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Subject : Thermodynamics
Date of test : 10/02/19
Answer Key
Detailed Explanations
1. (c)
Quasi means almost. Every state in quasi-static process through which system passes remains almost in
equilibrium.
4. (b)
The maximum inversion temperature of hydrogen and helium are 200 K and 24 K, so on throttling, the
temperature of both will increase.
5. (a)
For charging of an evacuated adiabatic chamber, Tf = γTL
where Tf = final temperature
cP
γ = c
V
6. (b)
T2 448
1− = 1−
700 T2
7. (b)
V2
dW = ∫ pdV = p(Vf – Vi) = 0.1 × (0.15 – 0.3)
V1
8. (c)
Wnet = (T1 – T2) (s1 – s2)
= (723 – 353) (2.5)
= 925 kJ/kg
9. (a)
At constant entropy, the phase change of a saturated liquid does not take place by increasing the
temperature. Thus, the resulting state will also be a liquid.
10. (d)
Tds = dh – vdp
At constant pressure dp = 0
dh
So, = T
ds P
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CT-2019 | ME • Thermodynamics 7
13. (d)
Decrease in potential energy = Increase in heat energy
mgh = mc∆t
1 × 9.81 × 100 = 1 × 4186 × ∆ t
981
∆t = = 0.234°C
4186
14. (b)
(T1 − T2 ) 2000 × 300(600 − 400)
Loss of available energy = Q1T0 T T = = 500 kJ
1 2 600 × 400
18. (b)
∆ PE = mg (h2 – h1) = 50 × 9.81 × 40 = 19620 J
∆ KE =
1
2
( 1
)
m V22 − V12 = × 50 × (302 − 102 ) = 20,000 J
2
Q1 – 2 = 30,000 J
W1 – 2 = Work delivered – Work received
= 0.002 × 1000 × 3600 – 4500 = 2700 J
For non-flow process,
Q1 – 2 = W1 – 2 + dE
Q1 – 2 = W1 – 2 + dU + ∆KE + ∆ PE
dU = 30,000 – 2700 – 20,000 – 19620
= – 12320 J
19. (a)
From the relation,
Tds = du + pdV
0
dT P dT dV
ds = Cv + dV = Cv +R
T T T V
Upon integration,
dT
s2 – s1 = ∫ Cv T
800 0.65
= ∫273 T
+ 0.0002 dT
800
= 0.65 l n + 0.0002(800 − 273)
273
= 0.6988 + 0.1054 = 0.8042 kJ/kgK
20. (b)
Revolutions made by the workpiece in 10 min,
N = 180 × 10 = 1800
0.3
Torque, T = Force × radius = 100 × = 15 Nm
2
Work done on the work piece
δW = 2πNT = 2π × 1800 × 15 = 169646 Nm(or J)
(work will be –ve sign since it is being done on the work piece)
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8 Mechanical Engineering
δQ = δW +δU
δQ = – 169.64 + 125 = – 44.64 kJ
21. (b)
Internal energy U = f (T )
= Constant for isothermal process
∴ U1 = U2
Change in Gibbs free energy, for an isothermal process is
P2
∆ G = RT ln P
1
22. (d)
Rmol 8314
Gas constant, R = = = 296.93 J/kg.K
Molecular mass 28
PV 1× 105 × 0.03
m = 1 1
= = 0.0348 kg
RT1 296.93 × 290
T P
Change in entropy, (S2 – S1) = m Cp l n 2 − R l n 2
T P1
[isothermal process → T1=T2 ]
1
P2
(S2 – S1) = −mR l n
P1
4
= − 0.0348 × 296.93 l n
1
= – 14.324 J/K
23. (c)
Work done in 2.5 hrs = VIT
12 × 8 × 2.5
= × 3600 = 864 kJ
1000
Non-flow energy equation,
δQ = δW + dU
δQ = 864 – 1250 = – 386 kJ
24. (a)
n
P2 T2 n −1 2
P = T n
1 1 PV
n −1 P
T2 P n
= 2
T1 P1 1
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T n − 1 P2
l n 2 = ln
T1 n P1
n −1 l n (T2 / T1 )
=
n l n (P2 / P1 )
n −1 l n(393 / 293)
= = 0.2118
n l n(6 / 1.5)
So, n = 1.2687
25. (d)
We know efficiency of Carnot engine operating between temperature limits TH and TL is
TL
η = 1−
TH
T T
∴ 2 1− L = 1 − L
TH TH ′
TLTH
∴ On solving, TH′ =
2TL − TH
26. (c)
For the reversible engine: T1= 1400 K
Q1 T Q1
= 1
Q2 T2
E P T3= 300 K
For the reversible pump: Q3
Q3 T Q2 Q4
= 3 T2= 400 K
Q4 T4
Since, the entire output of the heat engine is utilized to drive the pump,
Q1 – Q2 = Q4 – Q3
T2 T
Q1 − Q1 = Q4 − 3 Q4
T1 T4
Q1 T1 T4 − T3
Q4 = T4 T1 − T2
400 Q
100 = Q1 + 1 = 3.14 Q1
1400 0.35
∴ Energy taken from the reservoir at 1400 K,
100
Q1 = = 31.82 kJ/s
3.14
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27. (d)
From the principle of energy conservation,
heat given by hot gases = heat gained by water
(mCp ∆t )gas = (mCp ∆t )water = heat transfer (Q )
mg × 1.08 × (180 – 80) = 0.25 × 4.186 × (60 – 30) = Q
∴ mg = 0.2907 kg and Q = 31.395 kJ/s
T2g
(dS)gases = mgCpg l n
T1g
80 + 273
= 0.2907 × 1.08 × l n = – 0.078 kJ/K
180 + 273
T 60 + 273
(ds)water = mwCpw l n 2w = 0.25 × 4.186 × l n
T1w 30 + 273
= 0.098 kJ/K
∴Entropy production as a result of heat transfer is
(ds)net = (ds)gases + (ds)water
= – 0.078 + 0.098 = 0.02 kJ/K
Rate of increase in unavailable energy (or loss of available energy)
= T0 (ds)net
= (273 + 27) × 0.02
= 6 kJ/s
28. (d)
TH
(COP)heat pump =
TH − TL
800°C house 22°C
22 + 273
= = 14.75
20
QH HE HP
Power input to the heat pump =
COP
62000
= = 4203 kJ/h
14.75 20°C 2°C
1
(Winput)HP = W
2 HE
WHE = 8406 kJ/h
TL 293
ηHE = 1 − = 1− = 0.727
TH 1073
WHE 8406
QS for the heat engine = = = 11560 kJ/h
ηth 0.727
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11560
Heat supply to the heat engine = = 3.21 kW
3600
29. (a)
(∆S )universe = (∆S )system + (∆S )surrounding
T2 Q
= mC l n −
T1 T
363 1× 4.18(90 − 0)
= 1 × 4.18 l n −
273 363
= 1.191 – 1.036
= 0.155 kJ/K
30. (d)
In the absence of any other information regarding vg and vf , the Clausius Clapeyron equation can be used
to determine the saturation temperature corresponding to the given pressure.
∂P hfg ·P
∂T =
sat RT 2
hfg 1 T2
⇒ [ln P ]P
P2
1
= −
R T T1
P h 1 1
⇒ ln 2 = fg −
P1 R T1 T2
250 2257 1 1
⇒ ln = −
101.325 8.314 373 T2
18
1 1
⇒ 0.903 = 4886.45 −
373 T2
T2 = 400.6 K
t2 = 127.6°C
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