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ADVANCED FOUNDATION - CHEMISTRY KEY AND SOLUTIONS

AIMS
CHEMISTRY
IIT-JEE, NEET & OLYMPIADS
ADVANCED FOUNDATION

KEY
&
SOLUTIONS
VI to X CLASS

R & D CONTACT NUMBER:

7995745189

AIMS OLYMPIAD ACADEMY


KEY AND SOLUTIONS ADVANCED FOUNDATION - CHEMISTRY

AIMS OLYMPIAD ACADEMY


CHEMISTRY
ADVANCED FOUNDATION COURSE
IIT-JEE/NEET EXAMINATION CALENDAR FOR 2018-19
TEST NAME TEST DATE VI CLASS VII CLASS VIII CLASS IX CLASS

IIT-JEE/NEET IMPORTANCE OF LANGUAGE OF ATOMIC ATOMIC


14 – 07 – 2018
TEST 01 CHEMISTRY CHEMISTRY STRUCTURE STRUCTURE
PHYSICAL AND
IIT-JEE/NEET NATURE OF CLASSIFICATION CLASSIFICATION
04 – 08 – 2018 CHEMICAL
TEST 02 MATTER OF ELEMENTS OF ELEMENTS
CHANGES
CHEMICAL
IIT-JEE/NEET CHEMICAL CHEMICAL
25 – 08 – 2018 MIXTURES REACTIONS AND
TEST 03 BOND BOND
EQUATIONS
IIT-JEE/NEET
CUMULATIVE 29 – 09 – 2018 Chapters – 1 to 3 Chapters – 1 to 3 Chapters – 1 to 3 Chapters – 1 to 3
TEST 01
MOLE CONCEPT
IIT-JEE/NEET SYMBOLS AND AIR AND ITS HYDROGEN AND
10 – 11 – 2018 &
TEST 04 FORMULAE CONSTITUENTS OXYGEN
STOICHIOMETRY
IIT-JEE/NEET CHANGES WATER AND ITS CARBON AND BEHAVIOUR OF
24 – 11 – 2018
TEST 05 AROUND US CONSTITUENTS NITROGEN GASES
IIT-JEE/NEET ACIDS, BASES METALS AND ORGANIC
15 – 12 – 2018 WATER
TEST 06 AND SALTS NON METALS CHEMISTRY
IIT-JEE/NEET
CUMULATIVE 22 – 12 – 2018 Chapters – 4 to 6 Chapters – 4 to 6 Chapters – 4 to 6 Chapters – 4 to 6
TEST 02
LAWS OF
IIT-JEE/NEET INTRODUCTION STURCTURE OF
02 – 02 – 2019 CHEMICAL SOLUTIONS
TEST 07 OF ATOM ATOM
COMBINATION
IIT-JEE/NEET ELEMENTS AND CLASSIFICATION NUCLEAR CHEMICAL
16 – 02 – 2019
TEST 08 CLASSIFICATION OF ELEMENTS CHEMISTRY KINETICS
IIT-JEE/NEET
CUMULATIVE 09 – 03 – 2019 Chapters – 7 to 8 Chapters – 7 to 8 Chapters – 7 to 8 Chapters – 7 to 8
TEST 03
IIT-JEE/NEET TOTAL TOTAL TOTAL TOTAL
16 – 03 – 2019
GRAND TEST SYLLABUS SYLLABUS SYLLABUS SYLLABUS
Note :
Exam dates are flexible. After the Completion of syllabus at your
convenient date you can conduct the exams. But after completing the
exams please send the OMR sheets to the AIMS CENTRAL OFFICE. So
that you can announce the results within 48 hours.
ADVANCED FOUNDATION - CHEMISTRY VI - KEY AND SOLUTIONS

AIMS
CHEMISTRY
IIT-JEE, NEET & OLYMPIADS
ADVANCED FOUNDATION

VI CLASS
KEY
&
SOLUTIONS

AIMS OLYMPIAD ACADEMY


VI-CHEMISTRY IMPORTANCE OF CHEMISTRY IN OUR DAILY LIFE
VI CHEMISTRY

1 IMPORTANCE OF CHEMISTRY

19. A, B, C

20. A, C, D

COMPREHENSION PASSAGE TYPE (C.P.T.):


1. C
21. B
2. A
22. C
3. B
23. D
4. D

5. B MATRIX MATCHING TYPE (M.M.T.):

6. A 24. B

SINGLE CORRECT ANSWER TYPE (S.C.A.T.): 25. C

7. C 26. A

8. B 27. D

9. C

10. C

11. B

12. A
28. A
13. D

14. D
29. A
15. D

16. A
30. 5
17. C

31. D

32. B
MULTI CORRECT ANSWER TYPE (M.C.A.T.):
33. C
18. A, B, C, D

AIMS OLYMPIAD ACADEMY 1


NATURE OF MATTER VI-ADVANCED-CHEMISTRY
VI CHEMISTRY

2 NATURE OF MATTER
MATRIX MATCHING TYPE (M.M.T.):
37. A, D 38. B
39. A, D 40. C

1. C 2. A

3. A 4. C

5. C 6. A

7. D 8. C 41. 5 42. 4
9. B 10. B

11. A 12. B 43. B 44. D


13. C 45. B 46. B

SINGLE CORRECT ANSWER TYPE (S.C.A.T.): 47. A 48. B

14. C 15. D 49. A 50. A

16. C 17. A 51. D

18. D 19. A

20. D 21. C 52. A

22. A 23. A

24. C 25. C ACROSS: ()


3. MATTER

4. ATOM

7. IODINE
MULTI CORRECT ANSWER TYPE (M.C.A.T.):
8. GASEOUS
26. A & B 27. A, B, C & D
9. FREEZING
28. A & C 29. A & C
DOWN: ()
30. B & C 31. A, B & D
1. PLAZMA
32. B & C 33. B, C & D
2. MELTING
COMPREHENSION PASSAGE TYPE (C.P.T.):
5. MOLECULE
34. A 35. C 36. B 6. LIQUID

2 AIMS OLYMPIAD ACADEMY


VI-CHEMISTRY MIXTURES AND SEPARATION TECHNIQUES
VI CHEMISTRY

3 MIXTURES & SEPARATION TECHNIQUES

49. C
50. B
Sol: Air flow is not needed for threshing
1. B 2. D 3. C and sieving.
4. B 5. B 6. A 51. B
7. C 8. B 9. D Sol: First iron particles (Z) are separated
10. A 11. C 12. B by magnetic separation method.
SINGLE CORRECT ANSWER TYPE (S.C.A.T.): Light weight particles (Y) can be
13. D 14. C 15. A separated from heavy particles (X) by
winnowing method.
16. B 17. C 18. A
52. B
19. A 20. A 21. B
Sol: Sugar dissolves in water completely
22. C 23. D 24. D
and forms a transparent solution.
25. B 26. D
53. D
Sol: When the mixture of chalk power,
sugar and water is filtered, chalk
powder is separated as residue.
MULTI CORRECT ANSWER TYPE (M.C.A.T.): If the remaining sugar solution is
29. A & C 30. A, B & C distilled, sugar will be leftover and pure
29. B & C 30. C & D water is collected separately.
31. B & C 32. A, C & D Hence: Q is Chalk powder.
33. A & C P is Sugar solution.

COMPREHENSION PASSAGE TYPE (C.P.T.): R is Sugar.

34. B 35. C 36. C


ACROSS: ()
MATRIX MATCHING TYPE (M.M.T.):
2. MAGNET
37. B 38. A, D
5. FILTRATE
39. E 40. C
6. PURE
41. C, D 42. A, E
7. HETEROGENEOUS
43. C, D 44. B, E
8. WINNOWING
9. SEDIMENT
DOWN: ()
1. MIXTURE
45. A 46. A 3. THRESHING
4. HOMOGENEOUS

47. A 48. B

AIMS OLYMPIAD ACADEMY 3


SYMBOLS AND FORMULAE VI-ADVANCED-CHEMISTRY
VI CHEMISTRY

4 SYMBOLS AND FORMULAE


23. A

24. B

Sol: Potassium nitrate KNO3


1. D 2. D
Sulphate SO 4–2
3. A 4. A
Sodium chloride NaCl
5. C 6. A
Hydrogen peroxideH2O 2
7. D 8. A
25. D
9. B 10. C

11. A 12. A

SINGLE CORRECT ANSWER TYPE (S.C.A.T.):

13. B MULTI CORRECT ANSWER TYPE (M.C.A.T.):

Sol: Sodium chloride = NaCl 26. A, B & C

Hydragyrum = Hg Sol: All metals show mono atomicity

Carbon dioxide = CO2 Ozone (O3) is triatomic.


Ammonia = NH3
27. A, B & C
14. A 15. A
Sol: Compound Valency of metal
16. A 17. A
MgH2 2
18. D
BaH2 2
Sol: Element Formula Atomicity
CaH2 2
Sodium Na 1
NaH 1
Magnesium Mg 2
28. A, B & C
Phosphorous P4 4

Oxygen O2 2 Sol: Latin name of Mercury is Hydragyrum

19. B 20. A 29. B, C & D

21. D 22. D 30. A & B

4 AIMS OLYMPIAD ACADEMY


VI-ADVANCED-CHEMISTRY SYMBOLS AND FORMULAE
Sol: Ion Formula DOWN: ()

Oxide O –2 1. COPPER

Sulhide SO –2 2. ANTIMONEY

Nitride N –3 3. LEAD

Bromide Br– 6. GOLD

31. A, B & C 8. TIN

COMPREHENSION PASSAGE TYPE (C.P.T.):

32. C 33. B 34. C

MATRIX MATCHING TYPE (M.M.T.):

35. D 36. E

37. B 38. A

39. C 40. D

41. A 42. B, E

43. A 44. A

45. A 46. A

ACROSS: ()

4. IRON

5. TUNGSTEN

7. POTASSIUM

9. SILVER

10. SODIUM

11. MERCURY

AIMS OLYMPIAD ACADEMY 5


CHANGES AROUND US VI-ADVANCED-CHEMISTRY
VI CHEMISTRY

5 CHANGES AROUND US

COMPREHENSION PASSAGE TYPE (C.P.T.):


37. B 38. A 39. B

MATRIX MATCHING TYPE (M.M.T.):


1. C 2. D
40. B, D 41. A, C
3. A 4. D
42. A 43. B
5. B 6. A

7. B 8. C

9. A 10. D

11. C 12. A
44. A 45. B
13. A 14. A

SINGLE CORRECT ANSWER TYPE (S.C.A.T.):


46. D 47. B
15. A 16. D

17. C 18. D
48. B 49. D
19. D 20. B

21. B 22. B
ACROSS: ()
23. B 24. D
6. SLOW
25. A 26. B
8. IRREVERSIBLE
27. D 28. C
9. PERIODIC
29. C 30. B 10. CHEMICAL
31. A DOWN: ()

1. REVERSIBLE

2. ENDOTHERMIC

3. NONPERIODIC
MULTI CORRECT ANSWER TYPE (M.C.A.T.):
4. FAST
32. B & C 33. A, B & C
5. EXOTHERMIC
34. A & D 35. A, B & D
7. PHYSICAL
36. A, C & D

6 AIMS OLYMPIAD ACADEMY


VI-ADVANCED-CHEMISTRY WATER
VI CHEMISTRY

6 WATER

1. D 2. D 43. A 44. A
3. C 4. B 45. A 46. C
5. B 6. B
7. C 8. A 47. A 48. B
9. A 10. A
11. A 49. A

SINGLE CORRECT ANSWER TYPE (S.C.A.T.): Note: Please inform the students to observe
the following diagram missing in the
12. C 13. A question.
14. B 15. C
16. A 17. C
18. B 19. D
20. A 21. D
22. C 23. C
24. B 25. C

50. D
51. C
MULTI CORRECT ANSWER TYPE (M.C.A.T.):
26. A, B & C 27. A, B & C ACROSS: ()
28. A, B, C & D 29. C & D 2. COLOURLESS
30. A, C & D 31. A, B & C 8. LITERS
32. A, B & D 9. MELTING
10. BOILING
COMPREHENSION PASSAGE TYPE (C.P.T.):
DOWN: ()
33. D 34. C
1. BOILING
35. A 36. A
3. UNIVERSAL
37. A 38. B 4. SOFTENING
MATRIX MATCHING TYPE (M.M.T.): 5. WATER
39. B, D 40. C, E 6. SOFT
41. C, D 42. A 7. HARD

AIMS OLYMPIAD ACADEMY 7


INTRODUCTION OF ATOM VI-ADVANCED-CHEMISTRY
VI CHEMISTRY

7 INTRODUCTION OF ATOM
MATRIX MATCHING TYPE (M.M.T.):

28. C 29. D

30. A 31. B, E

1. B 2. D

3. C 4. B

5. B 6. C

7. D 8. C 32. A 33. C

9. D 10. B 34. A

11. B

SINGLE CORRECT ANSWER TYPE (S.C.A.T.): 35. B 36. C

12. A 13. B 37. A 38. A

14. B 15. C 39. B

16. C 17. B

18. B 19. C ACROSS: ()

20. A & B (MULTI) 3. ELECTRON

5. KANAD

6. ISOTOPES

MULTI CORRECT ANSWER TYPE (M.C.A.T.): 7. PROTON

21. A, B & D 22. C (SINGLE) 8. NEUTRON

23. A, C & D 24. A & B DOWN: ()

COMPREHENSION PASSAGE TYPE (C.P.T.): 1. ISOBARS

25. C 26. C 2. GOLDSTEIN

27. A 4. THOMSON
8 AIMS OLYMPIAD ACADEMY
VI-ADVANCED-CHEMISTRY ELEMENTS AND THEIR CLASSIFICATION
VI CHEMISTRY

8 ELEMENTS & THEIR CLASSIFICATION

1. C 2. C
31. C 32. C
3. A 4. A

5. B 6. B
33. 3 34. 7
7. D 8. C

9. A

SINGLE CORRECT ANSWER TYPE (S.C.A.T.): 35. D (OUT OF) 36. A

10. C 11. C 37. C 38. B

12. B 13. B 39. C

14. C 15. D Note: Please change option C) as IA, VIIA.

16. C 17. B

18. A 19. C
ACROSS: ()
20. D
3. SILICON

6. NEWLAND

7. LAVOISIER
MULTI CORRECT ANSWER TYPE (M.C.A.T.): 8. ELEMENT
21. A, B & C 22. A, B & C DOWN: ()
23. A, C & D
1. SCANDIUM
COMPREHENSION PASSAGE TYPE (C.P.T.): 2. TRIADS
24. B 25. A
4. SODIUM
26. C
5. WEIGHTS
MATRIX MATCHING TYPE (M.M.T.):

27. B 28. D

29. C 30. A
AIMS OLYMPIAD ACADEMY 9
ADVANCED FOUNDATION - CHEMISTRY VII - KEY AND SOLUTIONS

AIMS
CHEMISTRY
IIT-JEE, NEET & OLYMPIADS
ADVANCED FOUNDATION

VII CLASS
KEY
&
SOLUTIONS

AIMS OLYMPIAD ACADEMY


VII-CHEMISTRY LANGUAGE OF CHEMISTRY
VII CHEMISTRY

1 LANGUAGE OF CHEMISTRY

Sol: MgO is diatomic


16. B
Sol: Mg (+2), Cl(-1)
1. C 17. C
2. B Sol: Fe (+3), Cl(-1)
3. D 18. A
4. B Sol: Phosphorous is trivalent (P–3)
5. A 19. B
6. A 20. C
7. D 21. C
Sol: Nitride = N = Trivalent
–3
22. A
Phosphate = P = Trivalent
–3
Sol: Cu (+2), O(-2)
Chloride = Cl –1
= Monovalent 23. C
Sulphate = SO4–2 = Bivalent 24. A
8. C 25. D
9. A
Sol: Na+
10. A
11. B MULTI CORRECT ANSWER TYPE (M.C.A.T.):
Sol: Hydrogen = H2 = Diatomic 26. A, C, D

Helium = He = Monoatomic Sol: Oxygen (O–2)

Ozone = O3 = Triatomic Sodium (Na+)

Oxygen = O2 = Diatomic Magnesium (Mg+2)

SINGLE CORRECT ANSWER TYPE (S.C.A.T.): Calcium (Ca+2)

12. D 27. A, B, C, D

Sol: Ozone = O3 = Triatomic 28. A, B, C

13. D Sol: Nitrogen N2

14. C Hydrogen H2

Sol: Copper can exhibit two valencies 1 Phosphorous P4


and 2. Oxygen O2
15. C
AIMS OLYMPIAD ACADEMY 1
LANGUAGE OF CHEMISTRY VII-CHEMISTRY
COMPREHENSION PASSAGE TYPE (C.P.T.): 2) 2
3) 3
29. B
4) 1
30. A
5) 4
Sol: NH3
6) 3
31. D
49. 1) HCl
Sol: For l = 0, possible m value is 0 but not –1.
2) Na
MATRIX MATCHING TYPE (M.M.T.):
3) Mg
32. C
4) O2
33. D
5) Al
34. B
6) O3
35. A
Sol: P

50. A
51. A

36. 2
Sol: H 2 S 52. A
37. 4
Sol: MgSO 4 ACROSS: ()
38. 2 3. CALCIUMOXIDE
Sol: Ca (+2), O(–2) 5. SODIUMSULPHATE
6. NITROGENDIOXIDE

39. A 7. NITRICACID

40. B 8. FERROUSCHLORIDE

41. A DOWN: ()

42. D 1. AMMONIA

43. C 2. CALCIUMHYDROXIDE

44. A 4. LITHIUMNITRIDE

45. A
46. A
47. C
Sol: Al2SO 4
48. 1) 2

2 AIMS OLYMPIAD ACADEMY


VII-ADVANCED-CHEMISTRY PHYSICAL AND CHEMICAL CHANGES
VII CHEMISTRY

2 PHYSICAL & CHEMICAL CHANGES

20. B

21. A

1. B

2. A
MULTI CORRECT ANSWER TYPE (M.C.A.T.):
3. A
22. A, B & C
4. C
23. A, B & C
5. B
24. A, B & D
6. C
25. A, B & C
7. D
26. A, B & C
8. A
27. A, B & C
9. A
COMPREHENSION PASSAGE TYPE (C.P.T.):
10. B
28. D
SINGLE CORRECT ANSWER TYPE (S.C.A.T.):
29. D
11. A
30. D
12. D

13. A MATRIX MATCHING TYPE (M.M.T.):

14. D 31. A, B, D

15. B 32. D, E

Sol: When candle is heated in a vessel, it 33. A, D


will melt and form liquid wax which is
34. C, D
a physical change.
35. A, D
16. A
36. A, C
17. B
37. A, D
18. C
38. B, C, E
19. A
AIMS OLYMPIAD ACADEMY 3
PHYSICAL AND CHEMICAL CHANGES VII-ADVANCED-CHEMISTRY
5. IRREREVERSIBLE

6. PHYSICAL

7. PERMANENT

DOWN: ()
39. A
1. REVERSIBLE
40. C
2. CHEMICIAL
41. A
3. OXYGEN

42. D

43. A

44. D

45. A

Sol: After few days eggs will be spoiled


(Chemical change), Plastic bottle will
be remained same (no change) and
Moth balls will be sublimated (Physical
change).

46. B

47. A

Sol: In photosynthesis process, solar light


energy is absorbed by plants and food
is prepared.

48. C

Sol: No change in mass occurs during


physical change.

49. C

50. C

ACROSS: ()

4. YELLOW

4 AIMS OLYMPIAD ACADEMY


VII-ADVANCED-CHEMISTRY PHYSICAL AND CHEMICAL CHANGES
VII CHEMISTRY

3 CHEMICAL REACTIONS & EQUATIONS

25. A

26. D
Sol: HNO3 is reduced and I2 is oxidised.

1. D 2. B 3. A 27. C

4. D 5. C 6. A 28. A

7. B 8. A 9. B Sol: A) Water and calcium oxide both are


compounds.
SINGLE CORRECT ANSWER TYPE (S.C.A.T.):
B) Iodine and white phosphorous both
10. B are elements.
Note: Please change the option D) as: C) Iron and suphur both are elements.
Al2(CO3)3  Al2O3 + CO2 D) In electrolysis only the compound
11. C 12. B 13. A water is decomposed.

14. B 15. C 16. B

17. B
18. D
MULTI CORRECT ANSWER TYPE (M.C.A.T.):
Sol: H2S is losing hydrogens hence it is
oxidised and it is reducing agent. 29. A, B & C

Cl is gaining hydrogens hence it is Sol: Mg + 2H2O  Mg(OH)2 + H2


reuced and it is oxidising agent.
30. B & D
19. C
31. B
20. A
32. C & D
21. A
Sol: ZnO is losing oxygens hence reduced.
Note: Please change the equation as:

2Pb(NO3)2  2Pb + nA + 2O2 CO is gaining oxygen hence oxidised.

Sol: The ballanced chemical equation is: COMPREHENSION PASSAGE TYPE (C.P.T.):
2Pb(NO3)2  2Pb + 4NO2 + 2O2 33. C
22. C
34. D
23. A
35. C
24. B

AIMS OLYMPIAD ACADEMY 5


PHYSICAL AND CHEMICAL CHANGES VII-ADVANCED-CHEMISTRY
MATRIX MATCHING TYPE (M.M.T.): DOWN: ()

36. D 1. REACTION

37. B 2. CORROSION

38. C 3. DISPLACEMENT

4. EQUATION
39. A
6. PRODUCT

8. REDOX

40. C

Sol: The speed of the reaction we cannot


identify from the balanced equation.

41. C

42. A

Sol: The chemical equation representing


the formation of rust is:

Fe + O2 + xH2O  Fe2O3.xH2O (rust)

43. D

44. A

Note: Please change the equation as:

aFe + bH2O  Fe3O4 + 4H2

Sol: The ballanced chemical equation is:

3Fe + 4H2O  Fe3O4 + 4H2

ACROSS: ()

5. REACTANTS

7. COMBINATION

9. DECOMPOSITION

6 AIMS OLYMPIAD ACADEMY


VII-ADVANCED-CHEMISTRY AIR AND ITS CONSTITUENTS
VII CHEMISTRY

4 AIR AND ITS CONSTITUENTS

44. C
Sol: Carbon dioxide is non-poisionous but
people feel suffocation in the
1. C 2. B 3. A
atmosphere of crbon dioxide because
4. A 5. B 6. C of lack of oxygen.
7. A 8. B 9. A
10. B 11. A 12. D
45. A
13. C 14. D 15. D
SINGLE CORRECT ANSWER TYPE (S.C.A.T.):
46. C 47. A 48. C
16. D 17. B 18. B
19. B 20. D 21. C 49. A 50. A

22. A 23. C 24. D 51. A

25. A 26. B 27. D Sol: X : Carbon dioxide


28. C 29. C Y : Oxygen
Z : Nitrogen
Exhaled air will have more carbon
dioxide, less oxygen and same amount
MULTI CORRECT ANSWER TYPE (M.C.A.T.): of nitrogen.
30. A, B & C 31. B & D 52. A
32. A, B & D 33. A, C & D
34. A, B, C & D 35. A & B
ACROSS: ()
COMPREHENSION PASSAGE TYPE (C.P.T.): 3. ACIDRAIN
36. B 37. C 38. D 4. BASIC
MATRIX MATCHING TYPE (M.M.T.): 5. OZONE
39. D 40. A
7. NITROGEN
41. C 42. B
DOWN: ()
1. MIXTURE
2. CARBONIC
3. ACIDIC
43. C 5. OXYGEN
Sol: Nitrogen is insoluble in water. 6. ARGON

AIMS OLYMPIAD ACADEMY 7


WATER VII-ADVANCED-CHEMISTRY

VII CHEMISTRY

5 WATER

1. D 2. A 3. D 36. C 37. D

4. D 5. B 6. A

7. D 8. A 9. B 38. A

39. A
10. D
Sol: When oil flowtes on water and covers
SINGLE CORRECT ANSWER TYPE (S.C.A.T.): like a blanket, oxygen from
atomosphere cannot dissolve into
11. B 12. D 13. C
water. So, aquatic animals will because
14. A 15. C 16. B of no oxygen dissolved. Hence, oil
spilled into water can be poison for
17. A 18. C 19. C aquatic life.

20. C 21. A 22. C

23. C 40. D 41. B 42. D

43. D 44. B

ACROSS: ()
MULTI CORRECT ANSWER TYPE (M.C.A.T.):
1. ICE
24. B, C & D 25. A, B & D
3. BOILING
26. A, B & C 27. A, B & C
6. DISTILLED
28. A, B & D 9. FREEZING

COMPREHENSION PASSAGE TYPE (C.P.T.): DOWN: ()

29. D 30. D 31. D 2. CHLORINATION

4. BOILING
MATRIX MATCHING TYPE (M.M.T.):
5. HARD
32. E 33. B
7. WATER
34. A, C 35. D
8. SOFT

8 AIMS OLYMPIAD ACADEMY


VII-ADVANCED-CHEMISTRY ACIDS, BASES AND SALTS
VII CHEMISTRY

6 ACIDS, BASES AND SALTS

17. B

Sol: H 3PO 4  3H   PO 43

18. C
1. A
19. B
2. B
Sol: For example:
3. C CaCO3  2HCl  CaCl2  CO2  H 2O
4. B 20. B

5. C 21. D

6. D Sol: Mg  2HCl  MgCl 2  H 2

7. D 22. A

8. C 23. D

9. A 24. A

10. D 25. A

11. B 26. B

12. A 27. C

13. A 28. B

SINGLE CORRECT ANSWER TYPE (S.C.A.T.):

14. C

Sol: For example: MULTI CORRECT ANSWER TYPE (M.C.A.T.):


NaHCO 3  dil .HCl  NaCl  CO2  H 2O
29. A & B
15. D
30. A & C
Sol: Potassium, Zinc and Magnesium are
metals and they produce basic oxides. 31. B & C
Sulphur is a non-metal and it produces
32. A, B & D
acidic oxides (SO2 & SO3).
33. A, B & D
16. D
34. A, B & D
AIMS OLYMPIAD ACADEMY 9
ACIDS, BASES AND SALTS VII-ADVANCED-CHEMISTRY
COMPREHENSION PASSAGE TYPE (C.P.T.): 48. B

35. D

36. B ACROSS: ()

37. B 4. NEUTRALISATION

MATRIX MATCHING TYPE (M.M.T.): 5. LACTIC

38. D 6. INDICATOR

39. A 7. STRONGBASES

40. B 8. POTASHALUM

DOWN: ()
41. C, E
1. VINEGAR

2. BLUEVITRIOL

3. SALT

42. C

Sol: H2SO4 is a dibasic acid and H3PO4 is a


tribasic acid.

43. A

44. D

45. A

Sol: Formic acid released by ant will be


neutralised by sodium carbonate.

46. B

Sol: When blue litmus is dipped in dilute


Hydrochloric acid, it turns red.

This red litmus when dipped in dilute


Sodium hydroxide solution, it turns
blue.

47. A

10 AIMS OLYMPIAD ACADEMY


VII-ADVANCED-CHEMISTRY STRUCTURE OF ATOM
VII CHEMISTRY

7 STRUCTURE OF ATOM

1. A 2. C 3. B
41. A 42. A
4. B 5. C 6. A

7. C 8. B 9. D
43. B
10. A 11. A 12. C

13. C
44. A
SINGLE CORRECT ANSWER TYPE (S.C.A.T.):
Sol: Most of the alpha particles move
14. C 15. C 16. B
through the gold foil straight with out
17. A 18. C 19. B any deviation.

20. B 21. A 22. A 45. A 46. A

23. B 24. D 25. D 47. B

26. C Sol: Size of the orbit increases as we move


away from the nucleus.

(K < L < M < N < ...)

MULTI CORRECT ANSWER TYPE (M.C.A.T.): ACROSS: ()


27. A & B 28. A, B & C 3. NEUTRAL
29. A, B & C 30. A, B & D 4. ISOTONES
31. A, B & C 32. A & D 5. TWO
33. B, C & D 6. POSITIVE
COMPREHENSION PASSAGE TYPE (C.P.T.): 7. THREE

34. A 35. C 36. D DOWN: ()

MATRIX MATCHING TYPE (M.M.T.): 1. THOMSON

37. C 38. A, E 2. ISOTOPES

39. B 40. D 3. NEGATIVE


AIMS OLYMPIAD ACADEMY 11
CLASSIFICATION OF ELEMENTS VII-ADVANCED-CHEMISTRY
VII CHEMISTRY

8 CLASSIFICATION OF ELEMENTS

MATRIX MATCHING TYPE (M.M.T.):

32. B 33. D

34. E 35. A, C
1. C 2. A

3. A 4. C

5. D 6. B

7. B 8. A
36. A
9. D 10. B

SINGLE CORRECT ANSWER TYPE (S.C.A.T.):


38. B
11. B 12. D

13. C 14. B
39. D 40. B
15. C 16. A
41. C 42. A
17. A 18. A
43. C 44. D
19. C 20. C
45. B
21. D 22. A

23. C 24. D
ACROSS: ()

3. SODIUM

5. POTASSIUM
MULTI CORRECT ANSWER TYPE (M.C.A.T.):
6. CHLORINE
25. C 26. A, B & C
DOWN: ()
27. A, B, C & D 28. A, B & C
1. HYDROGEN
COMPREHENSION PASSAGE TYPE (C.P.T.):
2. ALUMINIUM
29. C 30. D 31. C
4. CARBON

12 AIMS OLYMPIAD ACADEMY


ADVANCED FOUNDATION - CHEMISTRY VIII - KEY AND SOLUTIONS

AIMS
CHEMISTRY
IIT-JEE, NEET & OLYMPIADS
ADVANCED FOUNDATION

VIII CLASS
KEY
&
SOLUTIONS

AIMS OLYMPIAD ACADEMY


VIII-CHEMISTRY ATOMIC STRUCTURE
VIII CHEMISTRY

1 ATOMIC STRUCTURE
Mass number = 56
No. neutrons
= Mass number - Atomic number

1. B = 56 - 26 = 30
2. D 22. C
3. B 23. B
4. D Sol: The species with same number of
5. C electrons are called isoelectonics.
6. D 24. B
7. C Sol: The atoms with same mass number
Sol: Tritium (1H3) is the radioactive isotope but different atomic numbers are called
of hydrogen. It has 1 electron, 1 proton isobars.
and 2 neutrons. 25. B
8. D
26. A
Sol: Atoms with same atomic number but
different mass numbers are called 27. B
isotopes. 28. B
9. C Sol: (E1–E2) > (E2–E3) > (E3–E4) > (E4–E5) ...
10. D
29. A
11. B
c 3  108
12. B Sol:    10
 6.25  1014 s 1
 4800 10
13. B
30. B
14. C
Sol: E  h  6.625  1034  3  1015
15. B
 19.87  10 19 J  1.987  10 18 J
SINGLE CORRECT ANSWER TYPE (S.C.A.T.):
31. D
16. C
17. B
18. B
19. C
MULTI CORRECT ANSWER TYPE (M.C.A.T.):
20. D
32. B, D
21. B
Sol: No. of electrons = No. of protons 33. A, B, C, D
= Atomic number = 26 34. B, C, D

AIMS OLYMPIAD ACADEMY 1


ATOMIC STRUCTURE VIII-CHEMISTRY
35. A, B, C

Sol: The radiations with greater frequency 48. B


are more energetic.
49. C
36. B, C, D 50. B
37. A, C, D Sol: Mass number A = 27
Sol: Bohr’s theory is applicable only for Number of neutrons n = 14
single electron species. Atomic number Z = A – n
38. A, B, C, D = 27 – 14 = 13
Hence the number of electrons in the
COMPREHENSION PASSAGE TYPE (C.P.T.): neutral atom = 13
39. D The number of electrons in the ion with
3 positive charges =13 – 3 = 10
c
Sol: A)       c 51. D

Sol: Mg+2 has 10e, 12p and 12n.
B) E = h 

c
C)     c  
52. C

40. A Sol: A neutral atom may or may not have
equal number of protons and neutrons.
Sol: Wave length (  ) = 97540 cm
53. A
c 310 10
  = 0.0000307 × 1010
 97540
ACROSS: ()
= 3.07 × 105 s-1
6. ORBIT
41. A
7. NEUTRON
MATRIX MATCHING TYPE (M.M.T.): 8. NUCLEONS
42. A, E 9. NEUTRON
43. B 10. KANAD
44. C, E DOWN: ()

45. D 1. ISOTOPES
2. RUTHERFORD
3. FREQUENCY
4. THOMSON
5. ELECTRON
46. 1

47. 2

Sol: Mg (12) = 2(K), 8(L), 2(M)

2 AIMS OLYMPIAD ACADEMY


VIII-CHEMISTRY PERIODIC CLASSIFICATION
VIII CHEMISTRY

2 PERIODIC CLASSIFICATION
23. B

24. B

25. D
1. B
2. B
3. B
4. A MULTI CORRECT ANSWER TYPE (M.C.A.T.):
5. D 26. A, B & C
6. D 27. A, B & D
7. B
28. A, B & D
8. B
29. A & D
9. A
Sol: After the removal of second electron
10. A
from the II A group elements, they
11. A attain stable configuration. Hence they
12. D have greater third IP.
SINGLE CORRECT ANSWER TYPE (S.C.A.T.): 30. B, C & D
13. C 31. A & C
14. A
32. A, B & D
15. B
Sol: A- 2He
COMPREHENSION PASSAGE TYPE (C.P.T.):

B- 3Li 33. A

C- 7N 34. C
D- 10
Ne 35. B
E- 30
Zn 36. A
16. C Sol: As electrons are removed from an atom,
17. A protons number will becom more than
electron number. Hence p/e ratio
18. D
increases.
19. D
37. B
20. C
Sol: IP values decreases in a group from
21. C
top to botom.
22. B

AIMS OLYMPIAD ACADEMY 3


PERIODIC CLASSIFICATION VIII-CHEMISTRY
38. B 9. LAVOISIER

Sol: IE1 for Mg g  Mg +  g + e- is 178 K cal/mol 10. WEIGHTS


11. ALKALIMETALS
IE2 for Mg + g   Mg 2+  g  + e- is 348 K cal/mol
DOWN: ()
Total energy required for
- 1. NUMBERS
Mg  g   Mg  g  + 2e is
2+

2. HELIUM
IE1 + IE2 = 178 + 348 = 526 K cal/mol
3. OCTAVES
MATRIX MATCHING TYPE (M.M.T.):
4. DECREASES
39. C
5. HALOGENS
40. E 8. SEVEN
41. A

42. B, D

43. A, D
44. C

45. B

46. E

47. A
48. B
Sol: The elements in the modern periodic
table are arranged on the basis of their
increasing atomic numbers.

49. C
Sol: The distance from the nucleus to the
outermost orbit of an atom is called its
atomic radius.

ACROSS: ()
6. FLUORINE
7. TRIADS

4 AIMS OLYMPIAD ACADEMY


VIII-CHEMISTRY CHEMICAL BOND
VIII CHEMISTRY

3 CHEMICAL BOND
17. C

Sol: 2-bond pairs, 3-lone pairs

1. D 4-bond pairs, no lone pairs

2. B
3. D 4-bond pairs, 2-lone pairs

4. B
5. B
6. B 6-bond pairs, no lone pairs
7. C
8. B 18. A
9. B Sol: Methane(CH 4 ) has 4 bond pairs,
10. C ammonia(NH3) has 3, fluorine(F2) has
2 and nitrogen(N2) has 3 bond pairs.
11. C
19. D
12. A
20. D
SINGLE CORRECT ANSWER TYPE (S.C.A.T.):
21. D
13. B
22. A
14. B
23. A
Sol: Given A: 2, 8, 3. A loses 3 electrons
and forms A+3. 24. A

B: 2,6. B gains 2 electrons and forms 25. C


B-2. Then, the formula of the compound
formed by A & B is

A+3 B-2
MULTI CORRECT ANSWER TYPE (M.C.A.T.):
A2 B3
26. A, C & D
Hence the formula of the compound is
A2B3. 27. A & B

15. A Sol: Elements with 1 or 2 or 3 valence


electrons, lose them to acquire stability.
16. C

AIMS OLYMPIAD ACADEMY 5


CHEMICAL BOND VIII-CHEMISTRY
28. A, B & D

29. A & B 48. B

30. A, B & C Sol: Fluorine has 7 valence electrons. It


loses one electron to attain stable
31. A & B
configuration(6 electrons) and forms F +.
Sol: N2 : O2 :
49. C

CH4 : C NH3 : Sol: As ‘C’ is an alkali metal, ‘B’ will be a


noble gas and ‘A’ will be a halogen. The
32. B, C & D bond formed between an alkali metal
and a halogen will be ionic bond.
COMPREHENSION PASSAGE TYPE (C.P.T.):
50. A
33. D
51. C
34. D
52. C
35. B

36. D
ACROSS: ()
37. B
4. COVALENT
38. D
6. BONDPAIR
MATRIX MATCHING TYPE (M.M.T.):
DOWN: ()
39. A
1. DATIVE
40. C, D
2. GOOD
41. B, E
3. IONIC BOND
42. B, E
5. LEWIS
43. B, E
7. NEON
44. B, D
8. POLAR
45. C, D

46. A

47. A

6 AIMS OLYMPIAD ACADEMY


VIII-CHEMISTRY CHEMISTRY OF HYDROGEN AND OXYGEN
VIII CHEMISTRY

4 CHEMISTRY OF H2 & O2

20. D

Sol: H  H + + e -

1. B Its is just like Na  Na + + e-

2. B 21. B

Sol: Protium has 1 proton, 1 electron and 22. D


no neutrons.
Sol: H + e -  H - Its is just like F + e -  F-
3. B
23. B
4. D
24. A
5. A
25. B
6. C
26. B
7. C
27. C
8. A
28. B
9. C
29. B
10. A

11. B

12. A

13. D MULTI CORRECT ANSWER TYPE (M.C.A.T.):

14. D 30. A, C & D

31. A, B, C & D
SINGLE CORRECT ANSWER TYPE (S.C.A.T.):
32. B
15. A

16. C Sol: Isotope e p n

17. D Protium 1 1 0

18. B Deuterium 1 1 1

19. D Tritium 1 1 2

Sol: 2 K + 2H 2 O  2KOH + H 2 + Energy

AIMS OLYMPIAD ACADEMY 7


CHEMISTRY OF HYDROGEN AND OXYGEN VIII-CHEMISTRY
33. A, B & C

Sol: Most abundant gas in the atmosphere 43. D


is Nitrogen.

Hydrogen is the most abundant gas


in the universe but rarely existing in 45. A
the atmosphere in free state.

34. A, B & C
ACROSS: ()
35. A, C & D
1. PROTIUM
36. A, B, C & D
4. OZONE
COMPREHENSION PASSAGE TYPE (C.P.T.):
7. CATALYST
37. B
8. HYDROGEN
38. C
9. CARBOGEN
39. A
DOWN: ()
40. A
2. REDUCING
MATRIX MATCHING TYPE (M.M.T.):
3. HALOGENS
41. E
4. OXYGEN
42. A, B
5. BASIC
43. D
6. LILAC
44. C

45. C

Sol: 4Na (s) +O2(g)   2N 2O + t

46. C

47. C

48. B

8 AIMS OLYMPIAD ACADEMY


VIII-CHEMISTRY CHEMISTRY OF CARBON AND NITROGEN
VIII CHEMISTRY

5 CHEMISTRY OF C & N2
MATRIX MATCHING TYPE (M.M.T.):
42. A, D 43. E

44. B 45. C

46. D 47. A
1. D 2. C 3. C
48. C, E 49. BS
4. C 5. C 6. B

7. D 8. B 9. A

10. A 11. C 12. A

13. A
50. A
SINGLE CORRECT ANSWER TYPE (S.C.A.T.):

14. A 15. B 16. B


51. D 52. D 53. C
17. B 18. A 19. A
54. B 55. B 56. D
20. A 21. B 22. A
57. B
23. B 24. C 25. B

26. C
ACROSS: ()

3. GRAPHITE

5. PNICOGENS

MULTI CORRECT ANSWER TYPE (M.C.A.T.): 6. AMMOTAL

8. ALLOTROPY
27. A, B & C 28. A & D
9. AQUAREGIA
29. A & D 30. A & B
10. NITRE
31. A 32. A, B & D
11. FOUR
33. B & C 34. A & B
DOWN: ()
35. A & B
1. CATENATION
COMPREHENSION PASSAGE TYPE (C.P.T.): 2. OXIDE
36. C 37. B 38. A 4. AMMONIA

39. B 40. D 41. A 7. DIAMOND


AIMS OLYMPIAD ACADEMY 9
METALS AND NON METALS VIII-CHEMISTRY
VIII CHEMISTRY

6 METALS AND NON METALS


32. B 33. C 34. B

1. A 2. C 3. D MULTI CORRECT ANSWER TYPE (M.C.A.T.):


4. B 5. A 6. C 35. A & B
7. B 8. C 36. A, B & D
9. B Sol: Some metals are non ductile and non
Sol: When Magnesium burns in air it forms malleable. For example, sodium and
magnesium oxide (MgO) which is basic potassium (soft metals).
in nature. Mercury is a liquid metal.
10. D 11. D 12. A 37. A, B & C 38. A & D
13. B COMPREHENSION PASSAGE TYPE (C.P.T.):
14. C 39. B 40. D 41. A
Sol: Sodium is highly reactive metal. It
MATRIX MATCHING TYPE (M.M.T.):
catches fire if it is kept out. Therefore,
42. B 43. C
it is always stored under kerosene.
15. B 44. A 45. D
Sol: Phosphorous is a reactive non-metal.
It catches fire when exposed to air.
Therefore, it is always stored under
water.
16. C 46. A
SINGLE CORRECT ANSWER TYPE (S.C.A.T.):
17. C 18. B 47. A 48. A
19. B
Sol: Sulphur (non-metal) is used to apply 49. B 50. C 51. A
on wounds as an antiseptic.
20. A 21. C 22. B ACROSS: ()
23. B 6. OXIDE
Sol: As zinc is more reactive than copper, 7. DUCTILITY
it replaces copper from copper sulphate 8. SULPHUR
solution and forms zinc sulphate and 9. GOLD
copper.
10. SONOROUS
24. C 25. A 26. A
DOWN: ()
27. B 28. D 29. B
1. BASIC
30. B
2. MERCURY
Example: Mg + 2HCl  MgCl2 (Salt) + H2
3. MALLEABLE
31. C
4. LUSTROUS
Note: Correct the question as “Aluminium
5. METALS
is a good conductor of heat and
9. GOOD
electricity, so it is used in”
10 AIMS OLYMPIAD ACADEMY
VIII-CHEMISTRY LAWS OF CHEMICAL COMBINATION
VIII CHEMISTRY

7 LAWS OF CHEMICAL COMBINATION


24. C
25. A
26. B
27. A
1. A
28. B
2. B
3. D
4. A
5. C MULTI CORRECT ANSWER TYPE (M.C.A.T.):

Sol: CaCO 3  CaO  CO2 29. A


30. A, C & D
6. D
31. A, B, C, D
7. C
Sol: Nitrogen combines with oxygen to form
8. C
the various oxides.
9. C
The ratio of weights of oxygen (8, 16,
SINGLE CORRECT ANSWER TYPE (S.C.A.T.): 24, 32, 40) combining with fixed weight
10. D of nitrogen (14) is 8 : 16 : 24 : 32 : 40
i.e. 1:2:3:4:5, which is simple whole
11. D
number ratio.
12. A
13. C
14. A
15. B

Sol: CaCO 3  CaO  CO2

16. A
OR
17. D
The ratio of weights of oxygen
18. A combining with fixed weight of nitrogen
19. C (28) is 16 : 32 : 48 : 64 : 80.

20. A COMPREHENSION PASSAGE TYPE (C.P.T.):


21. D 32. D
22. C 33. D
23. D 34. B

AIMS OLYMPIAD ACADEMY 11


LAWS OF CHEMICAL COMBINATION VIII-CHEMISTRY
MATRIX MATCHING TYPE (M.M.T.): 45. B

35. E, B Sol: The masses of oxygen that are


combining with copper to form curic
36. D oxide and cuprous oxide are in the ratio
2:1.
37. C
2:1  1.6:0.8
38. A
46. A

ACROSS: ()

2. MULTIPLE
39. A
4. DALTON
40. A
7. GAYLUSSAC

8. CONSERVATION
41. 24
DOWN: ()
Sol: 1:8  3:24
1. PROUST
42. 8
3. LAVOISIER
43. 0.734
5. AVOGADRO

6. DEFINITE
44. C

Sol: The equation for the given reaction is:

Na 2CO3 +CH3COOH  CH3COONa+CO2 +H2O

The masses of products are

Na2CO3 = 8.2 g

CO2 = 2.2 g

H2O = 0.9 g

Total mass of products = 11.3 g

According to law of conservation of The


total mass of products = The total mass
of rectants

12 AIMS OLYMPIAD ACADEMY


VIII-CHEMISTRY NUCLEAR CHEMISTRY
VIII CHEMISTRY

8 NUCLEAR CHEMISTRY
231
iii) 90 Th n = 231 – 90 = 141
Isotopic number = n – p
= 141 – 90 = 51
231
iv) 91 Pa n = 231 – 91 = 140
1. A
Isotopic number = n – p
2. D
= 140 – 91 = 49
3. D 14. C
4. B
Sol: Radioactive isotope of hydrogen is
5. B tritium 31 H (e = 1, p = 1 and n = 2).
6. D 15. D
7. B 16. C
Sol: Half life of a radioactive substance is 17. C
independant of the amount of the
Sol: Magic numbers are 2, 8, 20, 28, 50,
substance.
82 & 126.
8. C 115
i) 50 Sn : Number of protons(p) = 50,
9. B
Number of neutrons(n–p) = 115 – 50
10. C = 65
206
11. D ii) 81 Pb : Number of protons(p) = 81,

12. C Number of neutrons(n–p) = 206 – 81


= 125
SINGLE CORRECT ANSWER TYPE (S.C.A.T.): 208
iii) 82 Pb : Number of protons(p) = 82,
13. C Number of neutrons(n–p) = 208 – 82
Sol: The species with same isotopic number = 126
are called isodiaphers. iv) 118
50 Sn : Number of protons(p) = 50,
235
92 U n = 235 – 92 = 143 Number of neutrons(n–p) = 118 – 50
= 68
Isotopic number = n – p
18. B
= 143 – 92 = 51
209
Sol: Given binding energy = 6.46 MeV
i) Bi n = 209 – 83 = 126
We have, binding energy E =  m 
83

Isotopic number = n – p 931.5 MeV


= 126 – 83 = 43 Binding energy 6.46
 m = 
ii) 212
82 Pb n = 212 – 82 = 130 931.5 931.5
Isotopic number = n – p = 0.00693 amu
= 130 – 82 = 48

AIMS OLYMPIAD ACADEMY 13


NUCLEAR CHEMISTRY VIII-CHEMISTRY
19. D 22. B
Sol: Given t1/2 = 30 days Sol: A
X A
Y 0

Z Z 1 1

Initial amount = 80 g A 4
A
Z 1 Y Z 1 Z  42 
After 30 days = 40 g remained
A 4 A4
After 60 days = 20 g remained Z 1 Z Z 1 Z  00 
After 90 days = 10 g remained
23. A
20. A
24. B
Sol: Half life the radioactive matter = 6
years Sol: 14
7 N  42 He  17
8 O  1H
1

The decrease in mass between 18 and 25. B


24 years (i.e. in Half life) = 4g
Sol:
The mass of matter in 18th year
26. B
=4+4=8g
Sol: When a  -particle is emitted, the
The mass of matter in 12th year
atomic number of the nuclide increased
= 8 + 8 = 16 g by one but mass remains same. Thus
The mass of matter in 6th year parent and daughter nuclides have
same mass numbers but different
= 16 + 16 = 32 g
atomic numbers. Thus they are isobars.
The initial mass of matter
= 32 + 32 = 64 g
21. A
Sol: 90
Th234  84
Po218 MULTI CORRECT ANSWER TYPE (M.C.A.T.):
Difference in mass no = 234 – 218 27. B & D
= 16
Difference in atomic no = 90 – 84 X
Sol: 100

=6  
No. of  - particles emmited =
98 Y 101 Y
difference in mass numbers
4    

16
  4   particles 96 Z 99 Z 99 Z 102 Z
4

No. of  - particles emmited


28. A, B & C
= 2 × no. of  particles-difference in
atomic numbers 29. A, B, C & D

= 8 – 6 = 2  - particles 30. A, C & D

14 AIMS OLYMPIAD ACADEMY


VIII-CHEMISTRY NUCLEAR CHEMISTRY
31. A & C

238  84
Sol: 239
 X  8 24  6 01
92 U 92   32   61

206
The product is 82 X 43. A
A = 206 and Z = 82 44. D
 The number of protons (p) = 82

Number of neutrons (n) = A–Z 45. C

= 206 – 82 = 124 239


 218
 x 24  y 01
92 U 84 X
Sol:
32. B, C & D Number of  -particles emitted
COMPREHENSION PASSAGE TYPE (C.P.T.):
Difference in mass numbers of parent and daughter nuclei
33. C =
4

34. C 238  218


= =5
4
Sol: R = R0 × A1/3
Number of  -particles emitted
= 1.4 ×10 –15
× (27) 1/3
= 2 × No. of a particles emitted –
= 1.4×10–15 × 3m Difference in atomic numbers of parent
and daughter nuclei
R = 4.2 ×10–15 m
= 2  5  (92  84)
35. B
46. A
Sol: R = R0 × A 1/3
Sol: 216
Z Po  4
2 He + 2 0
1  + 212
Z X
= 1.4 ×10–15 × (233)1/3 m When a nuclide emits one alpha and
two beta particles, the atomic number
= 1.4 ×10–15 ×6.2
will be same but mass number will be
R = 8.68 ×10–15 m reduced by 4.
So, the parent and product nuclides
36. C have same atomic numbers but
different mass numbers. Thus, the
37. C product nuclide is isotope of parent
nuclide.
38. B
47. D
MATRIX MATCHING TYPE (M.M.T.): 48. C
39. B Sol: Half life of C-14 = 5,730 years
40. D 50 % of C-14 will be remained after
5,730 years
41. E
25 % of C-14 will be remained after
42. A 11,460 years

AIMS OLYMPIAD ACADEMY 15


NUCLEAR CHEMISTRY VIII-CHEMISTRY

ACROSS: ()
5. ISOTOPES
6. FISSION
8. HALFLIFE
9. BECQUERREL
DOWN: ()
1. RUTHERFORD
2. MASSDEFFECT
3. ISOSTERS
4. FUSION
7. NUCLEAR

16 AIMS OLYMPIAD ACADEMY


ADVANCED FOUNDATION - CHEMISTRY IX - KEY AND SOLUTIONS

AIMS
CHEMISTRY
IIT-JEE, NEET & OLYMPIADS
ADVANCED FOUNDATION

IX CLASS
KEY
&
SOLUTIONS

AIMS OLYMPIAD ACADEMY


IX-CHEMISTRY ATOMIC STRUCTURE
IX CHEMISTRY

1 ATOMIC STRUCTURE

SINGLE CORRECT ANSWER TYPE (S.C.A.T.):


16. A
17. D
1. D Sol: E = h  = hc/
2. C 1 E1  2
 E  
3. D  E 2 1
4. A E1 4000
   2 :1
5. D E 2 2000

6. D 18. C

Sol: Cs has the lowest IP and biggest size, Sol:  = 3 × 1015 s–1
so it can release elctrons easily by E = h  = 6.625 × 10–34 × 3 × 1015
passing light energy on its surface.
= 19.878 × 10–19 J
= 1.9878 × 10–18 J
7. B
19. A
8. C
Sol: Wave length (  ) = 97540 cm
9. A
Sol: According to De broglie’s wavelength c 31010
  = 0.0000307 × 1010
equation  97540

h 1 = 3.07 × 105 s–1


λ= or λ 
mv v 20. A

10. C 21. D

11. C Sol: In P-fund series, n1 = 5 and n2 = 6,


7, 8 ...
12. A
Sol: n+l value of 3p = 3 + 1 = 4 1 1 1 1 
  R     R   
n+l value of 4s = 4 + 0 = 4  n1 n 2  5 6

n+l value of 3d = 3 + 2 = 5 22. B


n+l value of 4f = 4 + 3 = 7 23. B
nh
n+l value of 3s = 3 + 0 = 3 Sol: Angular momentum, mvr 
2
13. A 2h h
 mvr  
14. B 2 

15. B Note: Replace ‘p’ with ‘ π ’ in all the


options.

AIMS OLYMPIAD ACADEMY 1


ATOMIC STRUCTURE IX-CHEMISTRY
24. A 31. A,B, C

1s 2s 2px 2py 2pz 3s


h Sol: Na :
Sol: We have de Broglie equation,  =
p

h Number of electrons with spin value


 p=
 +1/2 = 6
Number of electrons with spin value
25. B
–1/2 = 5
h 1s 2s 2px 2py 2pz
Sol: Momentum = (using de Broglie
 B:
equation)
Number of electrons with spin value
34
6.625  10 +1/2 = 3

2.5  1010 Number of electrons with spin value
24 1
 2.65  10 kg m sec –1/2 = 2
26. C 1s 2s 2px 2py 2pz
C:
Sol: Given m = 150g = 0.150 kg
x = 1 A = 10 m
O -10
Number of electrons with spin value
h = 6.6 × 10–34 Kg m2 s–1 +1/2 = 4
Number of electrons with spin value
h
We have, x.m v  –1/2 = 2
4
1s
h He :
 
4 x.m
6.6  1034 Number of electrons with spin value
 +1/2 = 1
4  3.143  1010  0.150
= 3.50 × 10–24 ms–1 Number of electrons with spin value
27. A –1/2 = 1

28. A 32. A, D
33. A, B, C
Sol: n + l value of 3d = 3 + 2 = 5
n + l value of 4p = 4 + 1 = 5
MULTI CORRECT ANSWER TYPE (M.C.A.T.):
n + l value of 5s = 5 + 0 = 5
29. A, C, D
n + l value of 5p = 5 + 1 = 6
Sol: Bohr’s theory is applicable only
species with one electron COMPREHENSION PASSAGE TYPE (C.P.T.):
30. B, C, D 34. B
Sol: Heisenberg’s principle is applicable Sol: For l = 0, possible m value is 0 but not –1.
only for micro particles which are
moving with high velocity. 35. C

2 AIMS OLYMPIAD ACADEMY


IX-CHEMISTRY ATOMIC STRUCTURE
MATRIX MATCHING TYPE (M.M.T.): The number of electrons with l=1
(p-electrons) = 6 + 6 = 12
36. C
The number of electrons with l=2
37. A
(d-electrons) = 5
38. D
42. A
39. B
h 6.625 10-34
Sol: λ = =
mv 60  10-3  10

= 1.104  10–33m

40. A 43. D
Sol: The energy of radiation must be equal Sol: Principal quantum number
to or greater than the work functions determaines the energy and size of the
of metals to show photoelectric effect. orbits but not orientation.
We need to convert wavelength of 44. A
radiation into energy expressed in eV
units.
45. A

Eradiation = hc/ λ 46. A

= 6.626  10–34Js  3.0  108 ms–1/


300  10–9m ACROSS: ()
= 6.626  10 –19
J 2. ORBITS
Now convert this value into eV. 8. SPECTRUM
We know that: 9. PLANCK
1 J = 6.24 × 1018 eV 10. SPHERICAL
Therefore: 11. SOMMERFELD
6.626  10 –19
J DOWN: ()
= 6.626  10 –19
 6.24× 1018 eV 1. BOHR
= 4.134 eV 3. THOMSON
Conclusion: Since the work functions 4. DEBROGLIE
of only Li, Na, K and Mg fall below
4.134 eV, only these metals can show 5. PRINCIPAL
photoelectric effect upon exposure of 6. CHROMIUM
radiation of 300nm wavelength.
7. ORBITAL
The number of metals that can show
photoelectric effect = 4.
41. B
Sol: Cr (24) = 1s22s22p63s23p64s13d5

AIMS OLYMPIAD ACADEMY 3


PERIODIC CLASSIFICATION IX-CHEMISTRY
IX CHEMISTRY

2 PERIODIC CLASSIFICATION

Sol: Iron belongs to d-block, first transition


series, 4th period and VIII group.
19. A
1. B Sol: Ionic radius increases from top to
bottom in a group.
2. A
20. C
3. B
4. B Sol: Mass number = 39

5. D Atomic number = 19 (From electronic


configuration)
6. D
7. C Hence e=19, p=19, and n=39-19=20.

Sol: If the size of the atom is greater IP The element is 19


K39.
value will be lower.
21. A
8. C 22. A
9. A
Sol: In Zero group all the elements have
10. A ns2np6 configuration except Helium
which has ns2 configuration.
SINGLE CORRECT ANSWER TYPE (S.C.A.T.):
23. B
11. D
12. A
13. C
Note: Actually, the remaining elements are MULTI CORRECT ANSWER TYPE (M.C.A.T.):
aslo discovered recently. Afficially they
have to be filled in the Moden periodic 24. A, B, C
table.
Sol: I B group elements are known as
14. B coinage metals.
15. B 25. B, C, D
Note: Replace (n-A) in options A), B) and Sol: s and p block elements together called
C) with (n-1). representative elements (except noble
gases).
The correct answer is (n-1)d1–10ns1–2.
26. A, B, C
16. B
27. A, D
17. B
18. B

4 AIMS OLYMPIAD ACADEMY


IX-CHEMISTRY PERIODIC CLASSIFICATION
Sol: After the removal of second electron
from the II A group elements, they
39. B
attain stable configuration. Hence they
have greater third IP. 40. B

28. A, B, D Sol: IE1 for Mg g  Mg +  g + e- is 178 K cal/mol

Sol: Electron affinity generally, decreases IE2 for Mg + g   Mg 2+  g  + e- is 348 K cal/mol


in a group. But because of very smaller
size of 2nd period elements, they have Total energy required for
less EA values than 3rd period -
Mg  g   Mg  g  + 2e is
2+

elements.
IE1 + IE2 = 178 + 348 = 526 K cal/mol
COMPREHENSION PASSAGE TYPE (C.P.T.):
41. A
29. A
42. B
30. C or D
Sol: When an electron is removed from an
Sol: 6 and 7 periods contain 32 elements
th th atom the number of electrons decreases,
each. nuclear attraction on the remaining
electrons increases and hence second
31. D IP will greater than first IP.

MATRIX MATCHING TYPE (M.M.T.):


32. A, D ACROSS: ()
33. C 1) TWO
34. B, E 6) NUMBERS
35. A, E 10) ELECTRONEGATIVITY
11) NEWLAND
12) WEIGHTS
DOWN: ()

36. C 1) TRIADS
2) ALKALIMETALS
Sol: I: Al has an unpaired electron in 3s
orbital where as Mg has paired 3) SEVEN
electrons in 3s.
4) OXIDATION
II: Mg+ has an unpaired electron in 3s
orbital where as Na + has paired 5) DECREASES
electrons in 2p. 7) INCREASES
37. A 8) SCANDIUM
38. B 9) ANGSTROM
I: E.N decreases as size increases. Sol: Add “9. An unit of atomic radius:” in
II: Reducing power (electron loosing down.
tendency) increases as size increases.

AIMS OLYMPIAD ACADEMY 5


CHEMICAL BOND IX-CHEMISTRY
IX CHEMISTRY

3 CHEMICAL BOND
15. C

Sol: As number of bonds increases between


two atoms, bond length decreases.

16. D
1. D
17. B
2. A
18. D
3. A

4. A 19. A

Sol: p-p overlapping > s-p overlapping > 20. C


s-s overlapping
Sol: H2O2 has non-polar bonds between two
5. B oxygen atoms and has polar covalent
bonds between oxygen and hydrogen
6. D atoms.
Sol: H2 and Cl2 form polar covalent bond.

7. B

8. D 21. A
9. A 22. C
10. B Sol: Percentage of p charactar
Sol: SO2 has two bond pairs and one lone
pair on its central atom. no.of p - orbitals
= ×100
total no.of orbitals
11. A 3
= ×100 = 75%
Sol: NH3 - Pyramidal 4

CO2 - Linear 23. B

BF3 - Trigonal planar 24. C


12. D 25. D
Sol: The shape of the molecule which is
Sol: AB4E2 represents 4 bond pairs and 2
having lone pairs of electrons on its
lone pairs on central atom.
central atom is affected by lone pairs.
26. A
SINGLE CORRECT ANSWER TYPE (S.C.A.T.):
13. B Sol: AB3E represents 3 bond pairs and 1
lone pair on central atom.
14. A

6 AIMS OLYMPIAD ACADEMY


IX-CHEMISTRY CHEMICAL BOND

MULTI CORRECT ANSWER TYPE (M.C.A.T.):


27. A & D 45. C

28. A, B, C & D

29. A, B, C & D 46. A

30. A, B, C & D
47. D
31. A, C & D
48. C
32. A & C
49. D
Sol: As bond length increases, bond energy
decreases.
ACROSS: ()
33. A, B, C & D
3. TWO
COMPREHENSION PASSAGE TYPE (C.P.T.):
6. COVALENTBOND
34. A
7. PYRAMIDAL
Note: Change the question as “Which of
the following elements cannot form 9. IONICBOND
hydrogen bonding?” 10. HYDROGENBOND
Sol: The atoms with high electronegativity DOWN: ()
can participate in hydrogen bonding.
1. POLARBOND
35. B
2. DATIVEBOND
36. D 4. CHEMICALBOND
MATRIX MATCHING TYPE (M.M.T.): 5. SIGMABOND
37. A, E 8. PIBOND
38. C, D

39. C, E

40. B, E

41. C, E
42. B, C, E

43. A, C, D

44. A, C, D

AIMS OLYMPIAD ACADEMY 7


MOLE CONCEPT AND STOICHIOMETRY IX-CHEMISTRY
IX CHEMISTRY

4 MOLE CONCEPT
14. A

Sol: 71 g of Cl2 gas occupies 22.4 L volume


at STP.
7.1 g of Cl2 gas occupies 2.24 L volume
1. B at STP.
15. A
2. A
16. C
3. C

4. C Sol: Percentage mass of Carbon

Sol: Weight of 1 atom of helium = 4 amu At. Wt. of carbon× No.of atoms of carbon
= ×100
Mol. Wt.
= 4×1.67×10 – 24
g
12× 2
= 6.64×10-24 g = ×100 = 40 %
60
5. B
17. A
18. A
Sol: We have, Percentage mass

Sol: ZnCO3   ZnO  CO 2
AW  No.of atoms of the element per molecule 1mol 1mol 1mol
 100
MW
From the balanced equation
No. of atoms of the element per
MW  percentage mass 125 g of ZnCO3 produces 81 g of ZnO
molecule 
AW 100
xg of ZnCO3 produces 10 g of ZnO
6. A
125  10
7. A x  15.43g
81
8. B 19. C
9. B Sol: CaCO3 

 CaO CO 2
1mol 1mol 1mol

10. B From the balanced equation

SINGLE CORRECT ANSWER TYPE (S.C.A.T.): 100 g of CaCO3 liberates 22.4 L of CO2

11. B xg of CaCO3 liberates 5.6 L of CO2

12. B 100  5.6


x  25g
22.4
13. A

8 AIMS OLYMPIAD ACADEMY


IX-CHEMISTRY MOLE CONCEPT AND STOICHIOMETRY
20. B

Sol: 2C 2 H 6  7 O 2 
 4 CO 2  6H 2 O
732g 444g

From the balanced equation MULTI CORRECT ANSWER TYPE (M.C.A.T.):

224 g of O2 liberates 176 g of CO2 24. A & B

16 g of O2 liberates x g of CO2 25. A, B, C & D

26. A, B & D
176  16
x  12.57g
224 27. A & B

21. A Sol: Mass percentage of an element =

Sol: SiO 2  3 C 
 SiC  2CO At.wt  No.of atoms of the element per molecule
60g 312g  100
Mol.Wt
From the balanced equation

60 g of SiO2 needs 36 g of C 12  1
C % in CO 2  100  27.27
44
20 g of SiO2 needs x g of C
16  2
O % in CO 2  100  72.73
36  20 44
x  12 g
60
28. B & D
22. D 12  3
Sol: C % in C3H6 =  100  85.71
42
Sol:
12  1
A) C % in CH4 = 100  75
16
Element W % W% / At.Wt. Least ratio
H 25 25 / 1 = 25 25 / 6.25 = 4 12  2
C 75 75 / 12 = 6.25 6.25 / 6.25 = 1 B) C % in C2H4 =  100  85.71
28

 Empirical formula = CH4 12  2


C) C % in C2H6 =  100  80
30
23. A
12  4
D) C % in C4H8 =  100  85.71
Sol: CO + 2H 2  CH 3OH 56
1mole 2moles
28g 2  22.4 L COMPREHENSION PASSAGE TYPE (C.P.T.):

29. D
From the balanced equation,
30. C
28 g of CO needed 2  22.4 L of H2
Sol: Weight of 1 mole of H 2O  18g
56 g of CO needed x 4 L of H2
Weight of 4 moles of H 2O  18  4  72g
2  22.4  56
x = 89.6 L
28 31. A

AIMS OLYMPIAD ACADEMY 9


MOLE CONCEPT AND STOICHIOMETRY IX-CHEMISTRY
MATRIX MATCHING TYPE (M.M.T.):
32. D, E

33. A

34. C

35. B

36. A

Sol: 2KNO3  2KNO 2 + O 2

37. A

Sol: 2CO + O 2  2CO 2

MATRIX MATCHING TYPE (M.M.T.):


38. A, C

39. E

40. D

41. B

ACROSS: ()
1. ISOTOPES

6. MOLECULAR
8. AMU

9. STOICHIOMETRY

10. MOLE

DOWN: ()

2. EMPERICAL

3. HYDROGEN

4. MOLECULE

5. ATOMICITY

7. GAYLUSSAC

10 AIMS OLYMPIAD ACADEMY


IX-CHEMISTRY BEHAVIOUR OF GASES
IX CHEMISTRY

5 BEHAVIOUR OF GASES
Final volume V2 = 26 L
Final pressure P2 = ? atm
We have P1V1 = P2V2

1. C 2. A 3. A P1V1 1  196
 P2 =
4. A 5. A 6. C V2 = 26 = 7.538 atm
7. C 8. A 9. C  The final pressure of the gas P2 = 7.538 atm
10. D 11. D 17. A
SINGLE CORRECT ANSWER TYPE (S.C.A.T.): Sol: 35oC = (35 + 273) K = 308 K
12. B 18. A
13. A Sol: Given data:
14. A Initial volume V1 = 5 L
Sol: Given data: Initial pressure P1 = 2 atm
Initial volume V1 = 5 L Initial temperature T1 = 273oC
Initial pressure P1 = 2 atm = (273 + 273) K = 2(273) K
Final volume V2 = ? L Final volume V2 = ? L
Final pressure P2 = 2+3 = 5 atm Final pressure P2 = 1 atm
We have P1V1 = P2V2 Final temperature T2 = 273 K
P1V1 2  5 P1V1 P2 V2
 V2 = We have T  T
P2 = 5 = 2 L 1 2

 The final volume of the gas V2 = 2 L


P1V1 T2 2  5  273
15. B  V2 = 
T1 P2 = 2  273  1 = 5 L
Sol: Given data:
 The final volume of the gas V2 = 5 L
Initial volume V1 = 300mL
19. C
Initial pressure P1 = 380mm
Sol: Given data:
Final volume V2 = ? L
Initial volume V1 = 5 L
Final pressure P2 = 1atm = 760mm
Initial temperature T1 = 100 K
We have P1V1 = P2V2
Final volume V2 = 20 L
PV
 V2 = 1 1 = 380  300 = 150mL Final temperature T2 = ? K
P2 760
V1 V2
 The final volume of the gas V2 = 150mL We have T  T
1 2
16. A
Sol: Given data: V2 T1 20  100
 T2 =
Initial volume V1 = 196 L V1 = 5
= 400 K

Initial pressure P1 = 1 atm  The final temperature of the gas T2 = 400K

AIMS OLYMPIAD ACADEMY 11


BEHAVIOUR OF GASES IX-CHEMISTRY
20. B PVM 1  11.2  28
Sol: Given data: w = = = 14 g
RT 0.0821  273
Initial volume V1 = 2.75 L
 14g of nitrogen occupies 11.2 L.
Initial temperature T1 = 18oC = 291 K (OR)
Final volume V2 = ? L At STP (760mm of Hg and 273K)
Final temperature T2 = 45oC = 318 K 28g of nitrogen (one mole) occupies
V1 V2 22.4 L volume.
We have T  T x g of nitrogen occupies 11.2 L
1 2
volume.
V1T2 2.75  318
 V2 = 28  11.2
T1 = 291
=3L x = = 14 g
22.4
 The final volume of the gas V2 = 3 L  14g of nitrogen occupies 11.2 L.
21. B 24. C
Sol: 22,400 cm3 of CH4 weighs 16 g
2
112 cm3 of CH4 weighs x g Sol: nH2 = = 1 moles
2
16  112
x = = 0.08 g 8
22400 nHe = = 2 moles
4
 112 cm3 of CH4 weighs 0.08 g
22. D 22
nCO2 = = 0.5 moles
Sol: Given data: 44
Initial volume V1 = 2 L
8
Initial pressure P1 = 380 mm nO2 = = 0.25 moles
32
Initial temperature T1 = 27oC
We have
= (27 + 273) K = 300 K
Partial pressure (PP) =
Final volume V2 = ? L
Mole fraction (X)  Total pressure (PT)
Final pressure P2 = 760 mm
 The gas with more number of moles
Final temperature T2 = 273 K
will have greater partial pressure.
P1V1 P2 V2 25. B
We have T  T
1 2 Sol: Molecules with greater molecuar
weight will diffuse at lower rate.
P1V1 T2 380  2  273
 V2 = 
T1 P2 = 300  760 = 0.91 L

 The final volume of the gas V2 = 0.91 L


23. B MULTI CORRECT ANSWER TYPE (M.C.A.T.):
Sol: Given data: 26. A, B & C 27. A, B, C & D
Volume V = 11.2 L 28. A, B, C & D
Pressure P = 1 atm 29. B&D
Temperature T = 273 K Sol: Given data:
Gas constant R = 0.0821 Initial volume V1 = 10 L
Molecular weight of N2 = 28 Initial temperature T1 = 27OC = 300 K
w Final volume V2 = 20 L
We have PV = nRT = RT Final temperature T2 = ? K
M

12 AIMS OLYMPIAD ACADEMY


IX-CHEMISTRY BEHAVIOUR OF GASES
V1 V2 Final volume V2 = 2V
We have T  T Final temperature T2 = ? K
1 2

V1 V2
VT
 T2 = 2 1 = 5  300 = 150 K = –123OC We have T  T
1 2
V1 10
 The final temperature of the gas T2 V2 T1 2V  273
 T2 =
= 150 K or –123OC. V1 = V
30. A, B, C & D = 546 K = 273OC
31. A, B & C  The final temperature of the gas T2
32. A&C = 546 K or 273OC.
Sol: Molecular mass of N2O = 44 MATRIX MATCHING TYPE (M.M.T.):
Molecular mass of CO2 = 44 36. D 37. A, B
Molecular mass of He = 4 38. E 39. C
Molecular mass of Ne = 20
Molecular mass of N2 = 28
Molecular mass of CO = 28
COMPREHENSION PASSAGE TYPE (C.P.T.):
33. B 40. 0.5
Sol: Given data: Sol: Given data:
Initial volume V1 = V mL Initial volume V1 = 2 L
Initial pressure P1 = 1 atm Initial pressure P1 = 380 mm
Final volume V2 = ? L Initial temperature T1 = 273oC
Final pressure P2 = 3 atm = 2  273 K
We have P1V1 = P2V2 Final volume V2 = ? L
Final pressure P2 = 760 mm
P1V1 1  V
 V2 = Final temperature T2 = 273 K
P2 = 3 = V/3 mL
P1V1 P2 V2
 The final volume of the gas V2 = V/3 mL We have T  T
1 2
34. A
Sol: Given data: P1V1 T2 380  2  273
 V2 = 
Initial volume V1 = 48 L T1 P2 = 2  273  760 = 0.5 L
Initial pressure P1 = 99.3 kPa
 The final volume of the gas V2 = 0.5 L
Final volume V2 = 16 L 41. 2
Final pressure P2 = ? kPa Sol: Given data:
We have P1V1 = P2V2
Rate of diffusion of Oxygen rO2 = r
PV
 P2 = 1 1 = 99.3  48 = 297.9 kPa
V2 16 Rate of diffusion of gas X rX = 4r

 The final pressure of the gas P2 = 297.9 kPa Molecular mass of Oxygen = 32 u
35. C Molecular mass of gas X = M u
Sol: Given data:
rX MO2
Initial volume V1 = V We have 
rO2 MX
Initial temperature T1 = 0OC = 273 K

AIMS OLYMPIAD ACADEMY 13


BEHAVIOUR OF GASES IX-CHEMISTRY
Final volume V2 = ? L
4r 32
 =
r M Final pressure P2 = P/2
Final temperature T2 = 2T
32
16=
M P1V1 P2V2
We have T  T
1 2
M=2
 The molecular mass of the gas = 2. P1V1 T2 P×8.4×2T×2
 V2 = 
T1 P2 = T×P
= 36.6 L

42. B  The final volume of the gas V2 = 36.6 L


Sol: Given data: 45. A
Initial volume V1 = V Sol: At constant temperature
Initial temperature T1 = T K P3
P2
Final volume V2 = ? L
V3 P1

Final temperature T2 = 2T K V2
V1
Vol (L)
Temp T
V1 V2
We have T  T
1 2
V1 < V2 < V3

V1T2 V  2T We have, V  1/P


 V2 =
T1 = T = 2V  P1 > P2 > P3

 The final volume of the gas V2 = 2V


ACROSS: ()
43. D
4. CHARLESLAW
Sol: Given data:
7. MOLECULES
Initial volume V1 = 500 mL
8. DALTON
Initial pressure P1 = 1 atm = 760 mm
9. LOWER
Final volume V2 = ? mL
10. AVOGADRO
Final pressure P2 = 380 mm
14. IDEALGAS
We have P1V1 = P2V2
DOWN: ()
PV
 P2 = 1 1 = 760  500 = 1000 mL 1. BPRESSURE
V2 380
2. GAYLUSSAC
 The final pressure of the gas P2 =
3. BAROMETER
1000 mL
5. GASEOUS
44. C
6. ISOTHERMS
Sol: Given data:
Initial volume V1 = 8.4 L
Initial pressure P1 = P
Initial temperature T1 = T

14 AIMS OLYMPIAD ACADEMY


IX-CHEMISTRY GENERAL ORGANIC CHEMISTRY
IX CHEMISTRY

6 GENERAL ORGANIC CHEMISTRY

26. A, B & C 27. B & C


COMPREHENSION PASSAGE TYPE (C.P.T.):
28. B 29. B 30. C
1. B 2. B 3. A MATRIX MATCHING TYPE (M.M.T.):
4. A 5. D 6. A 31. E 32. A, C 33. B, D
7. A 8. A 9. C 34. A 35. E 36. D
SINGLE CORRECT ANSWER TYPE (S.C.A.T.): 37. B 38. A
10. A
Sol: Methane (CH4) is compound of carbon.
11. D 12. B 13. B
14. C
15. B 39. A

Sol: Acetic acid 40. B, C


Sol: B & C structures represents Hexan-
2-ol where as A & B structures
16. D 17. A represents Hexane-3-ol.
18. C
45. A
Sol: Pentane
ACROSS: ()
19. A 20. A 21. C 1. HEX
2. ALLOTROPY
4. CATINATION
7. OICACID
MULTI CORRECT ANSWER TYPE (M.C.A.T.): 8. ALKANE
22. A, C & D 23. A, C & D
9. BENZENE
24. A, C & D
10. PARAFFINS
Sol: DOWN: ()

N 1. HYDROCARBON
Quinoline 3. CARBON
25. A, B & D 5. BUTANE
Sol: C7H16 - Hept 6. ETHENE

AIMS OLYMPIAD ACADEMY 15


SOLUTIONS IX-CHEMISTRY
IX CHEMISTRY

7 SOLUTIONS
Mole fraction of
n NaOH
NaOH  X NaOH 
n NaOH  n H2O

0.1 0.1
   0.05
1. A 0.1  1.9 2
2. B 13. A

3. A
wt.of solute
4. C Sol: w%   100
wt.of solute
5. A 10
  100
120
6. B
1000
 ( 83.33)
7. D 120

8. B
14. A
Mol.wt
Sol: Eq. wt. of H2SO4 = Basicity Sol: 3.5% by weight means 3.5g of NaCl
present in 100g of sea water
= 98/2 = 49

9. A 10. A The wt. of water = 100–3.5

SINGLE CORRECT ANSWER TYPE (S.C.A.T.): = 96.5 g = 0.0965 kg


11. D 15. B

Wt.of solute wt. of solute 1000


Sol: Solublity(S)= ×100 Sol: M = Mol.wt.of solute  vol. of solution in ml
wt.of solvent
5 5.85 1000
= ×100=20 =  = 0.5M
25 58.5 200
16. A
12. C
Sol: 10% w/v means 10g of NaCl present
Sol: No. of moles of NaOH = in 100 ml of solution

wt 4 x g of NaCl present in 300 ml of


n NaOH    0.1 solution
Mol.wt 40

34.2 300 10


x  30g
No.of moles of H2O = n H2O   1.9 100
18

16 AIMS OLYMPIAD ACADEMY


IX-CHEMISTRY SOLUTIONS
17. D 22. B
Sol: Mole fraction of water = Sol: Mol.wt.of acetic acid  CH 3COOH   60

No. of moles of water 8 8 60


   0.8 Eq. wt of acetic acid   60
Total no.of moles 8  2 10 1
6 1000
N   0.4N
18. A 60 250

Sol: Molarity = 23. B

Sol: Basicity of H3PO4 = 3


Wt of solute 1000
 
Mol wt of solute vol of solution(ml) We have Normality = n × Molarity
23 1000
  1  N = 3×0.1 = 0.3N
46 500
(where ‘n’ is valency factor or basicity
19. B of acid)

24. B
Weight of solute
Sol: Mass% 
Weight of solution wt 1000 49 1000
Sol: N      10N
15 Eq.wt V  ml  49 100
  100  20
15  60

20. B

wt 1000
Sol: m  Mol.wt  wt.of solvent MULTI CORRECT ANSWER TYPE (M.C.A.T.):

25. A, C & D
3.42 1000
=   0.04m 26. A & D
342 250
27. A & B
21. C
28. A, B & D
Normality
Sol: Molarity = Valencyfactor COMPREHENSION PASSAGE TYPE (C.P.T.):

29. A
1.0
A) M HCl   1M
1
No.of Moles of solute
So l : M 
0.4 v.of solution  in L 
B) M H2SO4   0.2M
2

0.1 no.of moles of solute


C) M Na 2CO3   0.05M Vol. of solution 
2 M
6
= = 3L = 3000ml
1 2
D) M NaOH   1M
1
AIMS OLYMPIAD ACADEMY 17
SOLUTIONS IX-CHEMISTRY
30. A wt.of solute
S  100
wt.of solvent
Sol: Weight of NaOH = ?
Mol. wt. of NaOH = 40 10
40  100
w
Molarity M = 0.1 M
Weight of solvent = 25 g
Volume V = 250 ml
34. C
wt 1000
M 
Mol.wt Vol.of solution  in.Mol  Sol: Wt. of solute = Wt. of solution – wt. of
solvent = 30 – 25 = 5g
0.1 40  250
w  1g
1000 wt.of solute
Solubility = wt. of solvent  100
31. A
5
= 100 = 20
Sol: Molecular weight Na2CO3 = 106 25

Strength = 2 g/L MATRIX MATCHING TYPE (M.M.T.):

We have, Molarity = 35. A, C, D

36. B, E
Strength 2
  0.0188 M
Molecular weight 100
37. B, D

32. A 38. B, E

Sol: Wt. of solution = 100g

Wt. of solute = 50g

Wt. of solvent = 100-50 = 50 g


39. A & C
Weight of solute
Solu b ility(S)   100 wt.of solute
Weight of solvent Sol: W% = wt. of solution  100
50
  100  100 wt. of solute (glucose) =
50
w%  wt.of solution
33. A 100

Sol: S = 40 20 180
= = 36g
100
Wt of solute = 10g
Wt.of solvent (water) = 180-36 = 144g

18 AIMS OLYMPIAD ACADEMY


IX-CHEMISTRY SOLUTIONS
40. A & B

Sol: Wt .of solution = 4+36 = 40 g ACROSS: ()

3. DILUTE
Density = 1g /c.c
4. MOLALITY
Volume of solution = mass / density
7. SOLUBILITY
= 40 c.c ( d= m / v)
8. NORMALITY
4 1000
i) Molarity M    2.5M 9. SOLVENT
40 40

wt.of solute 4 DOWN: ()


ii) w%  wt.of solution  100  40  100  10
1. AQUEOUS

wt.of solute 2. SOLUTE


iii) w / v%   100
volume of solution
4. MOLARITY
4
  100  10
40 5. SATURATED

41. D 6. SOLUTIONS

Sol: 30% w/w means 30 g of urea present


in 100g of solution.

Wt of solvent = 100-30 = 70g

30 1000
Molality (m) =   7.14m
60 70

42. D

N
Sol: M 
Valency factor

N 2
 M HCl    2M
1 1

N 2
C) M H2SO4    1M
2 2

N 4
D) M H2SO4    2M
2 2

2N HCl is isomolar with 4N H 2SO4


AIMS OLYMPIAD ACADEMY 19
CHEMICAL KINETICS IX-CHEMISTRY
IX CHEMISTRY

8 CHEMICAL KINETICS
15. D

Sol: P + Q  PQ , the rate of this reation


(r1 let) is given as
r1 = K[P][Q]
1. D 2. C 3. A
If [P] and [Q] are two folded, then the
4. A 5. B 6. A rate of reaction (r2) is given as

7. D r2 = K[2P][2Q]

SINGLE CORRECT ANSWER TYPE (S.C.A.T.): = 4K[P][Q]

8. B
 r 2 = 4 r1
Sol: p P + q Q  r R + s S

1 d[P] 1 d[Q] 1 d[R] 1 d[S]


r   
p dt q dt r dt s dt

MULTI CORRECT ANSWER TYPE (M.C.A.T.):


9. A
16. A, B & C 17. A, B, C & D
10. D
COMPREHENSION PASSAGE TYPE (C.P.T.):
Sol: a A + b B  c C + d D
18. B 19. B 20. A
1 d[A] 1 d[B] 1 d[C] 1 d[D]
r    MATRIX MATCHING TYPE (M.M.T.):
a dt b dt c dt d dt
21. C 22. D
11. A
23. A, B 24. E
12. A

13. A

14. C

Sol: 2A + 3B  P

1 d[A] 1 d[B] 25. C


r =–
2 dt 3 dt
26. B
d[A] d[B]
But  r1 and  r2 27. A
dt dt

1 1
 – r1   r2
2 3

3r1 = 2r2
20 AIMS OLYMPIAD ACADEMY

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