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Test - 3A (Paper - 1) (Code-E) (Answers) All India Aakash Test Series for JEE (Advanced)-2020

All India Aakash Test Series for JEE (Advanced)-2020


TEST - 3A (Paper-1) - Code-E
Test Date : 24/02/2019

ANSWERS
PHYSICS CHEMISTRY MATHEMATICS
1. (A) 21. (B) 41. (C)

2. (C) 22. (D) 42. (A)

3. (B) 23. (D) 43. (B)

4. (C) 24. (A) 44. (C)

5. (A) 25. (B) 45. (B)

6. (A) 26. (B) 46. (C)

7. (A, C) 27. (A, C, D) 47. (A, B, C)

8. (A, B, C) 28. (B, C, D) 48. (A, C)

9. (B, C) 29. (B, C, D) 49. (B)

10. (A, C) 30. (A) 50. (B)

11. (B, C) 31. (B) 51. (C)

12. (A, D) 32. (A, C) 52. (B)

13. (A, B) 33. (A, B, C) 53. (C)

14. (A, B) 34. (A, B, C) 54. (A)

15. (B, C) 35. (B, C) 55. (B)

16. A  (R) 36. A  (P, T) 56. A  (Q, S)

B  (Q, T) B  (P, Q, R, S, T) B  (Q, R, S, T)

C  (Q, T) C  (P) C  (R, S, T)

D  (P, S) D  (P, Q, R, S) D  (R, S, T)

17. A  (Q, T) 37. A  (Q, R, T) 57. A  (R, T)

B  (R) B  (P, S) B  (Q, R, T)

C  (P) C  (Q, R, T) C  (Q, R, T)

D  (Q, S, T) D  (Q, R, T) D  (Q, R, S, T)

18. (03) 38. (07) 58. (04)

19. (03) 39. (06) 59. (05)

20. (09) 40. (04) 60. (02)

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All India Aakash Test Series for JEE (Advanced)-2020 Test - 3A (Paper - 1) (Code-E) (Hints & Solutions)

HINTS & SOLUTIONS


PART - I (PHYSICS)
1. Answer (A) 3. Answer (B)
Hint:
I
Hint: T = 2 Based on Doppler effect observer will observe the
Mgd
frequency of wave which is emitted by source.
Solution: Solution:

 M 2 M 2  0 (v ) vs
I =  12  16   = (v  v cos )
s

  
  cot 
7M 2 
I= v sin  vs
48
vs = v cos
2
7M 
2 0
T=  
48  Mg sin2 
4

4 3
sin = , cos =
2 7  5 5
=
2 3g
4. Answer (C)
Hint:
7
= 
3g Calculate the effective phase difference at point P.
Solution:
2. Answer (C)
Hint:  2 2 
   3 cos   3   6 P
Add the total no. of mole by  

Pdv 2  
6 cos   6
using :  dn   RT 3 S1 S2

Solution: 1
3 cos   3
3
 T  T0 
T = T0   L x
 L  8
cos    
PA dx = dn RT 9

 = cos–1 (8/9)
T0 n
PA dx
R T T
  dn
Y
L 0  tan 
D

PV  TL  Y 17
n = (T  T )R ln  T  
L 0  0 D 8

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Test - 3A (Paper - 1) (Code-E) (Hints & Solutions) All India Aakash Test Series for JEE (Advanced)-2020

5. Answer (A) 12. Answer (A, D)


Hint: Hint and Solution of Q. Nos. 10, 11 to 12
Temperature of each body will change based on their Hint:
heat capacity. Process for system will be adiabatic. More over work
Solution: done by external force will be used to raise the internal
energy.
dT1 kA
ms  (T2  T1 ) Solution:
dt 
dT2 kA fext dx = (P1 – P2) dV = 2nCvdT
2ms  (T2  T1 )
dt   1 1 
nRT    dV  2nCv dT
2ms  4  V0  V V0  V 
t n 
3kA 3 V V T 
(   1) dV  ln  
0 V2 2
6. Answer (A) 0 V  T0 
Hint: 13. Answer (A, B)
Heat flow through conductor is constant. 14. Answer (A, B)
Solution: 15. Answer (B, C)
Hint and Solution of Q. Nos. 10, 11 to 12
(b  r )
Req  Hint:
4k br
Based on equation of travelling waves
dT b(T1 T2 ) Solution:

dr (b  r )r
dy
7. Answer (A, C) P = B
dx
8. Answer (A, B, C)
 y 
9. Answer (B, C) vp = v s  
 x 
Hint and Solution of Q. Nos. 7, 8 to 9
Hint: P 
vp = v s  
Draw the corresponding PV diagram and calculate  B0 
corresponding quantities.
v s   
Solution: ap = B  t 
0  
P = kV v s P0
= B  x  vs
RT 0 0
 kV
V v s2 p0
ap 
RT = kV 2 B0 x 0
2nV = nT 16. Answer A(R), B(Q, T), C(Q, T), D(P, S)
Hint:
dV dT
2 
V T Heat flow across section will be constant. Temperature
gradient is inversely proportional to area.
dV 1
2  Solution:
VdT T
In all case heat current flow will be same. Use
10. Answer (A, C)
electrical analogy for heat circuit to compute
11. Answer (B, C) temperature and gradient.

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All India Aakash Test Series for JEE (Advanced)-2020 Test - 3A (Paper - 1) (Code-E) (Hints & Solutions)

17. Answer A(Q, T), B(R), C(P), D(Q, S, T) Solution:


Hint:
31 

Distance will be maximum when velocity of each is 4 2
same.
Solution: 2
1 =
3
This has to be solved using
Phasor diagram 1 = 600 Hz
A 19. Answer (03)
2Asin = 3A
Hint: T = constant


=  Solution :
3
 = 2 or 2 – 2 B d 1 
 
dT 3 T
2 4
= or
3 3 20. Answer (09)

When they are at same position. Hint:

   
x = A sin     
2  2
A0 A B
= Solution :
2  
N

2
18. Answer (03)
N=8
Hint:
 9 nodes
0 = 2

PART - II (CHEMISTRY)
21. Answer (B) Solution:
Hint:
O Non-aromatic
R Reductive R
C = CH2 ozonolysis C =O & H – C – H H
R R
Solution: B
CH 2 CH 2 Antiaromatic
B

O3 H
CH 2 6HCHO
Zn–H2 O 
CH 2
Aromatic
CH 2 CH 2
22. Answer (D)
Hint:
Aromatic
is non-aromatic compound as it is non-planar
molecule.

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Test - 3A (Paper - 1) (Code-E) (Hints & Solutions) All India Aakash Test Series for JEE (Advanced)-2020

23. Answer (D) Solution:


Hint: Basic strength  lone pair concentration. HCl 
CH = CH 2 CH – CH 3
Solution:
(+I) (+I)
Et Et CH – CH 3
Cl–
N NH 2 NH 2
Ph (–R) Cl

> > > NH hydride


CH3 CH 3 ring
 ion shift
expansion
Ph (–R) 
NO2 Cl–1
(–I, –R)
24. Answer (A)
Hint:
Cl
Na/
CH2 – (CH 2)4 – CH 2 dry ether
28. Answer (B, C, D)
Br Br Hint: 1, 2 & 1, 4 addition of HCl
Solution: Solution:
Cl2/h (Et) 2CuLi
CH4 CH3 – Cl CH 3 – CH2 – CH3
A B H

D alc KOH Cl2/h CH3 – CH = CH – CH = CH 2 CH3 – CH = CH – CH – CH3


CH3 – CH = CH 2 CH 3 – CH – CH3 Cl–
C CH3 – CH = CH – CH – CH 3
NBS
Cl
Na, Cl CH3 – CH – CH = CH – CH3
Br – CH2 – CH = CH2 dry ether CH2 = CH – CH2 – CH 2 (1-2-addition product) –
E F Cl
CH = CH 2
CH3 – CH – CH = CH – CH3
HBr/ Cl
Proxide
Na/ 1, 4 addition product
dry ether CH 2 –(CH 2)4 – CH2 – Br
G
Br
29. Answer (B, C, D)
25. Answer (B)
Hint: Electrophilic addition reaction
Hint: Properties of canonical structure.
Solution: Solution:

One canonical structure will not explain all the HBr & HCl
properties of molecule. both follow Br2
Markownikoff
26. Answer (B) with carbonium ion Br

rearrangement
Hint:
H Ring 30. Answer (A)
 opening
CH 2 – CH = CH 2
 Hint:
Solution:
H

carbonium ion
Br2/high temperature will do allylic substitution
 rearrangment
Solution:

CH2 – CH = CH 2 CH2 – CH = CH2 
H2 O O O–H O–H
O 
 –H
H H CH2 = CH – CH 2 – OH
H


27. Answer (A, C, D)
Hint: Carbonium ion rearrangement.

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All India Aakash Test Series for JEE (Advanced)-2020 Test - 3A (Paper - 1) (Code-E) (Hints & Solutions)
OH OH OH 34. Answer (A, B, C)
Hint:
 Ring  Deprotonation
 Expansion
Electrophilic aromatic substitution
(–H +)
Solution:
(P)

E
NBS CH2 O

OH More CH2
activating

(major)
Br (Q)
31. Answer (B) E
Hint:  bonds which are not the part of aromatic ring, 35. Answer (B, C)
can undergo addition reaction. Hint:
Solution: Friedel Craft alkylation reaction
OH OH OH
Solution:
alc KOH Br 2
CH3 Me

& has greater electron


Br Br
Br CH3 Me Me
(Q) (R) (S)
32. Answer (A, C) density than CH3

Hint:
36. Answer A(P, T); B(P, Q, R, S, T); C(P), D(P, Q, R, S)
HO Hint: Alkene decolourise Br2/CCl4.
is aromatic compound.
Solution:
Solution:
+ H 2/Ni  CH3 – CH 2 – CH3
OH
It is aromatic
cyclic and stable
Compound R is Has acidic , , CH2 &
H-atom
CH
33. Answer (A, B, C) are unsaturated compound can give bromine water
Hint: test
CH4 + CH3 – C C Mg Br
– + –
Electrophilic aromatic substitution CH3 – C CH + CH 3MgBr
Solution:

O O Can react with


– C – CH 3 Na as it has acidic
– O – C – CH 3 (activating + R) & hydrogen atom
(deactivating i.e. – R) CH3 – C  CH
–Cl  deactivating
Hydrogen is
–O–CH3  more activating H acidic due to
aromaticity
–NO2  deactivating  aromatic

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Test - 3A (Paper - 1) (Code-E) (Hints & Solutions) All India Aakash Test Series for JEE (Advanced)-2020
37. Answer A(Q, R, T); B(P, S); C(Q, R, T); D(Q, R, T) 39. Answer (06)
Hint: Hint: Decarboxylation reaction
Reaction intermediate singlet carbene is sp 2 Solution:
hybridised.
Solution: O O
COOH COONa
R1 NaOH

C HOOC COOH NaOOC COONa


COOH COONa
R2 (salt)
electrolysis
Singlet carbene hybridisation is sp2. and have a vacant
2p orbital hence can behave like an electrophile. O
38. Answer (07)
+ 4 CO 2 (m = 4)
Hint: Kjeldahl method
Solution: Tautomerise

m.e of H2SO4 used for NH3 OH


= (25 × 2) – 30 × 0.5 × 2
(DBE = 4)
= 50 – 30 = 20
2m  d
 No. of m.e of NH3 = 20  6
2
% mass of nitrogen in organic compound 40. Answer (04)

(20)(14)  100 Hint: RMgX  RH


=
(1000)(4) Solution:

1.4 C6H5 SO3H, C 6H5OH


= 20 
4 NO 2 OH

2  14
= 7
4 ,

i.e 7 OH NH2

PART - III (MATHEMATICS)


41. Answer (C) Solution:

Hint: z  z  z – z  2 |x| + |y| = 1 |z1 + z2|2 + |z1 – z2|2 = 2(|z1|2 + |z2|2)

Solution: | – z3|2 + |z1 – z2|2 = 2(2)

zz  z–z 2 |x| + |y| = 1 |z1 – z2|2 = 3  | z1  z2 |  3

Locus of z is a square and z  i  z – i  2 Similarly | z2  z3 |2  | z3  z1 |  3

Locus of z is a straight line


Thus,  whose vertices are z1, z2 and z3 is equilateral
z = –i satisfies the given equations
triangle and its side is of length 3
42. Answer (A)
3
 3 3 3
2
3 2 Therefore, area of triangle  
Hint: Area = a 4 4
4

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All India Aakash Test Series for JEE (Advanced)-2020 Test - 3A (Paper - 1) (Code-E) (Hints & Solutions)

43. Answer (B) 47. Answer (A, B, C)


Hint : Number of exhaustive cases = 74 Hint:

Solution: 2 – 4  0
48. Answer (A, C)
Total no. of ways = (7)4
Hint:
7
Now no. of favourable case C2  (2  2)  21 14 4
2 – 4 > 0
49. Answer (B)
21 14 6
Now probability of required event  
(7)4 49 Hint:
44. Answer (C) z  –

Hint: greatest value of series when x1 = x2 = .....xn Solution for Q. Nos. 47 to 49


z2 + z + 1 = 0
Solution:
The value of the sum is greatest when x1 = x2 = ...    2  4
z
2
 
xn  and required value is n sin   Case 1
n n
–2 <  < 2
45. Answer (B)
2 – 4 < 0
Hint: sinx = cosecx and tany = coty
  i 4   2
Solution: z
2
sin x  cosecx  2 and tany + coty  2 
x  y 2  1 x2
2
So, sinx = 1, tany = 1
x2 + y2 = 1
 
 x , y Case 2
2 4
>2
y
tan    2  1 which satisfies t2 + 2t – 1 = 0 2 – 4 > 0
2
46. Answer (C)    2  4    2  4
z x ,y  0
2 2
Solution:
    2  4      2  4 
1 z1   ,0  , z2   ,0 
Put t  2   2 
n    
sin t One root lies inside the unit circle and other will lie
 1  sin t outside the unit circle.
 4   1 
  = lim  t   lim  2  Case 3
t 0 1 t 0 t (1  t 2 )
 
 2  1 
t  When  is very large


log l  lim – sin t log(t 2 (1  t 2 ))
t 0
     2  4 
z  z  
 2 
 
2log(t )  log(1  t 2 )
 lim
t 0 cosect
   2  4 2 1
z  
2 sin2 t 2    2  4 
 lim =0l=1
t 0 t cos t 50. Answer (B)

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Test - 3A (Paper - 1) (Code-E) (Hints & Solutions) All India Aakash Test Series for JEE (Advanced)-2020

51. Answer (C)  1 1


Now | z |2   1   1  | z |2 
52. Answer (B) 1  1  1 
Hint: Use projection formula | z |2

Solution: 1  | z |2
4 zz
cos( A  B )   2  ( z  z ) (1   ) 
5 1 | z |2

3 3 zz
 sin( A  B )  , tan( A  B )  
5 4 
2 1 | z |2 
2i 
 ( A  B)  zz
2 tan  1 

  2  3
zz
 AB 4 2i   ( z  z ) (1   ) 
1  tan2   1  | z |2
 2 

z  z  i
 AB 1 2 1 | z |2 
 tan  
 2  3 56. Answer A(Q, S); B(Q, R, S, T); C(R S, T); D(R, S, T)
 AB z
∵ is an acute angle
 2 Hint:
|z|
= unimodular

ab C 1 Solution:
 cot 
ab 2 3 z z
(A)  2i   2i
 C  90 |z| |z|

So triangle ABC is right angle triangle z


 unimodular complex no.
|z|
1 and lies on perpendicular bisector of 2i and –2i
Area of ABC   6  3 = 9 sq. units
2
z
   1  z   | z |  a real number
|z|
r 


9
s 363 5  2
3
 3 5   Im (z) = 0
  (B)  = ei
 2 
1  2 1  e 2i 
z   2cos 
1 3 5  ei 
Radius of the circumcircle = × hypotenuse 
2 2
(C) 2b = 8
53. Answer (C)
2be = 6 a2 = 7
54. Answer (A)
3
55. Answer (B) e=
4

 2  2 x2 y 2
Hint: z 
2
Equation of ellipse  1
(1   )2 7 16
(D) Iz – 2 – 3i| = 1
Solution:
( x  2)2  ( y  3)2  1
 2  2   2  x  2  cos , y  3  sin 
| z |2  2
 2

(1   ) (1   ) 1 
x  [1, 3], y  [2, 4]

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All India Aakash Test Series for JEE (Advanced)-2020 Test - 3A (Paper - 1) (Code-E) (Hints & Solutions)

57. Answer A(R, T); B(Q, R, T); C(Q, R, T); D(Q, R, S, T) 59. Answer (05)
Hint: x – 1  x Hint:
Solution:

sin x  cos x 1 z1  C is
lim 10
(A) lim(sin x  cos x )cosecx  e x 0 sin x
x 0

=e  3 
z2  C is   
n  10 
 4  n 10 
(B) L  lim  (1 form)
5 
n  
Solution:

 1  
lim z1  C is
Le n   4  (10) n  5  n 10
 5 
 
 3 
z2  C is   
1  10 
ln(10)
L e 5

1   3    3 
z1  z2   cos  cos  + i  sin  sin 
L  10 5  10 10   10 10 
L5
 2  10  2 5  10  2 5  1
5
z1  z2    i
xx  1  4  2
(C) xlim
0

 2 L= 2
3 5
| z1  z2 | 2 
5 x 2
(D) L  lim
x  x  
3 60. Answer (02)
Hint:
 x  x x
 3  1   3   3 |a – d|, |a|, |a + d| be three distances
 
Solution:
5  x  5 x 5 x
1   
x  3  x  3  x 3 As perpendicular distances are in A.P.

lim
Let |a – d|, |a|, |a + d| be these distances
5 x 5
x 
x  3  3 so the co-ordinates of point P are

58. Answer (04) (±(a – d), ± a, ± (a + d)

Solution: According to question


2a2 + d2 – 2ad = 5 ...(i)
sin   sin 2  sin3  0  sin2 (1 + 2cos) = 0
..(1) 2a2 + 2d2 = 10 ...(ii)
2 2
2a + d + 2ad = 13 ...(iii)
cos   cos 2  cos 3  0  cos2 (1 + 2cos) = 0
..(2) Solving (i), (ii) and (iii)
From (1) and (2) we get

1 a = ±2, d = ±1
cos   –
2 so points P (±1, ±2, ±3)
 Number of values of   [–2, 2] is 4 Now  = 1,  = 2,  = 3

  

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Test - 3A (Paper - 1) (Code-F) (Answers) All India Aakash Test Series for JEE (Advanced)-2020

All India Aakash Test Series for JEE (Advanced)-2020


TEST - 3A (Paper-1) - Code-F
Test Date : 24/02/2019

ANSWERS
PHYSICS CHEMISTRY MATHEMATICS
1. (A) 21. (B) 41. (C)

2. (A) 22. (B) 42. (B)

3. (C) 23. (A) 43. (C)

4. (B) 24. (D) 44. (B)

5. (C) 25. (D) 45. (A)

6. (A) 26. (B) 46. (C)

7. (A, C) 27. (A, C, D) 47. (A, B, C)

8. (A, B, C) 28. (C, D) 48. (A, C)

9. (B, C) 29. (B, C, D) 49. (B)

10. (A, C) 30. (A) 50. (B)

11. (B, C) 31. (B) 51. (C)

12. (A, D) 32. (A, C) 52. (B)

13. (A, B) 33. (A, B, C) 53. (C)

14. (A, B) 34. (A, B, C) 54. (A)

15. (B, C) 35. (B, C) 55. (B)

16. A  (Q, T) 36. A  (Q, R, T) 56. A  (R, T)

B  (R) B  (P, S) B  (Q, R, T)

C  (P) C  (Q, R, T) C  (Q, R, T)

D  (Q, S, T) D  (Q, R, T) D  (Q, R, S, T)

17. A  (R) 37. A  (P, T) 57. A  (Q, S)

B  (Q, T) B  (P, Q, R, S, T) B  (Q, R, S, T)

C  (Q, T) C  (P) C  (R, S, T)

D  (P, S) D  (P, Q, R, S) D  (R, S, T)

18. (09) 38. (04) 58. (02)

19. (03) 39. (06) 59. (05)

20. (03) 40. (07) 60. (04)

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All India Aakash Test Series for JEE (Advanced)-2020 Test - 3A (Paper - 1) (Code-F) (Hints & Solutions)

HINTS & SOLUTIONS


PART - I (PHYSICS)
1. Answer (A) 4. Answer (B)
Hint: Hint:
Heat flow through conductor is constant. Based on Doppler effect observer will observe the
Solution: frequency of wave which is emitted by source.

(b  r ) Solution:
Req 
4k br vs
0 (v )
dT b(T1 T2 )  = (v  v cos ) 
 s

dr (b  r )r
2. Answer (A)   cot 

Hint: v sin  vs
Temperature of each body will change based on their
vs = v cos
heat capacity.
Solution: 0

dT kA sin2 
ms 1  (T2  T1 )
dt 
4 3
dT kA sin = , cos =
2ms 2  (T2  T1 ) 5 5
dt 
5. Answer (C)
2ms ⎛ 4 ⎞
t n⎜ ⎟ Hint:
3kA ⎝3⎠
Add the total no. of mole by
3. Answer (C)
Hint: Pdv
Calculate the effective phase difference at point P.
using : ∫ dn  ∫ RT
Solution: Solution:

⎡ 2 2 ⎤ ⎛ T  T0 ⎞
⎢   3 cos   3 ⎥  6 P T = T0  ⎜ L ⎟x
⎣ ⎦ ⎝ L ⎠

2   PA dx = dn RT
6 cos   6
3 S1 S2
T n
1 PA 0 dx
R T∫ T
3 cos   3  ∫ dn
3 0
L

⎛8⎞
cos   ⎜ ⎟
⎝9⎠ PV ⎛ TL ⎞
n = (T  T )R ln ⎜ T ⎟
= cos–1 (8/9) L 0 ⎝ 0⎠
Y
 tan  6. Answer (A)
D
Y 17 I
 Hint: T = 2
D 8 Mgd

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Test - 3A (Paper - 1) (Code-F) (Hints & Solutions) All India Aakash Test Series for JEE (Advanced)-2020

Solution: Solution:

⎛ M 2 M 2 ⎞ fext dx = (P1 – P2) dV = 2nCvdT


I = ⎜⎜ 12  16 ⎟⎟ ⎡ 1
⎝ ⎠ 1 ⎤
nRT ⎢  ⎥ dV  2nCv dT
V
⎣ 0  V V0 V ⎦
7M 2
I= ⎛T ⎞
48 V V
(   1)∫ dV  ln ⎜ ⎟
0 V02 V 2
⎝ T0 ⎠
7M 2 13. Answer (A, B)
2
T= 
48  Mg 14. Answer (A, B)
4
15. Answer (B, C)
2 7  Hint and Solution of Q. Nos. 13 to 15
=
2 3g Hint:
Based on equation of travelling waves
7
=  Solution:
3g
dy
7. Answer (A, C) P = B
dx
8. Answer (A, B, C)
9. Answer (B, C) ⎛ y ⎞
vp = v s ⎜ ⎟
Hint and Solution of Q. Nos. 7 to 9 ⎝ x ⎠

Hint: ⎛P ⎞
vp = v s ⎜ ⎟
Draw the corresponding PV diagram and calculate ⎝ B0 ⎠
corresponding quantities.
v s ⎛  ⎞
Solution: ap = B ⎜ t ⎟
0 ⎝ ⎠
P = kV
v s P0
RT = B  x  vs
 kV 0 0
V
v s2 p0
RT = kV 2 ap 
B0 x 0
2nV = nT
16. Answer A(Q, T), B(R), C(P), D(Q, S, T)
dV dT Hint:
2 
V T Distance will be maximum when velocity of each is
dV 1 same.
2 
VdT T Solution:
10. Answer (A, C) This has to be solved using
11. Answer (B, C) Phasor diagram
12. Answer (A, D) 2Asin = 3A
Hint and Solution of Q. Nos. 10 to 12  A
=
Hint: 3

Process for system will be adiabatic. More over work  = 2 or 2 – 2 
done by external force will be used to raise the internal
2 4 B
energy. = or
3 3

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All India Aakash Test Series for JEE (Advanced)-2020 Test - 3A (Paper - 1) (Code-F) (Hints & Solutions)

When they are at same position. N=8


⎛ ⎞ A B  9 nodes
x = A sin ⎜   ⎟  
⎝ 2 ⎠
19. Answer (03)
A0
= Hint: T = constant
2
Solution :
17. Answer A(R), B(Q, T), C(Q, T), D(P, S)
Hint: d 1 
 
Heat flow across section will be constant. Temperature dT 3 T
gradient is inversely proportional to area.
Solution: 20. Answer (03)

In all case heat current flow will be same. Use Hint:


electrical analogy for heat circuit to compute
0 = 2
temperature and gradient.
18. Answer (09) Solution:

Hint: 31 

4 2
 

2 2
1 =
Solution : 3

N 1 = 600 Hz

2

PART - II (CHEMISTRY)
21. Answer (B)
Na/
Hint: CH2 – (CH2)4 – CH2 dry ether

H Ring
Br Br
 opening
CH 2 – CH = CH 2

Solution:
Solution:

 Cl2/h (Et) 2CuLi


H carbonium ion CH4 CH3 – Cl CH 3 – CH2 – CH3
 rearrangment
A B
D alc KOH Cl2/h
 CH3 – CH = CH 2 CH 3 – CH – CH3
CH2 – CH = CH 2 CH2 – CH = CH2 NBS
C
H2 O Cl
Na,
O Br – CH2 – CH = CH2 CH2 = CH – CH2 – CH 2
 –H E
dry ether
F
H H CH2 = CH – CH 2 – OH
CH = CH 2

22. Answer (B)


Hint: Properties of canonical structure.
Solution:
HBr/
One canonical structure will not explain all the Proxide
Na/
properties of molecule. dry ether CH2 –(CH2)4 – CH2 – Br
23. Answer (A) G
Br
Hint:

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Test - 3A (Paper - 1) (Code-F) (Hints & Solutions) All India Aakash Test Series for JEE (Advanced)-2020

24. Answer (D) 27. Answer (A, C, D)


Hint: Basic strength  lone pair concentration. Hint: Carbonium ion rearrangement.
Solution: Solution:

(+I) (+I) CH = CH 2 HCl
CH – CH 3
Et Et
N NH 2 NH 2
Ph (–R) CH – CH 3
Cl–
> > > NH Cl
Ph (–R) hydride
NO2 CH3 CH 3
 ion shift ring
expansion
(–I, –R) 
Cl–1
25. Answer (D)
Hint:

is non-aromatic compound as it is non-planar Cl


molecule. 28. Answer (C, D)
Solution: Hint: 1, 2 & 1, 4 addition of HCl
Solution:
Non-aromatic 
H
CH3 – CH = CH – CH = CH 2 CH3 – CH = CH – CH – CH3
H Cl–
CH3 – CH = CH – CH – CH 3
B Cl CH3 – CH – CH = CH – CH3
Antiaromatic (1-2-addition product) –
Cl
B
CH3 – CH – CH = CH – CH3
H
Cl
 1, 4 addition product

Aromatic 29. Answer (B, C, D)


Hint: Electrophilic addition reaction
Solution:

Aromatic HBr & HCl


both follow Br2
Markownikoff
with carbonium ion Br

rearrangement
26. Answer (B)
Hint: 30. Answer (A)
O Hint:
R Reductive R
C = CH2 C =O & H – C – H Br2/high temperature will do allylic substitution
R ozonolysis
R
Solution: Solution:
CH 2 CH 2

O O–H O–H
O3
CH 2 6HCHO
Zn–H2 O
H


CH 2

CH 2 CH 2

5/10
All India Aakash Test Series for JEE (Advanced)-2020 Test - 3A (Paper - 1) (Code-F) (Hints & Solutions)
OH OH OH 34. Answer (A, B, C)
Hint:
 Ring  Deprotonation
 Expansion (–H +) Electrophilic aromatic substitution

(P) Solution:
NBS 
E
CH2 O
OH
More CH2
activating

Br (major)
(Q)
31. Answer (B)
E
Hint:  bonds which are not the part of aromatic ring,
can undergo addition reaction. 35. Answer (B, C)
Solution: Hint:
OH OH OH
Friedel Craft alkylation reaction
alc KOH Br 2
Solution:

CH3 Me
Br Br
Br
& has greater electron
(Q) (R) (S)
CH3 Me Me
32. Answer (A, C)
Hint:
density than CH3

HO
is aromatic compound. 36. Answer A(Q, R, T); B(P, S); C(Q, R, T); D(Q, R, T)

Solution: Hint:

OH Reaction intermediate singlet carbene is sp 2


It is aromatic hybridised.
cyclic and stable
Compound R is Solution:
Has acidic
H-atom
R1
33. Answer (A, B, C)
C
Hint:
Electrophilic aromatic substitution R2
Solution:
Singlet carbene hybridisation is sp2. and have a vacant
O O
2p orbital hence can behave like an electrophile.
– O – C – CH 3 (activating + R) & – C – CH 3
37. Answer A(P, T); B(P, Q, R, S, T); C(P), D(P, Q, R, S)
(deactivating i.e. – R)
Hint: Alkene decolourise Br2/CCl4.
–Cl  deactivating
–O–CH3  more activating Solution:
–NO2  deactivating + H 2/Ni  CH3 – CH 2 – CH3

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Test - 3A (Paper - 1) (Code-F) (Hints & Solutions) All India Aakash Test Series for JEE (Advanced)-2020

O O
COOH COONa
NaOH
, , CH2 &
HOOC COOH NaOOC COONa
CH COOH COONa
are unsaturated compound can give bromine water (salt)
test electrolysis

CH4 + CH3 – C C Mg Br


– + –
CH3 – C CH + CH 3MgBr O

+ 4 CO 2 (m = 4)

Can react with


Tautomerise
Na as it has acidic


hydrogen atom OH
CH3 – C  CH
(DBE = 4)

H
Hydrogen is
2m  d
acidic due to
aromaticity
 6
 aromatic 2
40. Answer (07)
38. Answer (04)
Hint: Kjeldahl method
Hint: RMgX  RH
Solution: m.e of H2SO4 used for NH3
Solution: = (25 × 2) – 30 × 0.5 × 2 = 50 – 30 = 20
C6H5 SO3H, C 6H5OH  No. of m.e of NH3 = 20
NO 2 OH % mass of nitrogen in organic compound
(20)(14)  100
=
, (1000)(4)

OH NH2
1.4
= 20 
4
39. Answer (06)
2  14
Hint: Decarboxylation reaction = 7
4
Solution: i.e 7

PART - III (MATHEMATICS)


42. Answer (B)
41. Answer (C)
Hint: sinx = cosecx and tany = coty
Solution:
Solution:
1
Put t sin x  cosecx  2 and tany + coty  2
n
sin t So, sinx = 1, tany = 1
⎛ 1 ⎞
⎜ 4 ⎟ ⎛ 1 ⎞
sin t
 
  = lim ⎜ t ⎟  lim ⎜ 2 ⎟  x
2
, y
4
⎜⎜ 1  1 ⎟⎟
t 0 t 0 t (1  t 2 )
⎝ ⎠
⎝ t2 ⎠ y
⎛ ⎞
tan ⎜ ⎟  2  1 which satisfies t2 + 2t – 1 = 0
⎝2⎠

log l  lim – sin t log(t 2 (1  t 2 ))
t 0
 43. Answer (C)
Hint: greatest value of series when x1 = x2 = .....xn
2log(t )  log(1  t 2 )
 lim Solution:
t 0 cosect
The value of the sum is greatest when x1 = x2 = ...
2 sin2 t 
 lim =0l=1 xn  ⎛⎞
t 0 t cos t and required value is n sin ⎜ ⎟
n ⎝n⎠

7/10
All India Aakash Test Series for JEE (Advanced)-2020 Test - 3A (Paper - 1) (Code-F) (Hints & Solutions)
44. Answer (B) 49. Answer (B)
4
Hint : Number of exhaustive cases = 7 Hint:
Solution: z  –
Total no. of ways = (7)4 Solution for Q. Nos. 47 to 49
z2 + z + 1 = 0
Now no. of favourable case 7 C2  (24  2)  21 14
   2  4
z
21 14 6 2
Now probability of required event  4

(7) 49 Case 1
45. Answer (A) –2 <  < 2
3 2 2 – 4 < 0
Hint: Area = a
4
  i 4   2
Solution: z
2
|z1 + z2|2 + |z1 – z2|2 = 2(|z1|2 + |z2|2) 
x ⇒ y 2  1 x2
2
| – z3|2 + |z1 – z2|2 = 2(2)
x2 + y2 = 1
|z1 – z2|2 = 3 ⇒ | z1  z2 |  3 Case 2
>2
Similarly | z2  z3 |2  | z3  z1 |  3
2 – 4 > 0

Thus,  whose vertices are z1, z2 and z3 is equilateral    2  4    2  4


z ⇒x ,y  0
2 2
triangle and its side is of length 3
⎛    2  4 ⎞ ⎛    2  4 ⎞
z1  ⎜ ,0 ⎟ , z2  ⎜ ,0 ⎟
3
 3 3 3
2 ⎜ ⎟ ⎜ ⎟
Therefore, area of triangle   2 2
⎝ ⎠ ⎝ ⎠
4 4
46. Answer (C) One root lies inside the unit circle and other will lie
outside the unit circle.
Hint: z  z  z – z  2 |x| + |y| = 1 Case 3

Solution: When  is very large

zz  z–z 2 |x| + |y| = 1 ⎛    2  4 ⎞


z⎜ ⎟ , z  
⎜ 2 ⎟
Locus of z is a square and z  i  z – i  2 ⎝ ⎠

Locus of z is a straight line


   2  4 2 1
z  
z = –i satisfies the given equations 2    2  4 
50. Answer (B)
47. Answer (A, B, C) 51. Answer (C)
Hint: 52. Answer (B)
2 – 4  0 Hint: Use projection formula
48. Answer (A, C) Solution:
Hint: 4
cos( A  B ) 
 –4>0
2 5

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Test - 3A (Paper - 1) (Code-F) (Hints & Solutions) All India Aakash Test Series for JEE (Advanced)-2020

3 3 zz

⇒ sin( A  B )  , tan( A  B ) 
5 4 
2 1 | z |2 
2i 
zz
⎡ ( A  B) ⎤ 1 
2 tan ⎢ ⎥
⇒ ⎣ 2 ⎦ 3 zz
⎛ AB⎞ 4 2i   ( z  z ) (1   ) 
1  tan2 ⎜ ⎟ 1  | z |2
⎝ 2 ⎠

z  z  i
⎛ AB⎞ 1 2 1 | z |2 
⇒ tan ⎜ ⎟
⎝ 2 ⎠ 3
56. Answer A(R, T); B(Q, R, T); C(Q, R, T); D(Q, R, S, T)
⎧ AB Hint: x – 1  x
⎨∵ is an acute angle
⎩ 2 Solution:
sin x  cos x 1
ab C 1 (A) lim(sin x  cos x )cosecx  e x 0
lim
⇒ cot  sin x

ab 2 3 x 0

=e
⇒ C  90
n
So triangle ABC is right angle triangle ⎛ 4  n 10 ⎞
(B) L  lim ⎜ (1 form)
n  ⎝ 5 ⎟⎠
1
Area of ABC   6  3 = 9 sq. units 1
2 lim
⎛ ⎞
n  ⎜ 4  (10) n 5
⎟n
Le ⎜ ⎟
5
⎜⎝ ⎟⎠
r 


9
s ⎛363 5 ⎞ 2
3
 3 5  
⎜⎜ ⎟⎟ 1
ln(10)
⎝ 2 ⎠ L  e5
1
1 3 5 L  10 5
Radius of the circumcircle = × hypotenuse 
2 2 L5
 2
53. Answer (C) 5
54. Answer (A) (C) xlim xx  1
0

55. Answer (B)  2 L= 2

2  2  2 5 ⎡x⎤
Hint: z  (D) L  lim
(1   )2 x  x ⎢⎣ 3 ⎥⎦
Solution:
⎛ x ⎞ ⎡x⎤ x
⎜⎝ 3  1⎟⎠  ⎢ 3 ⎥  3
⎣ ⎦
 2  2   2 
| z |2   
(1   ) 2
(1   )2 1  5 ⎛ x ⎞ 5 ⎡x⎤ 5 x
1   
x ⎜⎝ 3 ⎟⎠ x ⎢⎣ 3 ⎥⎦ x 3
 1 1
Now | z |2   1  ⇒ 1  | z |2  lim 5 ⎡x⎤ 5
1  1  1  x 
x ⎢⎣ 3 ⎥⎦ 3
| z |2
 57. Answer A(Q, S); B(Q, R, S, T); C(R S, T); D(R, S, T)
1  | z |2
z
zz Hint: = unimodular
⇒ 2  ( z  z ) (1   )  |z|
1 | z |2

9/10
All India Aakash Test Series for JEE (Advanced)-2020 Test - 3A (Paper - 1) (Code-F) (Hints & Solutions)
Solution: Solving (i), (ii) and (iii)
z z we get
(A)  2i   2i
|z| |z| a = ±2, d = ±1
z so points P (±1, ±2, ±3)
 unimodular complex no.
|z| Now  = 1,  = 2,  = 3
and lies on perpendicular bisector of 2i and –2i
59. Answer (05)
z
   1 ⇒ z   | z | ⇒ a real number Hint:
|z|
Im (z) = 0 
z1  C is
(B)  = ei 10

1  2 1  e 2i  ⎛ 3 ⎞
z   2cos  z2  C is ⎜  ⎟
 ei  ⎝ 10 ⎠

(C) 2b = 8 Solution:
2be = 6 a2 = 7

z1  C is
3 10
e=
4
x2 y 2 ⎛ 3 ⎞
z2  C is ⎜  ⎟
Equation of ellipse  1 ⎝ 10 ⎠
7 16
(D) |z – 2 – 3i| = 1
⎛  3 ⎞ ⎛  3 ⎞
( x  2)2  ( y  3)2  1 z1  z2  ⎜ cos  cos ⎟ + i ⎜ sin  sin ⎟
⎝ 10 10 ⎠ ⎝ 10 10 ⎠
x  2  cos , y  3  sin 
⎛ 10  2 5  10  2 5 ⎞ 1
x  [1, 3], y  [2, 4] z1  z2  ⎜ ⎟ i
⎜⎝ 4 ⎟⎠ 2
58. Answer (02)
Hint: 3 5
| z1  z2 | 2 
|a – d|, |a|, |a + d| be three distances 2
Solution: 60. Answer (04)

As perpendicular distances are in A.P. Solution:

Let |a – d|, |a|, |a + d| be these distances sin   sin 2  sin 3  0  sin2 (1 + 2cos) = 0
so the co-ordinates of point P are ..(1)

(±(a – d), ± a, ± (a + d) cos   cos 2  cos 3  0  cos2 (1 + 2cos) = 0


..(2)
According to question
From (1) and (2)
2a2 + d2 – 2ad = 5 ...(i)
1
2a2 + 2d2 = 10 ...(ii) cos   –
2
2a2 + d2 + 2ad = 13 ...(iii)
 Number of values of   [–2, 2] is 4

  

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