TECHNOLOGICAL INSTITUTE OF THE PHILIPPINES- D.

between ions in aqueous solution is extremely rapid

MANILA because there are no bonds that need to be broken.

GENERAL CHEMISTRY CALCULATIONS 9. The decomposition of carbon disulfide, CS2, to carbon

monosulfide, CS, and sulfur is first order with k = 2.8 x 10-7 s-1
NAME:______________________DATE:______ at 1000oC. CS2 CS + S
What is the half-life of this reaction at 1000oC?
1. Which one of the following is incombustible ? A. 5.0 x 10+7 s b. 4.7 x 10-6 s
A.H2 B.CCl4 C. C2H2 D. S c. 3.8 x 10+5 s d. 2.5 x 10+6 s

2. Fog is an example of colloidal system of 10. Calculate the standard heat of formation, Hfo, for FeS2(s),
A. solid dispersed in gas. given the following information:
B. solid dispersed in liquid. 2FeS2(s) + 5O2(g) 2FeO(s) + 4SO2(g)
C. liquid dispersed in gas. Horxn = -1370 kJ
D. gas dispersed in liquid. Hfo for SO2(g) = -297 kJ/mol
Hfo for FeO(s) = -268 kJ/mol
3. __________ of air does not increase with increase in a. -177 kJ b. -1550 kJ c. -774 kJ d. -686 kJ
temperature.
A. Density B. Thermal diffusivity 11. The standard heat of combustion of ethanol, C2H5OH, is
C. Viscosity D. Thermal conductivity 1372 kJ/mol ethanol. How much heat (in kJ) would be liberated
by completely burning a 20.0 g sample?
4. Consider the equilibrium A(g) + B(g) = AB(g). When the A. 519 kJ B. 715 kJ C. 597 kJ D. 469 kJ
partial pressure of A is 10-2 atm, the partial pressure of B is 10-
3 atm and the partial pressure of AB is 1 atm, the equilibrium
constant 'K' is 12. What volume of 12.6 M HCl must be added to enough water
A. 10 atm-1 B. 105 atm-1 to prepare 5.00 liters of 3.00 M HCl?
C/ 10 (dimensionless) D.105 (dimensionless) A. 1.19 L b. 21.0 L c. 0.840 L d. 7.56 L

5. Which one of the following statements is TRUE? 13. How many equivalents of phosphoric acid are contained in
A. One mole of any acid will ionize completely in aqueous 300 mL of 4.00 M phosphoric acid? (Assume the acid is to be
solution to produce one mole of H+ ions. completely neutralized by a base.)
B. Solutions of weak acids always have lower a. 0.600 eq b.1.20 eq c. 2.40 eq d. 3.60 eq
concentrations of H+ than solutions of strong acids.
C. There are several common acids that are insoluble. 14. Consider the following unbalanced equation in acidic
D. All of the IA and IIA metal hydroxides are soluble. solution: NaClO3 + H2O + I2 HIO3 + NaCl

6. Which statement is false? A 25.0 mL sample of 0.0833 M NaClO3 reacted with 30.0 mL of
A. The density of a gas is constant as long as its an aqueous solution of I2. How many grams of I2 were
temperature remains constant. contained in the I2 solution?
B. Gases can be expanded without limit. a. 0.264 g b. 0.397 g c. 0.236 g d. 0.317 g
C. Gases diffuse into each other and mix almost immediately
when put into the same container. 15. Consider the following unbalanced net ionic equation:
D. The molecular weight of a gaseous compound is a non- NO2- + MnO4- NO3- + Mn2+
variable quantity. (in acidic solution)
What is the sum of all coefficients when the following net ionic
7. In a surprisingly large number of their properties beryllium equation is balanced using the smallest whole number
resembles aluminum, and boron resembles silicon. Such a coefficients possible? Do not forget coefficients of one.
relationship is called: MnO4- + Mn2+ MnO2
a. amphoterism b. an allotropic relationship (in basic solution)
c. a diagonal relationship d. the periodic law A. 19 b. 16 c. 13 d. 11

8. The speed of a chemical reaction
A. is constant no matter what the temperature is.
B. is independent of the amount of contact surface of a solid
involved.
C. between gases should in all cases be extremely rapid
because the average kinetic energy of the molecules is great.
16. A 0.580 g sample of a compound containing only carbon
and hydrogen contains 0.480 g of carbon and 0.100 g of
hydrogen. At STP, 33.6 mL of the gas has a mass of 0.087 g.
What is the molecular (true) formula for the compound?
a. CH3 b. C2H6 c. C2H5 d. C4H10
17. . What pressure (in atm) would be exerted by a mixture of 25. Calculate the amount of work done for the conversion of
1.4 g of nitrogen gas and 4.8 g of oxygen gas in a 200 mL 1.00 mole of Ni to Ni(CO)4 in the reaction below, at 75oC.
container at 57oC? Assume that the gases are ideal. The value of R is 8.31 J/molK.
a. 4.7 b. 34 c. 47 d. 27 Ni(s) + 4 CO (g) Ni(CO)4(g)
a. 1.80 x 103 J b. 8.68 x 103 J
18. A sample of hydrogen gas collected by displacement of c. -1.80 x 103 J d. -8.68 x 103 J
water occupied 30.0 mL at 24oC on a day when the barometric
pressure was 736 torr. What volume would the hydrogen 26. What is the standard entropy change of the reaction below
occupy if it were dry and at STP? The vapor pressure of water at 298 K with each compound at the standard pressure?
at 24.0oC is 22.4 torr.
a. 32.4 mL b. 21.6 mL c. 36.8 mL d. 25.9 mL N2(g) + 3H2(g) 2NH3(g)

19. If helium effuses through a porous barrier at a rate of 4.0 So298 (J/mol K) 191.5 130.6 192.3
moles per minute, at what rate (in moles per minute) would A. -198.7 J/K b. 76.32 J/K
oxygen gas diffuse? B. 303.2 J/K d. -129.7 J/K
a. 0.20 b. 0.50 c. 2.0 d. 1.41
27. For the following reaction at 25oC, Ho = +115 kJ and
20. What total gas volume (in liters) at 520oC and 880 torr So = +125 J/K. Calculate Go for the reaction at 25o.
would result from the decomposition of 33 g of potassium
bicarbonate according to the equation: SBr4(g) S(g) + 2Br2(l)
2KHCO3(s) K2CO3(s) + CO2(g) + H2O(g)
a. 56 L b. 37 L c. 10 L d. 19 L A. +152 kJ c. -56.7 kJ
B. +77.8 kJ d. +37.1 kJ
21. A 300 g sample of CaCO3 was heated until 10.0 L of CO2
was collected at 50.0oC and 742 torr. What percentage of the 28. The heat of vaporization of freon, CCl2F2, is 17.2 kJ/mol at
CaCO3 had decomposed? 25oC. What is the change of entropy for one mole of liquid freon
a. 6.84% b. 9.10% c. 12.3% d. 15.8% when it vaporizes at 25oC? (Hint: The vaporization process is at
equilibrium and what is true for G at equilibrium?)
22. A 5.000 g sample of methanol, CH3OH, was combusted in A. 57.7 J/K B. 0.688 J/K
the presence of excess oxygen in a bomb calorimeter conaining C. 5.13 x 103 kJ/K D. 3.16 J/K
4000 g of water. The temperature of the water increased from
24.000 oC to 29.765 oC. The heat capacity of the calorimeter 29. Estimate the boiling point of Br2(l) ( H = 30.9 kJ; S=
was 2657 J/oC. The specific heat of water is 4.184 J/goC. 93.0 J/K).
Calculate E for the reaction in kJ/mol.
a. -314 kJ/mol b. -789 kJ/mol Br2(l) Br2(g)
c. -716 kJ/mol d. -121 kJ/mol
A. 85oC B. 373oC C.177oC D. 59oC
23. A coffee cup calorimeter having a heat capacity of 451 J/oC
was used to measure the heat evolved when 0.0300 mol of 30. How much heat is absorbed in the complete reaction of 3.00
NaOH(s) was added to 1000 mL of 0.0300 M HNO3 initially at grams of SiO2 with excess carbon in the reaction below? Ho
23.000 oC. The temperature of the water rose to 23.639 oC. for the reaction is +624.7 kJ.
Calculate H (in kJ/mol NaNO3) for this reaction. Assume the
specific heat of the final solution is 4.18 J/goC; the density of SiO2(s) + 3C(s) SiC(s) + 2CO(g)
each solution is 1.00 g/mL; and the addition of solid does not
appreciably affect the volume of the solution. A. 366 kJ B. 1.13 x 105 kJ
HNO3(aq) + NaOH(s) NaNO3(aq) + H2O(l) C. 5.06 kJ D. 31.2 kJ
a. -63.7 kJ/mol b. -151 kJ/mol
c.-2.55 kJ/mol d. -98.6 kJ/mol

24. The Ho for the following reaction at 298 K is -36.4 kJ.

1/2 H2(g) + 1/2 Br2(l) HBr(g)
Calculate Eo at 298 K. The universal gas constant, R, is 8.314
J/mol K.
a. -35.2 kJ b. +35.2 kJ c. -36.4 kJ d. -37.6 kJ