Nama : Ridho Hermawan

Nim : 16036086

Prodi : Kimia NK

Tugas Elektroanalisis 8

1. In experiment 1, a cyclic voltammogram was obtained from a 0.167 mM solution

of Pb2+ at a scan rate of 2.5 V/s. In experiment 2, a second cyclic voltammogram
is to be obtained from a 4.38 mM solution of Cd2+. What must the scan rate be in
experiment 2 to record the same peak current in both experiments if the diffusion
coefficients of Cd2+ and Pb2+ are 0.72x10-5 cm2s-1 and 0.98x10-5 cm2s-1,
respectively.

2. The concentration of copper in a sample of sea water is determined by anodic

stripping voltammetry using the method of standard additions. When a 50.0-mL
sample is analyzed, the peak current is 0.886 mA. A 5.00-mL spike of 10.0-ppm
Cu2+ is added, giving a peak current of 2.52 mA. Calculate the parts per million of
copper in the sample of sea water.

3. Tulis tentag prinsip dasar analisis kimia dengan metode consuctometry!

Answer:

1. Diket : Eksperimen 1
n Pb2+ = 2
C = 0.167 mM = 1,67x10-4 M
V = 2.5 V/s
D1/2 = 0.72x10-5 cm2s-1 = 7.2x10-6 cm2s-1
Ekseperimen 2
n Cd2+ = 2
C = 4.38 mM = 4.38 M
D1/2 = 0.98x10-5 cm2s-1 = 9.8x10-6 cm2s-1
Dit : V Eksperimen 2
Jawab:
 ip Pb 2 ipCd 2

2,69.10 n 5
3
2
1
. A.C.D 2 .V
1
2
2,69.10 n
5
3
2
1
A.C.D 2 .V
1
2

ipPb 2 269000.2,83. A.1,67.10  4.7,2.10 6.2,5 2

1


ipCd 2 269000.2,83. A.4,38.10 3.9,8.10 6.V 2
1

1 1,45.103
V 2
 2
 4,43.102
3,27.10

2. Diket : Volume sampel yang dianlisis = 50 mL, I = 0.886 mA = 886 μA

Volume dan konsentrasi penambahan = 5 mL 10 ppm, I = 2.52 mA
=2520 μA
Dit : C (konsentrasi) dalam ppm

886 c50  5 44300

 c  0.47
k 50c  5.10 94300

886 c50  5

2520 50c  5.10

88(50c+50)=55c(2520)

44300c+44300=138600c

3. prinsip- prinsip yang mendasari titrasi-titrasi konduktometri yaitu substitusi ion-ion

dengan suatu konduktivitas oleh ion-ion dengan konduktivitas lain.