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This work was supported by funding from the PA DCED BFTDA. A.R.
Sparacino, G.F. Reed, R.J. Kerestes, B.M. Grainger, and Z.T. Smith are with
the Department of Electrical & Computer Engineering and the Power &
Energy Initiative, in the Swanson School of Engineering at the University of
Pittsburgh, Pittsburgh, PA 15210 USA (e-mails: ars88@pitt.edu,
Fig. 1. Worldwide installed energy storage capacity [1]
reed5@pitt.edu, rjk39@pitt.edu, bmg10@pitt.edu, zts6@pitt.edu).
TABLE I
COMPARISON OF ENERGY STORAGE TECHNOLOGIES [1-4]
Storage Power Capacity % Efficiency Total Cost Self- Response
Maturity
Technology (MW) (MWh) (total cycles) ($/kW) Discharge Time
Lead-Acid Commercial 50 300 85-90 (2200) 3100-3300 Low ms
Valve-Regulated Lead-Acid (VRLA) batteries, which 150A at an average voltage of 96V for 4 hours [20]. The
automatically allows recombination of charge gas [2]. Lead- battery stack design allows for individual stacks to be replaced
acid batteries have a very low energy density when compared instead of the entire module [20]. Zinc-bromine battery life
to other battery technologies. Lead-acid batteries also suffer time is rated at 2500 cycles [20]. The electrochemical reaction
from relatively short calendar/cycle lives of approximately 4-5 used for charging and discharging energy is characterized as
years/750 cycles, meaning that they are replaced frequently, reversible and non-destructive, meaning it is capable of 100%
for heavy usage beyond back up power [9, 10]. depth of discharge. The zinc bromine battery uses less toxic
electrolytes when compared to traditional lead-acid batteries
B. Sodium-Sulfur
making them a more environmentally friendly choice [9].
The Sodium sulfur battery was originally developed by the Zinc-bromine flow batteries lack technological maturity and
Ford Motor Company in the 1960’s. It contains sulfur at the have few examples of real world installations.
positive electrode and sodium at the negative electrode. These
electrodes are separated by a solid beta alumina ceramic [11]. D. Lithium Ion
Through an electrochemical reaction, electrical energy is Lithium-Ion batteries have traditionally been used to
stored and released on demand. This effect is shown below in power consumer electronic devices, and more recently for
Fig. 3 [12]. NaS batteries have an operating temperature plug-in hybrid electric vehicles [1]. The lithium-ion battery
between 300 and 360 °C [11]. The primary manufacturer of operates by allowing the lithium ions to move between the
NaS batteries, NGK Insulators, LTD, builds the batteries in 50 anode and cathode producing a flow of current. Lithium-ion
kW modules which are combined to make MW class battery battery technology is one of the newer technologies examined
systems [13]. in this paper (first commercialized in 1991 by Sony Co.) [21].
There are many chemical configurations that are classified as
a lithium-ion battery. Each of these configurations has its own
power and energy characteristics [21].
Advantages of Lithium-ion batteries include high energy
density, no memory effect, long calendar life and a low self-
discharge. Having no memory effect means that li-ion
batteries do not require scheduled cycling [21, 22]. Due to the
scarcity of lithium, lithium-ion batteries are more expensive
than other battery technologies [2]. Current grid level Li-Ion
storage installations include smaller demonstration systems of
1MW or less [1]. According to the U.S. DOE, Li-Ion batteries
used for frequency regulation are one of the fastest growing
markets for energy storage. The DOE estimates that the
installed capacity of Lithium-Ion batteries in the U.S. for Grid
Fig. 3. NaS battery electrochemical reaction [12] level storage is 54 MW [23].
NaS batteries exhibit high power and high energy density, IV. BATTERY MODELING
high coulombic efficiency, good temperature stability, long
Mathematical battery models aim to predict the operation of
cycle life, and low material costs [14, 15]. Their energy
a battery given a specific set of parameters. There are
density is approximately three times that of traditional lead-
numerous factors that affect a battery’s operation including
acid batteries [16]. They have a high DC conversion
discharge rate, charge rate, battery age, battery type, and
efficiency of approximately 85% [15]. This high DC
temperature. There are many methods of modeling battery
conversion efficiency makes sodium sulfur batteries an ideal
operation; each model has its own benefits and drawbacks.
candidate for implementation into future DC distribution
Due to the highly non-linear operation of batteries, accurate
systems [17]. NaS batteries can be used for a wide variety of
models tend to be overly complex mathematical models. For
applications including peak shaving, renewable integration,
grid level simulations, battery models expressed as equivalent
power quality management, and emergency power. They have
circuit models are necessary. These equivalent circuit models
the ability to discharge above their rated power, which makes
need to be dynamic to accurately represent the operation of a
them ideal to operate in both a peak shaving and power
battery. There are two main methods of creating these
quality management environment [13]. NaS batteries are also
dynamic models. Using experimentally obtained data to create
one of the more commercially mature battery technologies,
lookup tables which are referenced by the simulation, or using
with use by AEP and TEPCO [12, 18, 19].
experimentally obtained data to create non-linear equations
C. Zinc/Bromine which represent how the battery parameters change during
Zinc/Bromine (Zn/Br) batteries are a type of redox flow operation.
battery. Zinc/bromine batteries operate by using a pump A. Electrochemical Models
system which circulates reactants through the battery. One
Electrochemical models of batteries are designed to take
manufacturer, ZBB Energy, builds Zn/Br batteries in 50 kWh
into account the chemical, thermodynamic, and physical
modules made out of three parallel connected 60 cell battery
qualities of the batteries and are typically more precise and
stacks [20]. The battery modules are rated to discharge at
4
I n * Ti = K (1)
SOC = 1 − C Di / Ci
(3) Fig. 5. Linear battery equivalent circuit model [26]
C Di = I i t
3) Thevenin Model
For a non-constant discharge rate, which is the case with a The Thevenin Model, Fig. 6, includes the ideal no load
real world battery energy storage system implementation, the voltage, E, the battery internal resistance, R2, as well as the
SOC equation will change so that the relation is evaluated in addition of capacitance, C, and an overvoltage resistance, R1.
small time intervals, as shown by (4). SOCK (5) is the net state Like the linear model, the Thevenin model’s accuracy can be
of charge at k-th time interval. improved by making the latter parameters correspond with the
values of the battery internal resistance, R, and open circuit
n −1 voltage, E, variable and determined by the battery current
I Δt ⎛ Ii ⎞
ΔSOC K = − i ⎜⎜ ⎟⎟ (4) SOC [27].
3600C n ⎝ In ⎠
SOCK = SOCK −1 + ΔSOCK (5)
The parameters for the short term lead-acid model are during charging and discharging is presented. The curves
calculated in [30]. representing charging have the highest peaks at low depth of
discharge. The increase in resistance at high and low SOC, is
caused by polarization effects, and shows why such areas
should be avoided [27]. The battery nominal operating
temperature is between 300°C and 360°C. When discharging,
the battery temperature increases. During charging, the battery
temperature will decrease since the heat generated by the
resistance is less than that of entropic heat absorption [27].
During the final standby state, the battery temperature will
also decrease. Battery temperature is maintained at 300°C
through the use of heaters [27]. The battery internal resistance
rises over time with respect to the number of charge and
discharge cycles on the battery as, shown in Fig. 10.
Charging
Discharging
Fig. 7. Fourth order equivalent circuit model for short term lead-acid battery
[30]
Fig. 8. Second order equivalent circuit model for long discharge lead-acid
battery [28, 31]
The cells electromotive force, EMF, is based off of the OCV − Vbattery
batteries current depth of discharge as is illustrated in Fig. 11. Rint = (6)
Installations limit the maximum discharge to 100%, and in I disch arg ing
typical usage the maximum discharge is limited to 90% [18].
Using the effect of temperature and state of discharge on
the NaS cells internal resistance and EMF, the equivalent
circuit model shown in Fig. 12 was developed. The values of
Rc and Rd represent the battery internal resistance and vary
with respect to temperature and depth of discharge. The
battery voltage source E is the battery EMF and varies with
respect to the depth of discharge. RLC represents the
deterioration caused by the number of cycles. These values
are determined using a lookup table based on measured values
obtained through experimentation [27]. These individual cells
can then be combined to create 50 kW modules which can be
combined to create full scale 1 MW peak shaving installations
[27].
Fig. 14. Internal resistance as a function of SOC for different discharge levels
[33]
continuous charging and discharging. It should be noted that reference profile at zero SOD. In (10), rk is the kth-order
the model was originally developed and intended for modeling polynomial representing R2_ref [22].
of an energy storage system employed in a hybrid-electric This lithium-ion battery model was designed for smaller
vehicle. size batteries. The model does not operate properly at low
temperatures or high discharge rates. However, for a peak
7) Lithium-Ion Battery Model shaving implementation it would useable.
Lithium-Ion battery output voltage and current are
determined primarily by the battery temperature, discharge V. CONCLUSIONS
current and lifecycle. Fig. 17 shows an equivalent circuit This paper presents information on the operating
model that was developed for use in power system simulation. characteristics and modeling techniques of four of the more
This model consists of a voltage source E which varies as the commercially mature battery technologies (lead-acid, sodium-
battery discharges, and an internal resistance made up of two sulfur, zinc-bromine, and lithium-ion). General information on
series resistors R1 and R2 [22]. This model is based off of the battery modeling was presented with the conclusion that for
model developed in [34]. The model shown in Fig. 17 was power system simulation, accurate equivalent circuit battery
used because it was originally validated for use in higher models are required. For accuracy, these models need to take
power system applications. The values for the equivalent into account the electrochemical properties of the batteries.
circuit model are based off of a manufacturer’s data.
VI. ACKNOWLEDGMENT
The electric power and energy research group for grid
infrastructure (EPERGI) would like to extend a special thanks
to the Commonwealth of PA Ben Franklin Development
Authority (BFTDA) for their support of this work.
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VIII. BIOGRAPHIES