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Article history: A number of MCM-41 samples were produced with different ageing times and zinc dopant
Received 22 May 2007 levels. Hydrogen adsorption experiments performed at 77 K on pure MCM-41 samples
Received in revised form showed a maximum excess wt% uptake of 2.01%. Samples were doped with Zn in the Si:Zn
10 December 2007 ratio of 50:1, 25:1 and 10:1. These samples showed an increase in d-spacing in their XRD
Accepted 10 December 2007 patterns, suggestive of Zn incorporation into the structure but resulting in a decrease in
Available online 5 March 2008 long range pore ordering and surface area with increasing Zn content. Two of the three
doped samples showed an increase in H2 adsorbed per unit surface area suggestive of
Keywords:
increased interaction strength. However, definitive confirmation is difficult due to
Hydrogen storage material
degradation of the pore structure and surface area. Adsorption at room temperature was
Porous material
minimal, being 0.1 wt% or below.
Silica
& 2008 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights
MCM-41
reserved.
Hydrogen
Zinc
Doping
Corresponding author. Tel.: +61 8 9266 3532; fax: +61 8 9266 2377.
E-mail address: c.buckley@curtin.edu.au (C.E. Buckley).
0360-3199/$ - see front matter & 2008 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
doi:10.1016/j.ijhydene.2007.12.021
ARTICLE IN PRESS
I N T E R N AT I O N A L J O U R N A L O F H Y D R O G E N E N E R G Y 33 (2008) 1688 – 1692 1689
Method Ageing (1 0 0) peak Repeat Surface area ðm2 =gÞ BJH pore Wall
time (h) position (Å) distance (Å) ðp=po ¼ 0:0120:1Þ size (Å) thickness
(Å)
while the Si: Zn ¼ 50 : 1 and Si: Zn ¼ 10 : 1 showed hydrogen and Engineering for the granting of an Australian Post
uptake of 2.09 and 2.07 wt% per 1000 m2 =g, respectively. The Graduate Research Award (PGRA).
relatively poor hydrogen adsorption of the sample doped at
Si: Zn ¼ 25 : 1 cannot be readily explained. At pressures below R E F E R E N C E S
15 bar, this sample behaves as may be expected for a surface
area that is between the other two doping levels but plateaus
sooner. Biz and White [28] have indicated that Al-doped [1] Zuttel A. Materials for hydrogen storage. Mater Today
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