Sri Chaitanya IIT Academy.

, India
A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON CENTRAL OFFICE, MADHAPUR - HYD
Sec: Sr. ICON ALL Jee-Main Date: 29-12-18
Time: 09:00 AM to12:00 Noon CODE-C Max.Marks:360
KEY SHEET
PHYSICS
1 1 2 3 3 1 4 3 5 2

6 1 7 1 8 4 9 1 10 4

11 4 12 4 13 3 14 4 15 1
16 4 17 3 18 2 19 3 20 4

21 1 22 3 23 4 24 1 25 3

26 4 27 3 28 2 29 1 30 4

CHEMISTRY
31 3 32 1 33 1 34 4 35 3

36 3 37 1 38 1 39 1 40 1

41 2 42 2 43 3 44 4 45 4
46 4 47 3 48 2 49 2 50 1

51 3 52 3 53 2 54 2 55 1

56 2 57 1 58 1 59 1 60 1

MATHS
61 2 62 3 63 4 64 1 65 2

66 2 67 1 68 1 69 3 70 1

71 4 72 4 73 2 74 1 75 4
76 1 77 4 78 1 79 4 80 2

81 2 82 3 83 1 84 1 85 4

86 2 87 4 88 3 89 3 90 2
Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-C(9th Jan)_Key & Sol’s
SOLUTIONS
PHYSICS
RS 10x4 20
1. G   
R  S 10  4 3
 v v
2. vw = i+ j
 2 2
v m =  at  j
 v  v 
v wm =  -at  j
2  2 
It appears due east when,
v
-at  0
2
v
 t
2a
m
3. v x =u cos 45o =10 2 cos 45o =10
s
m
v y =  v 2 -v 2x   125  100  5
s
v y = u y  gt

We have, t 
u y  vy

 5    5   1.0 s
g 10
4. Let acceleration of mass m relative to wedge down the plane is ar. Its absolute
acceleration in horizontal direction is arcos 60o-a (towards right). Hence, let N be the
normal reaction between the mass and the wedge. Then
N sin θ = Ma = m (ar cos 60o – a)
Or ar 
 M  m a  2 M  m a
m cos 60o m
5. Maximum frictional force between A and B could be
f1  1mA g   0.2  2 10  N
f1  4 N
Hence, maximum common acceleration till both the blocks move with same
acceleration is

f1 4
a   2m / s 2
mA 2
Now, taking (A + B) as the system
F – 24 = (m A + mB)a = 6 x 2 = 12
 F = 36 N
Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-C(9th Jan)_Key & Sol’s
6. Taking point of suspension as the reference point for gravitational potential energy
(where h = 0)
 l  3l   7
Ui = -  mg +2mg    = - mgl
 2  2  2
 l  3l   5
U f = -  2mg +mg    = - mgl
 2  2  2
U=U f - U i  mgl
7. Ei – Ef = work done against friction
1 2 1 2
 mv  Kx    mg  x
2 2
Substituting the values we get, x = 1m
8. OP  2m


Lz    m   vxy   OP     2  2 2  2 
= - 8 kgm2/s
9. Just after collision velocity of disc will become u (elastic collision between equal
masses)

Now maximum friction will act backwards and this will convert forward slipping into
pure rolling. Till then torque of friction about bottommost point will remain zero and
angular momentum will remain conserved.
 Li = Lf
 muR = mvR + lω
1
Putting v = Rω and l = mR 2
2
2u
We get, 
3R
10. Density of given material
M  3M 
  3 
4 
  2 R    R    28 R 
3 3

3  
Vwhole = V hole + Vremaining
 V remaining = Vwhole - Vhole
3  GM 1 GM 2 
   … (1)
2  2R R 
Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-C(9th Jan)_Key & Sol’s
4  3 8
Here, M 1       2 R   M
3  7
4  3 M
and M 2       R  
3  7
Substituting in Eq. (1), we get
9GM
Vremaining  
14 R
11. Hydrostatic force is perpendicular to the cylindrical surface.
Therefore it passes through O, or its torque about O is zero.
Therefore no force (F = 0) is required to counter balance this torque.

12.
 RT / M   5
 3RT / M  9
 5 5
  or 
3 9 3
Hence the given gas is monoatomic
PT = constant
 PV 
 P = constant
 nR 
Or PV1/2 = constant
Comparing with PVx = constant … (1)
1
We have, x
2
Molar heat capacity in equation (1) is given by
R 3 R 7R
C  CV   R 
1 x 2 1 2
1  
2
k 54
13.    3 rad/s
m 6
Maximum friction between 1 kg and 2 kg blocks can be 0.6 x 1 x 10 = 6 N.
6
Therefore, maximum acceleration of 1 kg block can be  6m/s 2 . Maximum force of
1
friction between 2 kg and 3 kg blocks can be 0.4 x 3 x 10 = 12 N. Therefore maximum
12
acceleration of 1 kg and 2 kg blocks jointly can be  4m/s 2 .
3
So, maximum acceleration of the whole system, so that there is no slipping between
any of blocks is 4 m/s2.
Now ,  2 Amax  4
4 4
Or Amax  2  m
 9
14. First assume reflecting surface, as the observer. Frequency received by it is:

Sec: Sr. ICON ALL Page 4

Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-C(9th Jan)_Key & Sol’s
 330  2 
f1  334    332 Hz
 330 
Now this reflector will behave like a source, moving away from the observer
 330 
f 2  332    330 Hz
 330  2 
15. Phase difference corresponding to y1 is –π/2 and that for y2 is +π/2.
Average intensity between y1 and y2
1  /2
  lmax cos 2  / 2  d
  / 2
 lmax   2  / 2
1 2
The required ratio   1  
2  
16. Let l1, l2 and l3 be the images formed by

(i) refraction from ABC

(ii) reflection from DEF and
(iii) again refraction from ABC
Then Bl1 = (5)µg = (5)(1.5) = 7.5 cm
Now El1 = (7.5 + 2.5) = 10cm
 El2 = 10 cm behind the mirror
Now Bl2 = (10 + 2.5) = 12.5 cm
12.5 12.5
 Bl3    8.33cm
g 1.5
17. Flux of qA, qB, qc and qD will be zero from the surface ABCD. But flux due to other
q
four charges from ABCD is each.
24 0
 q  q
 Total  4  
 24 0  6 0
18. Charge distribution will be as shown in figure
Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-C(9th Jan)_Key & Sol’s
Q
E
A 0
Ed
VP  VA  
2
Qd Q
 
2 A 0 2C0
19. Resistance across CD and BE is short circuited.
R 3R
Now, Rnet  R  
2 2
= 30 Ω (as R = 20 Ω)
2
V 2 10  10
 P   W
Rnet 30 3
20. When R = 120 Ω
Then R + r = 125 Ω
Maximum potential drop across potentiometer wire (of resistance 75Ω)
75
  20   7.5V
75  125
When R = 170 Ω
Then R + r = 175 Ω
Maximum potential drop across potentiometer wire
75
  20 
75  175
= 6 Volt
Therefore potential drop > 7.5 volt cannot be measured by this potentiometer.
21. Given VC = 3VR = 3(V - VC)
Here, V is the applied potential.
3
 VC  V
4
3
Or V (1  et / c )  V
4
1
 et / c 
4
Here,  c  cR  10 s
Substituting this value of c in Eq. (1) and solving for t, we get
t = 13.86 s
22. The torque on the loop must be equal to the gravitational torque exerted about an axis
tangent to the loop.
The gravitational torque:
 1  mgr … (1)
Only Bx causes a torque. Therefore torque to the magnetic field
 
 2  M x B  MB sin90o   r 2iBx … (2)
Eqs. (1) and (2), we get

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Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-C(9th Jan)_Key & Sol’s
mg
i
 rBx
R 1
23. Old power factor = 
2
R 2   3R  10
R 1
New power factor = 
2
R 2   3R  R  5
l 1 m
24. v   1
t 1 s
Bvl 111 A
i  1
R 1 S
F  ilB  111  1N
W = Fl = 1 J
25. After absorbing a photon of energy 12.1 eV electron jumps from ground state (n = 1)
to second excited state (n = 3).
Therefore change in angular momentum
 h  h h
L  L3  L1  3   
 2  2 
34
6.6x10
 J  s  2.11x1034 J  s
3.14
26. ΔEmin = 12.1eV
Minimum value of the maximum kinetic energy = (12.1 – 4)eV = 8.1eV
Therefore minimum value of stopping potential is, -8.1V.
Therefore the correct answer is (d).
27. Initial activity,
R0 = λN 0 (N0 = initial number of nuclei)
m
    NA
M 
28. Frequency of LC oscillations is
1
v
2 LC
1

2x3.14 100x106 x400x1012
= 0.0796 x 107 Hz
c
So, wavelength,  
v
3x108

0.0796x107
= 377 m
29. For, upper part

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Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-C(9th Jan)_Key & Sol’s

Here, C=A.B=A+B
=A+B
Here, output C is equivalent to OR gate.
For, lower part

C=A.B  A.B
In this case output C is equivalent to AND gate.
30. A = 2πRh = (2)(π)(6.4 x 106)(150)m2
= 1.92 π x 10 9 m2
= 1.92 π x 10 3 km2

CHEMISTRY
31. Conceptual
32. The balanced equation is
2MnO4  5C2O42  16 H   2Mn 2  10CO2  8 H 2O
33. Pm = dRT
PAmB d A RT

PB mB d B RT
PA 1
x 2
PB 3
PA : PB  6 :1
CaCO3  s  CaO  s   CO2  g 
34.
K c = PCO2, therefore, Kc only depends upon concentration of CO2 as long as
temperature remains constant and both CaCO3(s) and CaO(s) are present.
35. K spMS = [M2+][S2-]
5 x 10-21 = (0.05)[S2-]
For precipitation Qsp = Ksp
5x1021
  S 2   2
 1019
5x10
For H2S:
H2S H   HS   K1 
HS  H   S 2  K 2 
Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-C(9th Jan)_Key & Sol’s
2
 H    S 2 
K1xK 2 
H 2S
2
 H   1019 
107 x1014 
0.1
2
 H    10 3 ,
 [Taking negative logarithm both sides]
2log  H    3
3
pH   1.5
2
36. ΔG = ΔH – T ΔS
Entropy decreases during absorption. Entropy factor is disfavouring, therefore the
enthalpy factor must favour spontaneity, so it must be exothermic and ΔH must be
negative.
37. WA  CH 3COOH  is titrated with SB(NaOH) and 20% of the WA is neutralized, so 20%
of the salt of WA/SB (CH3COONa) is formed and 80% of the WA(CH3COOH) is left.
So an acidic buffer if formed.
[Acid] = 80; [Salt] = 20
 Salt 
pH  pK a  log 
 Acid 
 Salt 
 4.7447  log 
 Acid 
1
 4.7447  log
4
 4.7447  2log 2  4.7447  2x0.3010  4.14
38. i. Edge length = AB = AD = BC = CD = a
2
ii. AC   AB    BC   a  a  2a
2 2 2

2
iii. AG   AC    CG   2a  a  3a
2 2 2

39. Al2(SO 4)3 furnishes maximum number of ions.

40. KCo  FeCN    2.06x106  0.41x106  1.65x106
2 6
4
 mCo  FeCN    2  mCo 2   m  Fe  CN 6 
2 6

= 2 x 86 + 444 = 616 S cm2 mol-1


  m  1000  c  2.7x106 M
c
 K spCo  FeCN    4c 3  7.87x1017 M 3
2 6

41. Conceptual
42. It follows first order kinetics sinceT50 is independent of concentration.

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Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-C(9th Jan)_Key & Sol’s
Hence, x = 10 L, a = 50 L
2.303 50 2.303
k  log  log1.25min 1
10 40 10
43. In physical adsorption, van der Waal’s forces exist.
44. Conceptual
45. px and py orbitals do not have proper orientation to overlap and hence no bond is
formed.

46. Conceptual
HCl
HO H  C  CH 3  H OH
 H 2O

CH 3

OH C OH

CH 3
47.
48. Metal sulphides reduction with carbon is not possible since  f G  for the reaction is not
compensated.
49. Conceptual
50. Conceptual
2
51. Co  NH 3 5 Cl  Cl2 
H 2O
 Co  NH 3 5 Cl   2Cl 
2 AgNO3  2Cl   2 AgCl  2 NO3
52. Let B be the original base.

2B  H 2 PtCl6  B2 H 2 PtCl6   Pt
Ew of B2 H 2 PtCl6  2 B  2  195  6x35.5
= 2B + 410
weight of chloroplatinate Eq. wt. of salt

Weight of Pt Eq. wt. of Pt
0.3 2 B  410

0.09 195
B(Ew) of base = 120
Molecular weight of base = Ew x Acidity
= 120 x 2 =240
53. Conceptual
54. Hydrolysis of 3o RX is independent of nucleophilic concentration (SN1 reaction)
Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-C(9th Jan)_Key & Sol’s
Me Me 
Me
OH
Cl    OH
Me Me Me
Me Me Me
O
Me O O  CH 2
Me3COK  Me3C  OH O O3 /Red Me
  Me  
Me Bulky base
(Hofmann elimination)
Less-substituted alkene H
Br Propanal Methanal
55.
56. Conceptual
57. Conceptual
58. More the e -withdrawing group, more is the NA reactivity
Cl3C  CHO  HCHO  PhCHO  MeCOMe
Chloral
CH 2OH
OH
* O
* OH *
*
HO *
59. OH Five chiral centres
60. Reaction of (X) with Br2 + KOH suggests that (X) is an amide. Carbylamine test and
coupling reaction of (Y) suggest that (Y) is 1o aromatic amine.
Br2  KOH NaNO2  HCl Phenol
PhCONH 2 Hofmann
 PhNH 2   Ph  N  N  Cl   Azo dye
bromamide
X  reaction Y 
CHCl3  KOH

 
Ph  N  C
MATHS
61. Solving we get x  4 x  32  0  x  2, 2
4 2

2 x2 
  dx
8
 The area is S    2
2  x  4 4 
62. Number divisible by 2 and 3 is divisible by 6 case (i) delete 0
i) fix 2 in units place ----> 4!
ii) fix 4 in units place ----> 4!
Case (ii) delete 3
i) fix 0 in units place ------>4!
ii) fix 2 in units place ------> 4!-3! iii) fix 4 in units place ----> 4! – 3!
63. C20  C12  .......  C2n   2n Cn   1000

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Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-C(9th Jan)_Key & Sol’s
Which is satisfied by n  1, 2, ........, 6 only
Max. value of n is 6
64. Either a girl will start the sequence or will be the second position and will not required
the last position as well.
3
C1  2 C1 5 1
Required probability 5
 
C2 10 2
10 16.3  23  32 154
65. Correct mean    15.4
10 10
66. p  q is logically equivalent to ~ q ~ p

 (p  q)  (~ q  ~ p ) is a tautology but not a contradiction.

5
67. Solving given equations we get x 
3  4m
x is an integer, if 3  4m  1,  5
2 4 2 8
 m   , , ,
4 4 4 4
So m has two integral values.
68. Pointsare  2, 1 ,  2, 1 and 1, 0 
2 1
1 2 1 1
 Required area  | | 4  2 sq unit.
2 1 0 2
2 1
69. Equation of
1
 bisector of AB is  L  1, 4  y  4    x  1  slope of AB  0   x  1
0
…………(ii)
Solving Eqs. (i) and (ii) we get the coordinates of the centre of the circle as (1, 2)
2 2
 OL  1  1   4  2  2
 BC  2OL  4 units
AB  8 units
2
70.  x  6  y 2  2  tangent is y  m  x  6   2m 2  2
It is passing through (4, 0) focus of parabola
0  2m  2m2  2  2m2  2  4m2
m 2  1  m  1
71. Clearly race course is an ellipse with the flag-posts as its foci.
x2 y2 x2 y 2
72.   1 and  1
a 2 b2 a2 B2
a 2  b 2  4 R 2  a 2  2  e12  and a 2  B 2  R 2  a 2  2  e22 

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Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-C(9th Jan)_Key & Sol’s
2
2  e1
4 2
 4 e 2 2  e12  6
2  e2
73. P3  Q3 and P 2Q  Q 2 P gives

P 3  P 2Q  Q 3  Q 2 P

P 2  P  Q   Q 2  P  Q 

  P 2  Q2   P  Q   0 the possible value of det  P 2  Q 2  is 0

74. f (0)  lt f(x)

x 0

75. Apply L hospital and Newton Leibnitz formula

x 3 y 6 z x  2 y 1 z  6
76. Lines L1    and L2   
4 3 2 4 1 1
Let shortest distance  d
  
d
 
a1  a2 . b1  b2
 

b1 b2
 
a1  3iˆ  6 ˆj ; a 2  2iˆ  ˆj  6kˆ
 
b1  4iˆ  3 jˆ  2kˆ ; b2  4iˆ  ˆj  kˆ
5iˆ  7 ˆj  6kˆ .iˆ  4 ˆj  8kˆ 
d 9
iˆ  4 jˆ  8kˆ
       2
77. b  c  a  a b c   a .a  a
 
   2 2
Similarly a b c   b  c
 
     
 a  b  c  a b c 
 
        2
Now b  c c  a a  b   a b c 
   
     2
 a b c   a b c 
   
  
But a b c   0
 
   
So a b c   1
 
  
Hence a  b  c  1
78. Let n1  3,  2, 1, n 2  4,  3, 4, n 3  2,  1, m 
Then n1  n 2 is parallel to the line and  to normal n 3 to the given plane
 n1 n 2 .n 3  0 or n1 n 2 n 3   0  m  2

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Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-C(9th Jan)_Key & Sol’s
79. For  3,9   R,  9,3  R
 Relation is not symmetric which means our choices (1) and (2) are out of question.
We therefore need to prove reflexivity and transitivity.
For reflexive a  A,  a , a   R which holds, i.e., R is reflexive. Again, for transitivity of
 a, b   R,  b, c   R
  a, c   R which is also true in R   3,3 ,  6,6  ,  9,9  , 12,12  ,  6,12  ,  3,9 ,  3,12  ,  3,6  .
80. The number of ordered pairs is 3  3  3  3  3  35
[ Every element has 3 options, either it can be in y but not in z, or it can be in z but
not in y or it can be neither in y nor z]
81. dt 1 1 1  1 1  t  ; A  B 2  1
   2  2
dt    tan 1  c

t2 2  t2  2 t 2t  2t 2 2  2
  2 
4 2 4 8 2
82.  cos x   1   1  u
u 
0
 sin x
 dx 
 cos x  0  1  tan x  dx , put x =2t  2 0  1  tan 2t  dt  2.v  v  2
3
83. ydx  xdy  3x 2e x . y 2 dx  0
ydx  xdy
y 2
3
 d ex  0 
x 3

 
d    d ex  d c 
 y
x 3
 ex  c
y
 1, x 1
84. f 1  x   2
 3 x , x  1
 In 1,   f is increasing in  ,1 f is decreasing  f has min. at x  1
 f 1   f 1   a  1  1  1  0
  a  1  0  a  1
85. Equation is true only when sin 2 y  1 tan 4 x  1
 
x , y
4 2
86.

6mt

h
 

2 3
x

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Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-C(9th Jan)_Key & Sol’s
h h6

x x2 3
hx  2 3h  xh  6 x
h
 3
x
   60 o
1 4  1 1 
87. sn     4   
tn (n  2)(n  3)  n 2 n3
 1 1   1 1   1 1 
s2015  4          .......    
 3 4   4 5   2017 2018  
1 1  4(2015) 8060 4030
 4    
 3 2018  3(2018) 6054 3027
1 1 1 1
 
H1  2 H 20  3 2 H1 3 H 20
88.   
H1  2 H 20  3 1  1 1

1
2 H1 3 H 20
1 1 1 1
 d  d
2 2 3 3 1 1
   40(as  21 d  )
1 1 1 1 2 3
d  d 
2 2 3 3
89.  2  1, 2   8
( 2 ) ( 2  )  8    2
1 17 1 33
   ,  4  p     2  ; q   2    16  
2 4 2 2
r r pq  17 33 
is AM of p,q   r  4     83
8 8 2  4 2 
90. Conceptual

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