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DPP-1
6..aExplain how much portion of an atom located at (i) corner and (ii)
bodycentreof a cubic unit cell is part of its neighbouring unit cell.
b. (i) What is meant by the term 'coordination number'?
c. What is the coordination number of atoms:
(i) in a cubic close-packed structure? (ii) in a body-centred cubic structure?
(iii).What is the two dimensional coordination number of a molecule insquare
close-packed layer?
d. A cubic solid is made of two elements P and Q. Atoms of Q are at the
corners of the cube and P at the body-centre. What is the formula of
the compound? What are the coordination numbers of P and Q?
5..aAn element has a body-centred cubic (bcc) structure with a cell edge of
288 pm. The density of the element is 7.2 g/cm3. How many atoms are
present in 208 g of the element?
b.X-ray diffraction studies show that copper crystallises in an fcc unit
cell with cell edge of 3.608×10-8 cm. In a separate experiment, copper is
determined to have a density of 8.92 g/cm3, calculate the atomic massof copper.
6.a.Silver forms ccplattice and X-ray studies of its crystals show that the
edge length of its unit cell is 408.6 pm. Calculate the density of silver
(Atomic mass = 107.9 u).
b.An element with molar mass 2.7×10-2 kg mol-1 forms a cubic unit cell
with edge length 405 pm. If its density is 2.7×103 kg-3, what is the
nature of the cubic unit cell?
c. Gold (atomic radius = 0.144 nm) crystallises in a face-centred unit cell.
What is the length of a side of the cell?
7..a.Aluminiumcrystallises in a cubic close-packed structure. Its metallic
radius is 125 pm.(i) What is the length of the side of the unit cell?
(ii) How many unit cells are there in 1.00 cm3 of aluminium?
b.Silver crystallises in fcc lattice. If edge length of the cell is 4.07 × 10 –
8
cm and density is 10.5 g cm–3, calculate the atomic mass of silver.
c.Niobiumcrystallises in body-centred cubic structure. If density is 8.55g
cm–3,calculate atomic radius of niobium using its atomic mass 93 u.
d.Copper crystallises into afcc lattice with edge length 3.61 × 10–8 cm.
Show that the calculated density is in agreement with its measuredvalue of
8.92 g cm–3.
1. Determine the type of cubic lattices to which the iron crystal belongs if
its unit cell has an edge length of 286 pm and the density of iron
crystals is 7, 86 g cm-3.
(Atomic mass of Fe = 56 g mol-1, NA = 6.02 X 1023 mol-1).
2. KX crystals have fcc structure. What is the distance between K+ and X-
in a KX crystal if the density of KX is 2.48 g cm-3 ? (Molar mass of
KX = 58 g mol-1, NA = 6.02 X 1023mol-1)
3. An element A crystallises in fcc structure. 200 g of this element has
4.12 x 1024 atoms. The density of A is 7.2 g cm-3. Calculate the edge
length of the unit cell.
4. Lithium metal crystal has a body centred cubic structure. Its density is
0.53 g cm-3 and its molar mass is 6.94 g mol-1. Calculate the volume
of a unit cell of lithium metal.
5. Sodium crystallises in the cubic lattice and the edge of the unit cell is
430 pm. Calculate the number of atoms in a unit cell. (At mass of Na =
23 amu, density of sodium = 0.9623 g cm-3, NA = 6.023 x 1023 mol-1
).
6. An element crystallises in a bcc structure. The edge length of its unit
cell is 288 pm. If the density of the crystal is 7.3 g cm-3, what is the
atomic mass of the element?
7. Chromium metal crystallizes with a body-centered cubic lattic. The
length of unit cell is found to be 287 pm. Calculate atomic radius, the
number of atoms per unit cell and the density of chromium.
(At. mass of Cr = 52 g mol-1 and NA = 6.02 x 1023 mol-1).
8. Br- ions form close packed structure. If the radius of Br- ion is 195 pm,
calculate the radius of the cation that just fits in the tetrahedral hole.
Can a cation A+ having a radius of 82 pm be slipped into the octahedral
hole of the crystal A+ Br- ?
9. Caesium chloride crystallises as a body centred cubic lattice and has a
density of 4.0
g cm -3. Calculate the length of the edge of the unit cell of caesium
chloride crystal.
[Molar mass of CsCI = 168.5 g mol-1 NA = 6.02 x 1023 mol-1]
10. The ionic radius of CI- ion is 181 pm. Consider the closest packed
structure in which all anions are just touching.
(i) Calculate the radius of the cation that just fits into the octahedral
holes of this lattice of anions.
(ii) Calculate the radius of the cation that just fits into the tetrahedral
holes of this lattice of anions.
11. Calculate the value of the Avogadro constant from the following data:
Density of
NaCl = 2.165 g cm-3 Distance between Na + and Cl- ion NaCl = 281
pm
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TOPIC: SOLID STATE
HOTS QUESTIONS
1.a) What type of crystal system is with cell dimensions a = 0.328 nm, b =
0.328 nm, c = 0.527 nm ?
b) Urea has a sharp melting point but glass does not Explain.
c) A metallic crystal has the bcc type packing pattern. What percentage of
volume of this lattice is empty space ?
2.a) The metal calcium crystallises in a face centred cubic unit cell with a =
0.556 nm. Calculate the density of the metal if
(i) it contains 0.2% Frenkel defects. (ii) it contains 0.1% Schottky
defects
c) In the mineral, "spinel" having the formula MgAl2O4, oxide ions are
arranged in the cubic close packing, Mg2+ ions occupy tetrahedral
voids while Al3+ ions occupy the octahedral voids.
(i) What percentage of tetrahderal voids is occupied by Mg2+ions ?
(ii) What percentage of octahedral voids is occupied by Al3+ions ?
3a) A metal crystallizes into two cubic phases, face-centred cubic (FCC)
and body-centred cubic (BCC) whose unit cell lengths are and
respectively. Calculate the ratio of the densities of FCC and BCC.
4 a) A unit cell consists of a cube in which there are A atoms at the corners
and B atoms at the face centres. Two A atoms are missing from the two
corners of the unit cell. What is the formula of the compound?
b) Name the transition metal oxide which has appearance and conductivity
like that of copper.
c) In a cubic close packed structure of mixed oxides, the lattice is made of
oxide ions, one eighth of tetrahedral voids are occupied by divalent ions
(A2+) while one half of the octahedral voids are occupied by trivalent
ions (B3+). What is the formula of the oxide?
Contextual Question:-
Value Points:-
Organized Behaviour leads to stability.
High Efficiency
Mental Calmer/Satisfaction
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