EINECS/ELINCS No. (R-phrases)
2,4,6- 90-72-2 10-15 22-36/38 (1) Xn
tris(dimethylaminomethyl)phenol
202-013-9
phenol 108-95-2 <5 23/24/25-34- T;C
48/20/21/22-68 (1)(2)
203-632-7
2-piperazin-1-ylethylamine 140-31-8 <5 21/22-34-43-52/53 C
(1)
205-411-0
formaldehyde, oligomeric 32610-77-8 10-15 38-41-43 (1)
reaction products with phenol
and triethylenetetramine 500-083-8
(1) For R-phrases in full: see heading 16
(2) Substance with a Community workplace exposure limit
(3) PBT-substance

4. First aid measures

4.1 After inhalation:
- Remove the victim into fresh air
- Respiratory problems: consult a doctor/medical service

Printing date : 07-2009 1/9

Compiled by : Brandweerinformatiecentrum voor Gevaarlijke Stoffen vzw (BIG)
Technische Schoolstraat 43 A, B-2440 Geel
 +32 14 58 45 47 http://www.big.be e-mail address: info@big.be

Date of issue : 29-09-2003 Revision : 10-06-2008

Reference number : BIG\40159GB Revision number : 006
Reason for revision : 15.2
 S1401 HARDENER
4.2 Skin contact:
- Wash immediately with lots of water (15 minutes)/shower
- Do not apply (chemical) neutralizing agents
- Remove clothing while washing
- Do not remove clothing if it sticks to the skin
- Cover wounds with sterile bandage
- Consult a doctor/medical service
4.3 Eye contact:
- Rinse immediately with plenty of water for 15 minutes
- Do not apply neutralizing agents
- Take victim to an ophtalmologist
4.4 After ingestion:
- Rinse mouth with water
- Immediately give lots of water to drink
- Do not induce vomiting
- Immediately consult a doctor/medical service

5. Fire-fighting measures

5.1 Suitable extinguishing media:

- Water spray
- Polyvalent foam
- BC powder
- Carbon dioxide
5.2 Unsuitable extinguishing media:
- No data available
5.3 Special exposure hazards:
- Not easily combustible
- On heating: release of toxic/combustible gases/vapours (hydrogen sulphide)
- On burning: release of toxic and corrosive gases/vapours (nitrous vapours,
sulphur oxides, carbon monoxide - carbon dioxide)
5.4 Instructions:
- Cool tanks/drums with water spray/remove them into safety
- Dilute toxic gases with water spray
- Take account of toxic firefighting water
- Use firefighting water moderately and contain it
5.5 Special protective equipment for fire-fighters:
- Heat/fire exposure: compressed air/oxygen apparatus
- Corrosionproof suit

6. Accidental release measures

6.1 Personal precautions:

See heading 8.2/13
6.2 Environmental precautions:
- Prevent soil and water pollution
- Prevent spreading in sewers
- Contain released substance, pump into suitable containers
- Plug the leak, cut off the supply
- Dam up the liquid spill
6.3 Methods for cleaning up:
- Take up liquid spill into a non combustible material e.g.: sand, earth,
vermiculite
- Scoop absorbed substance into closing containers
- Damaged/cooled tanks must be emptied
- Carefully collect the spill/leftovers
- Take collected spill to manufacturer/competent authority
- Clean contaminated surfaces with an excess of water
- Wash clothing and equipment after handling

Printing date : 07-2009 2/9

 S1401 HARDENER

7. Handling and storage

7.1 Handling:
- Observe very strict hygiene - avoid contact
- Use earthed equipment
- Do not discharge the waste into the drain
- Remove contaminated clothing immediately
- Clean contaminated clothing
7.2 Storage:
- Keep container tightly closed
- Store at ambient temperature
- Protect against frost
- Provide for a tub to collect spills
- Keep away from: heat sources, oxidizing agents, acids, water/moisture
Storage temperature : 2/40 °C
Quantity limits : N.D. kg
Storage life : N.D. days
Materials for packaging :
- suitable : no data available
- to avoid : no data available

7.3 Specific use(s):

- See information supplied by the manufacturer for the identified use(s)

8. Exposure controls/Personal protection

8.1 Exposure limit values:

8.1.1 Occupational exposure:
phenol
TLV-TWA : mg/m33 5 ppm
TLV-STEL : mg/m3 - ppm
TLV-Ceiling : mg/m ppm
WEL-LTEL : - mg/m33 2 ppm
WEL-STEL : - mg/m - ppm
TRGS 900 : 7.8 mg/m³ 2 ppm
MAK : mg/m3 ppm
MAC-TGG 8 h : 8 mg/m3
MAC-TGG 15 min. : mg/m33
MAC-Ceiling : mg/m
VME-8 h : 7.8 mg/m33 2 ppm
VLE-15 min. : 15.6 mg/m 4 ppm
GWBB-8 h : 7.8 mg/m33 2 ppm
GWK-15 min. : - mg/m3 - ppm
Momentary value : mg/m ppm
EC : 7.8 mg/m33 2 ppm
EC-STEL : - mg/m - ppm

8.1.2 Sampling methods:

- Phenol OSHA 32
- Phenol (Cresols) NIOSH 2546
- Amines, Aliphatic NIOSH 2010

Printing date : 07-2009 3/9

 S1401 HARDENER
8.2 Exposure controls:
8.2.1 Occupational exposure controls:
- Measure the concentration in the air regularly
- Work under local exhaust/ventilation
Personal protective equipment:
a) Respiratory protection:
- Gas mask with filter type A
- High vapour concentration: gas mask
b) Hand protection:
- Gloves
Suitable materials: No data available
- Breakthrough time: N.D.
c) Eye protection:
- Face shield
d) Skin protection:
- Corrosionproof clothing
Suitable materials: No data available
8.2.2 Environmental exposure controls: see headings 6.2, 6.3 and 13

9. Physical and chemical properties

9.1 General information:

Appearance (at 20°C) : Liquid
Odour : Characteristic
Colour : Light yellow
9.2 Important health, safety and environmental information:
pH value (at %) : N.D.
Boiling point/boiling range : N.D. °C
Flash point/flammability : 257 °C
Explosion limits (explosive properties) : N.D. vol%
Oxidising properties :
Vapour pressure (at 20°C) : N.D. hPa
Vapour pressure (at 50°C) : N.D. hPa
Relative density (at 20°C) : 1.1
Water solubility : 1 g/100 ml
Soluble in : N.D.
Relative vapour density : > 2
Viscosity (at °C) : N.D. Pa.s
Partition coefficient n-octanol/water : N.D.
Evaporation rate
ratio to butyl acetate : N.D.
ratio to ether : N.D.
9.3 Other information:
Melting point/melting range : N.D. °C
Auto-ignition temperature : N.D. °C 3
Saturation concentration : N.D. g/m
Specific conductivity : N.D. pS/m

10. Stability and reactivity

10.1 Conditions to avoid:

- Stable under normal conditions
10.2 Materials to avoid:
- Keep away from: heat sources, oxidizing agents, acids, water/moisture
10.3 Hazardous decomposition products:
- On heating: release of toxic/combustible gases/vapours (hydrogen sulphide)
- On burning: release of toxic and corrosive gases/vapours (nitrous vapours,
sulphur oxides, carbon monoxide - carbon dioxide)

Printing date : 07-2009 4/9

 S1401 HARDENER

11. Toxicological information

11.1 Acute toxicity:

2,4,6-tris(dimethylaminomethyl)phenol
LD50 oral rat : 1200 mg/kg
LD50 dermal rat : > 2000 mg/kg
phenol, solid
LD50 oral rat : 317/650 mg/kg
LD50 dermal rat : 669 mg/kg
LD50 dermal rabbit : 850/1400 mg/kg
2-piperazin-1-ylethylamine
LD50 oral rat : 1470 mg/kg
LD50 dermal rabbit : 880 mg/kg

11.2 Chronic toxicity:

phenol
EC carc. cat. : not listed
EC muta. cat. : 3
EC repr. cat. : not listed
Carcinogenicity (TLV) : A4
Carcinogenicity (MAC) : not listed
Carcinogenicity (VME) : not listed
Carcinogenicity (GWBB) : not listed
Carcinogenicity (MAK) : 3B
Mutagenicity (MAK) : not listed
Teratogenicity (MAK) : not listed
IARC classification : 3

11.3 Routes of exposure: ingestion, inhalation, eyes and skin

Caution! Substance is absorbed through the skin
11.4 Acute effects/symptoms:
- AFTER SKIN CONTACT
- Caustic burns/corrosion of the skin
- AFTER EYE CONTACT
- Corrosion of the eye tissue
11.5 Chronic effects:
- May cause sensitization by skin contact
- Contains substance with uncertain carcinogenic properties (phenol)
- No certainty about human mutagenic properties
- Not classified as toxic to reproduction (EC)
- ON CONTINUOUS/REPEATED EXPOSURE/CONTACT:
- Skin rash/inflammation

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12. Ecological information

12.1 Ecotoxicity:
2,4,6-tris(dimethylaminomethyl)phenol:
- LC50 (96 h) : 70.9 mg/l (PISCES)
- LC50 (48 h) : 41.3 mg/l (DAPHNIA MAGNA)
- EC50 ( h) : 10/100 mg/l (ALGAE)
phenol:
- LC50 (96 h) : 5/12 mg/l (SALMO GAIRDNERI/ ONCORHYNCHUS MYKISS)
- EC50 (48 h) : 6.6 mg/l (DAPHNIA MAGNA)
- EC50 (48 h) : >287 mg/l (SELENASTRUM CAPRICORNUTUM)
2-piperazin-1-ylethylamine:
- LC50 (96 h) : >=100 mg/l (SALMO GAIRDNERI/ ONCORHYNCHUS MYKISS)
- EC50 (48 h) : 32/58 mg/l (DAPHNIA MAGNA)
- EC50 (72 h) : 495 mg/l (SELENASTRUM CAPRICORNUTUM)
- Effect on waste water purification : no data available

12.2 Mobility:
- Volatile organic compounds (VOC): N.D.%
- Poorly soluble in water
For other physicochemical properties see heading 9

12.3 Persistence and degradability:

- biodegradation BOD5 : N.D. % ThOD
- water : - N.D.

- soil : T ½: N.D. days

12.4 Bioaccumulative potential:

- log Pow : N.D.
- BCF : N.D.
12.5 Results of PBT assessment:
- Not applicable, based on available data.
12.6 Other adverse effects:
- WGK : 2 (Classification based on the components in compliance
with Verwaltungsvorschrift wassergefährdender Stoffe
(VwVwS) of 17 May 1999)
- Effect on the ozone layer : Not dangerous for the ozone layer
(1999/45/EC)
- Greenhouse effect : no data available

13. Disposal considerations

13.1 Provisions relating to waste:

- Waste material code (91/689/EEC, Council Decision 2001/118/EC, O.J. L47 of
16/2/2001): 07 02 14* (wastes from additives containing dangerous
substances)
- Hazardous waste (91/689/EEC)

13.2 Disposal methods:

- Do not discharge into drains or the environment
- Dispose of at authorized waste collection point

13.3 Packaging/Container:
- Waste material code packaging (91/689/EEC, Council Decision 2001/118/EC,
O.J. L47 of 16/2/2001): 15 01 10* (packaging containing residues of or
contaminated by dangerous substances)

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14. Transport information

14.1 Classification of the substance in compliance with UN Recommendations

UN number : 2735
CLASS : 8
SUB RISKS : -
PACKING GROUP : III
14.2 ADR (transport by road)
CLASS : 8
PACKING GROUP : III
CLASSIFICATION CODE : C7
DANGER LABEL TANKS : 8
DANGER LABEL PACKAGES : 8
PROPER SHIPPING NAME :
Amines, liquid, corrosive, n.o.s.
(2-piperazin-1-ylethylamine, phenol)
14.3 RID (transport by rail)
CLASS : 8
PACKING GROUP : III
CLASSIFICATION CODE : C7
DANGER LABEL TANKS : 8
DANGER LABEL PACKAGES : 8
PROPER SHIPPING NAME :
Amines, liquid, corrosive, n.o.s.
(2-piperazin-1-ylethylamine, phenol)
14.4 ADNR (transport by inland waterways)
CLASS : 8
PACKING GROUP : III
CLASSIFICATION CODE : C7
DANGER LABEL TANKS : 8
DANGER LABEL PACKAGES : 8
14.5 IMDG (maritime transport)
CLASS : 8
SUB RISKS : -
PACKING GROUP : III
MFAG : -
EMS : F-A, S-B
MARINE POLLUTANT : -
14.6 ICAO (air transport)
CLASS : 8
SUB RISKS : -
PACKING GROUP : III
PACKING INSTRUCTIONS PASSENGER AIRCRAFT : 818/Y818
PACKING INSTRUCTIONS CARGO AIRCRAFT : 820
14.7 Special precautions : none
14.8 Limited quantities (LQ) :
When substances and their packaging meet the conditions established by
ADR/RID/ADNR in chapter 3.4, only the following prescriptions shall be
complied with:
each package shall display a diamond-shaped figure with the following
inscription:
- ‘UN 2735'
or, in the case of different goods with different identification numbers
within a single package:
- the letters 'LQ'

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15. Regulatory information

15.1 EU legislation:
Classification according to directives 67/548/EEC and 1999/45/EC

Corrosive

contains: formaldehyde, oligomeric reaction products with phenol and

triethylenetetramine; phenol; 2-piperazin-1-ylethylamine
R20/21/22 : Harmful by inhalation, in contact with skin and if
swallowed
R34 : Causes burns
R43 : May cause sensitisation by skin contact
R68 : Possible risk of irreversible effects

S(01/02) : (Keep locked up and out of reach of children)

S23 : Do not breathe vapour
S26 : In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice
S36/37/39 : Wear suitable protective clothing gloves, and eye/face
protection
S45 : In case of accident or if you feel unwell, seek medical
advice immediately (show the label where possible)

15.2 National provisions:

The Netherlands:
Waterbezwaarlijkheid: 9
Germany:
WGK : 2 (Classification based on the components in compliance
with Verwaltungsvorschrift wassergefährdender Stoffe
(VwVwS) of 17 May 1999)

16. Other information

Users are advised that they may have additional disclosure obligations under other national and local
laws. Users are advised to ensure that this information is brought to the attention of all employees,
agents, and contractors handling this product. Users of Berry Plastics BVBA products should make their
own evaluation to determine the suitability of each such product for the specific application and to
establish safe handling and installation procedures. Distributors of this product are advised to
forward this document, or the information contained herein, to every purchaser of this product.

Berry Plastics BVBA makes no warranties as to the accuracy or completeness of this information and
disclaims any liability in connection with its use. Berry Plastics BVBA obligations shall be only as
set forth in Berry Plastics BVBA standard terms and conditions of sale for this product. In no case
will Berry Plastics BVBA be liable for any incidental, indirect or consequential damages arising out
of the sale, resale, use or misuse of this product.

N.A. = NOT APPLICABLE

N.D. = NOT DETERMINED
(*) = INTERNAL CLASSIFICATION (NFPA)

PBT-substances = persistent, bioaccumulative and toxic substances

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Exposure limits:
TLV : Threshold Limit Value - ACGIH USA
WEL : Workplace Exposure Limits - United Kingdom
TRGS 900 : Technische Regel für Gefahrstoffe 900 (Arbeitsplatzgrenzwerte) - Germany
MAK : Maximale Arbeitsplatzkonzentrationen - Germany
MAC : Maximale aanvaarde concentratie - The Netherlands
VME : Valeurs limites de Moyenne d’Exposition - France
VLE : Valeurs limites d’Exposition à court terme - France
GWBB : Grenswaarde beroepsmatige blootstelling - Belgium
GWK : Grenswaarde kortstondige blootstelling - Belgium
EC : Indicative occupational exposure limit values - directive 2000/39/EC

Chronic toxicity:
K : List of the carcinogenic substances and processes - The Netherlands

Full text of any R phrases referred to under headings 2 and 3:

R21/22 : Harmful in contact with skin and if swallowed

R22 : Harmful if swallowed
R23/24/25 : Toxic by inhalation, in contact with skin and if swallowed
R34 : Causes burns
R36/38 : Irritating to eyes and skin
R38 : Irritating to skin
R41 : Risk of serious damage to eyes
R43 : May cause sensitisation by skin contact
R48/20/21/2 : Harmful: danger of serious damage to health by prolonged exposure through
inhalation, contact with skin and if swallowed
R52/53 : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment
R68 : Possible risk of irreversible effects

Printing date : 07-2009 9/9