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Inorganic Chemistry B
[Fe(CN)2(CH3NC)4]
dicyanotetrakis(methylisocyano)iron(II) or
dicyanotetrakis(methylisocyano)iron(0)
Rb[AgF4]
rubidium tetrafluoroargentate(III) or
rubidium tetrafluoroargentate(1–)
[Ag(NH3)2][BF4]
diamminesilver(I) tetrafluoroborate(III) or
diamminesilver(1+) tetrafluoroborate
[Co(N3)(NH3)5]SO4
pentaammineazidocobalt(III) sulfate or
pentaammineazidocobalt(2+) sulfate
[V(C2O3)3]3
tris(oxalato)vanadate(III) or
tris(oxalato)vanadate(3–)
Bis(en)Co(III)--amido--hydroxobis(en)Co(III) ion
-oxo-bis[pentaamminechromium(III)] ion
cis -Diamminebromochloroplatinum(II)
Tetrahedral d6
[Co(H2O)6]2+
Cr(H2O)6]3+
octahedral d3, 3 unpaired electrons
a square-planar d7 ion
[Cr(H2O)6]2+
n=4
[Cu(en)2(H2O)2]2+
n=1
[Co(CO)4] 0 0 0
MnO4 0 0 0
[Fe(H2O)6]3+ 5 5.9 0
3H
4
V(III) is a d2 ion
v2 = 21,413 cm–1
and v1 = 14,409 cm–1
v2/v1 = 1.49
From the Tanabe-Sugano diagram at o/B = 34.5
v1: E/B = 29
E = 29 B =14,409 cm–1
B = 497 cm–1
v2: E/B = 44
E = 44 B = 21,413 cm–1
B = 487 cm–1