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Abstract
This paper proposes to use a suitable liquid desiccant to extract 6esh water from the humid atmosphere. The
night-time moisture absorption and the day-time moisture desorption take place in the same unit. It consists of a flat,
blackened, tilted surface and is covered with a single glazing. During the night, the strong absorbent flows down as
a thin film over the glass cover in contact with the humid ambient air. Due to absorption of moisture from the ambient
air at night, the absorbent becomes diluted. In order to recover the fresh water from the weak absorbent, it flows
down as a thin film over the absorber during the day and is heated by solar energy. The water that evaporates from
the absorbent rises to the glass cover by convection where it is condensed on the underside of the glass cover. The
absorbent leaving the unit becomes strong and ready for moisture absorption at night. The performance of the unit
was computed analytically for typical summer climatic data for the month of August in Dhahran, Saudi Arabia, by
solving the energy balance equations. It is shown that for the given operating conditions it is possible to obtain about
1.92 kg of water per m2 of the unit. The influence of absorbent concentration and its flow rate on the performance
of the system are briefly discussed in the paper.
Keywords: Fresh water; Atmosphere; Saudi Arabia; Liquid desiccant; Absorption; Desorption
double pipelines. However, salt water or in other humidity and temperature as illustrated in Figs. 1
words, seawater, is needed for desalination plants and 2. Hence, an attempt is made to obtain fresh
and the seawater always has the tendency for water from the atmosphere, and this paper
scale formation and fouling problems due to presents some of the preliminary analytical
dissolved salts and finely suspended solids. results obtained from a cost effective system to
Hence, a low cost and renewable method is extract fresh water from the atmosphere.
required for areas where no salt water is
available.
The ambient atmosphere contains a large
2. Obtaining fresh water from the earth
quantity of water in varying amounts since water
continuously rises into the air in the form of Although this paper deals with the problem of
vapor, not only from bodies of water but also obtaining fresh water from the atmosphere, some
from the surfaces of plains, fields, mountains, and thoughts were given to obtain fresh water from
hills. A vast amount of water also exists under the the earth also. Kobayashi [ 1] reported an
ground in certain areas. In recent years the experimental method of obtaining fresh water
problem of obtaining fresh water from the from the earth in arid lands as well as in desert
atmosphere has received more attention and this areas. Since Saudi Arabia is a desert country,
endless source of fresh water can be recovered for attention was focussed on obtaining water from
general domestic use. the earth in desert areas.
Dhahran (26.32”N, 50.13 ‘E) is situated just Deserts can be broadly divided into two
north of the Tropic of Cancer on the eastern categories. One type is mostly composed of
coastal plain of the Kingdom of Saudi Arabia and coarse sand lies heaped in mounds. The other
is nearly 10 km inland from the Arabian Gulf. type has extremely dry ground with a sparse
Total annual precipitation is about SO mm in scattering of short grass that manages to exist in
Dhahran. The typical summer climatic conditions spite of the insignificant rain. In general, these
in Dhahran for the month of August indicate high two types combine to form a desert. It is expected
Ambientirmpw~turr
, _. _ Wind v~locily
10 30.0 I I I f 1 I I 1 I 1.5
1 0 9 10 11 12 1 2 3 1 5 6
pm I
C%k time
---
_..
-.-
-
Insolation
Ambient lamp.
Whd velOCity
iwollw humidity
95
90
I I
, 3 10 11 12 _I55 1 2 3
p5m
NOOtY
Clock time
point temperature. Nebbia [3] has reported process is heating the air to about 300°C using
experiments on the condensation of moisture gasoline burner and circulated with fan through
from the air using conventional fuel-driven vapor the bed. It evaporates the captured water in the
compression refrigeration machinery. The air desorption process. Finally, the hot water vapor is
entering the unit flows over the elements of the condensed and cooled in the third process using
cooling system and the water condensing on the air-cooled condenser. The water production and
evaporator coil is collected as the fresh water. It fuel consumption are reported for various
is also reported that the energy consumption was climatic conditions. A similar system using
high due to low heat exchange process. Since the composite material for extraction of water from
amount of water collected was low with small the air is reported by Alayli et al. [7], but the
units, this method was suggested for emergency evaporation was accomplished by solar energy
use only. and about 1 1 of water per square meter of the
A similar study was recently conducted composite material was produced.
analytically [4] for the climatic conditions of It is to be noted that this system can operate at
UAE coastal regions, and it was reported that the lower temperatures but requires large volumes of
quantity of fresh water obtained depends on the desiccant and also entails significant operating
properties of humid air, air velocity, cooling coil costs for the parasitic systems of blowers required
surface area, and the heat exchange arrangement. to circulate air streams. Further, as time
It is to be noted that this system uses chlorinated progresses, the efficiency of the desiccant bed
fluorocarbon compounds (CFCs) identified as will be reduced due to dust and foreign matter
contributors to depletion of the ozone layer. deposited in the pores. To avoid this, additional
air filtering can be added but only at the cost of
3.3 Adsorption method additional air pressure drops through the system.
transferred by suitable tubing to the entrance of will be carried out during the day in the same
the conventional roof-type solar still to separate unit.
the product water from the absorbent. A The desired absorbent characteristics for this
composition-psychrometric chart was constructed research are:
and used to demonstrate how water recovered can high solubility and low vapor pressure at
be changed with change in different operating absorbing conditions
conditions. In fact, Hollands [9] investigated the low viscosity and low heat of absorption
regeneration of a liquid desiccant in a roof-type under operating conditions
solar still. It is reported that when the still was high thermal conductivity and stability against
acting as a desalinator for producing potable thermal decomposition
water from brackish water, the efficiency was low density and low freezing point
56% and when it was used for regenerating the low toxicity and low corrosivity
weak desiccant, the efficiency was in the range of low cost and should be readily available.
5-20% depending upon the insolation and the Since calcium chloride satisfies most of the
concentration of the desiccant. The reduction in requirements, the same is chosen as the absorbent
efficiency is attributed to the lower partial for this research.
pressure of the desiccant compared with saline
water at a given temperature.
An analytical procedure for calculating the 5. Description of the proposed unit
mass of water absorbed by a desiccant from the
atmosphere in a slanted absorber is reported by The schematic of the proposed unit is shown
the authors [lo]. In this paper, a method is in Fig. 5. It consists of a flat, blackened, tilted
proposed to absorb moisture from the atmosphere surface and is covered by a single glazing with an
and to drive off the moisture and condense the air gap of about 45 cm. The bottom of the unit is
vapor stream in the same unit. well insulated. At night, the strong absorbent
flows down as a thin film over the glass cover in
contact with the ambient air. If the vapor pressure
of the strong desiccant is less than the vapor
4. Absorbent characteristics
pressure of water in the atmospheric air, mass
For designing a unit to produce fresh water transfer takes place from the atmosphere to the
from the atmosphere by absorption with subse- absorbent. Due to absorption of moisture from the
quent recovery using solar energy, a number of ambient air during the night, the absorbent
factors have to be taken into account. They becomes diluted. The water-rich absorbent must
include climatic variables such as insolation, be heated during the day to recover the water
wind velocity, ambient temperature and humidity, from the weak absorbent. Therefore, during the
concentration of the absorbent, initial temperature day, the weak desiccant flows down as a thin film
and the flow rate of the absorbent. Two processes over the absorber surface. The weak absorbent is
are required to extract fresh water from the heated by solar energy, and the water that
atmosphere by the absorption method. They are: evaporates from the solution rises to the glass
(1) the absorption process and (2) the cover by convection where it is condensed on the
evaporation-condensation process. In order to underside of the glass cover and the absorbent
make the system attractive and cost effective, leaving the unit becomes strong. The performance
both processes must be conducted in the same of the unit at night depends on the potential for
unit. The absorption process will be carried out at mass transfer, which is the difference in water
night and the evaporation-condensation process vapor pressure between the ambient air and the
H. I. Abualhamayel, P. Gandhidasan /Desalination I I3 (1997) 51-63 57
Day-time operation
Night-Time Operation
absorbent film on the glass cover, whereas the desorption rate per unit area have been
performance of the unit during day-time determined for different flow rates of desiccant.
operation depends on the difference in water They have been computed for the climatic data
vapor pressure between the absorbent film and pertaining to Dhahran for the month of August as
glass cover. The vapor pressure of water to be shown in Figs. 1 and 2.
condensed on the glass cover is a function of the When the absorbent flows over the glass cover
glass temperature, and hence it must be kept at night and on the absorber surface in the day-
minimum. For this purpose, the glass must be time, its temperature, concentration, and hence its
placed away from the absorber surface. vapor pressure vary along the flow length of the
As an alternative to the proposed arrangement, unit. However in the present analysis, the
the absorbent solution can be permitted to flow as arithmetic mean of these values between inlet and
a thin film over the absorber surface during the outlet of the unit are used. Further, it is assumed
night-time operation by removing the glass cover. that the areas of the glass cover and absorber
surface are equal, and steady-state conditions
prevail in the unit. The back and edge losses are
6. Mathematical model assumed to be small. The following energy
In this paper, an analysis has been carried out balance equation for a unit absorber area can be
for predicting the performance of the unit. By written for the day-time operation:
making use of energy balance equations, the rate
of absorption at night and the rate of desorption at
day-time intervals of 1 h have been computed.
Any change in the pattern of climatic conditions
(1)
- 2 GS CS (tS- t,,i) - m hfg = 0
being about a change in the performance of the
unit. The variation of the desiccant temperature
and the rate of water absorption as well as water When the absorbent flows down on the glass
58 H.I. Abualhamayel, P. Gandhidasan / Desalination 113 (1997) 51-63
cover in the night-time, the energy balance night-time operation, the constants were:
equation becomes a=-31.26, b=0.629, and c=lOOl.S.
An approximate equation which relates the
rate of desorption, solution flow rate, initial and
(2) average value of concentration of absorbent
solution is given by
-1
(8)
(3)
The mass of water evaporated from the absorbent By combining Eqs. (2), (5), (6), and (S), an
during the day-time operation is given by expression for the mass of water absorbed by the
absorbent solution from the atmosphere at night
(4) can be obtained and is given by
ml = Pl(k-ps) (5)
(6)
0.26 r
I
- Desiccanl
iemp.
0.23 -
0.22 -
0.2t -
0.2 -
Moss of waler _ 70
collected
_ 65
0 9 10 11 12 1 2 3 4 5
am Noon Pm
Clock time
L5X cq
_.-
35x
30%
0 1 5 10 15 20 25
I I
5 10 1s 20 25
0.6
G, = IOkgIhm’
Fig. 10. Effect of ambient temperature and humidity on the water absorption rate.
period of time and hence, the rate of desorption is summer climatic conditions of Dhahran, Saudi
less. Further, as the absorbent concentration Arabia, the diurnal variation of rate of absorption
decreases, the rate of desorption increases due to of water at night and the water desorption rate
increase in potential for mass transfer. during the day were calculated using the energy
The study was extended to analyze the effect balance equations. It was found that the increase
of ambient temperature and humidity on the in absorbent solution flow rate increases the rate
system peformance for the desiccant concen- of absorption of water from the atmosphere but
tration of 35% calcium chloride solution at a flow decreases the desorption rate of water during day-
rate of 10 kg/hm2, and the results are shown in time operation. Experimental studies are in
Fig. 10. For any particular condition of humidity, progress, and economic study is needed to
as the ambient temperature increases the rate of determine its feasibility.
absorption of water also increases during the
night due to the high potential for mass transfer,
which is the difference between the partial
9. Symbols
pressure of water vapor in the atmospheric air and
the desiccant film. As the ambient humidity c - specific heat, kJ/kg “’
decreases, the mass of water absorbed by the G - mass flow rate, kg/hm2
desiccant also decreases due to low potential for h - total (convection and radiation) heat
mass transfer. transfer coefficient, W/m2 “’
hfg -
atent heat of vaporization, kJ/kg
hfgl
- latent heat of condensation, kJ/kg
8. Conclusions
I - incident solar flux, kJ/hm2
A method has been proposed to extract fresh m - mass of water evaporated, kg/hm2
water from the humid atmosphere. For typical ml - mass of water absorbed, kg/hm2
H.I. Abualhamayel, P. Gandhidasan / Desalination 1 I3 (I 997) 51-63 63