Methane 1

tR (min) FID (area) tR (min) TCD tR (min) FID (height)
H2 1.99 0 4.4 1169.95

O2 0 0 2.5 98.18
CO 5.79 1684.13 5.72 98.79
CH4 3.39 1640.49 3.36 248.79 232.25
CO2 16.23 1732.13 16.15 94.18
C2H2 8.66 3056.34 8.63 192.9 161.3
C2H4 9 3253.34 8.97 185.84 146.98
C2H6 29.4 3279.95 29.36 384.73 306.61
C3H6 42.13 4454.86 42.08 402.9 351.59
C3H8 28.19 4232.11 28.17 308.94 329.66
C3H4 43.77 4433.96 43.72 339.57
iC4H10 32.9 5654.26 32.87 324.09 340.22
nC4H10 33.87 5165.35 33.84 281.9 363.87
calibration data (area method)

H2 729.54 727.39 728.47
150.17 149.68 149.93
O2 843.81
86.76 101.73 102.09 102.15 98.18
CO
CH4 1640.98 1640.69 1640.61 1639.77 1640.38 1640.49

248.54 249.26 248.73 248.53 248.92 248.79
CO2
C2H2 3006.26 3075.96 3086.79 3056.34

192.71 193.81 192.17 192.9
C2H4 3257.34 3257.44 3245.25 3253.34
187.15 186.11 184.27 185.84
C2H6
C3H6
C3H8 4193.32 4327.03 4327.72 4080.38 4232.11

316.98 314.8 299.64 304.34 308.94
C3H4
iC4H10 5660.91 5647.6 5654.26

323.17 325.01 324.09
nC4H10 5486.82 4843.88 5165.35
296.72 267.08 281.9
calibration data (height method)

CH4 232.28 232.21 232.24 232.25 232.23 232.25
C2H2
C2H4 146.88 146.94 147.12 146.98
C3H8 206.69 206.69 197.87 203.75
iC4H10 259.9 258.22 259.06
nC4H10 256.69 235.01 245.85
tR (min) FID (area) tR (min) TCD tR (min) FID (height)
H2 0 0 1.99 728.47 1.99 149.93
O2 0 0 2.46 85.78 2.46 17.22
CO 2.57 64.09 0 2.57 12.8
CH4 3.63 3535.88 0 3.63 467.46
CO2 6.62 3400.25 0 6.62 225.92
C2H2 10.69 6531.64 0 10.69 344.71
C2H4 10.91 6490.51 0 10.91 258.45
C2H6 13.42 6901.19 0 13.42 306.61
C3H6 24.06 9706.08 0 24.06 351.59
C3H8 25.07 9799.68 0 25.07 329.66
C3H4
iC4H10 33.37 12117.36 0 33.37 340.22
nC4H10 35.23 12060.91 0 35.23 363.87
calibration data (area method)

H2 729.54 727.39 728.47
150.17 149.68 149.93
O2 84.81 86.76 85.78
16.81 17.63 17.22
CO 63.99 64.19 64.09
12.75 12.84 12.8
CH4 3535.88 3535.88 3535.88
467.46 467.46 467.46
CO2 3165.35 3635.15 3400.25
212.53 239.31 225.92
C2H2 6520.06 6543.23 6531.64
344.13 345.28 344.71
C2H4 6490.51 6490.51 6490.51
258.45 258.45 258.45
C2H6 6865.79 6936.58 6901.19
305.72 307.5 306.61
C3H6 9706.08 9706.08 9706.08
351.59 351.59 351.59
C3H8 9731.27 9868.09 9799.68
327.93 331.4 329.66
C3H4
iC4H10 12070.94 12163.77 12117.36

339.5 340.93 340.22
nC4H10 12060.74 12061.08 12060.91
363.73 364.02 363.87
column 10ft Hayesep D + 10ft 10%Carbowax
Inject 180 oC
Detector 1 250 oC
Detector 2 250 oC
Aux 1 140 oC
Aux 2 350 oC
Temperature program
50oC 5 mins
5oC/min
220oC 3 mins
Analysis conditions
FID TCD
Threshold 0.01 0.01
Peak width 5 5
Peak area 0.75 0.5
Peak Height 0 0
Range 8 0
Sense 1 4
Attn 0 0
Experiment of Methane Kinetic Conversion
power @ 60 and 80W and flowrate @ 30 mL/min
frequency 20 kHz sample volume 500 uL
flow rate 30 mL/min mole sample 0 mol
power 60 W (Metex)
reactant CH4 Al2O3 ZSM5

before after before after before after
FID (flow rate) 29.19 29.88
8.42 1744.71 1583.17
25.53 18.81
25.66
29.40 71.79
42.13
42.98 29.21
43.77
51.25
53.31
TCD
4.40 72.57
8.39 312.87 281.47
power
V (kV) 2.77
I (mA) 24.82
total mol
FID 0 0 0 0 0 0
TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
calculation 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
FID FID TCD FID TCD FID TCD
8.42 7.12 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
43.77 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
TCD
power (Watt) 50.00

RMS 68.85 0.00 0.00
integration
C total #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
H total #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
2n
FID 20 19 70.88 70.18 62.95 62.63
8.42 1767.31 1530.75 1566.43 1368.43 1583.33 1384.03
25.53 22.84 19.56 18.78
25.66
29.40 105.31 81.12 81.58
42.13 17.75
42.98 50.60 30.62 32.21
43.77
51.25 14.60
53.31 12.33
TCD
4.40 106.56 81.43 86.89
8.39 307.64 264.30 276.56 237.60 278.62 242.06
power (RMS)
V (kV) 2.85 2.79 2.79
I (mA) 23.74 23.67 23.90
total mol
FID 0 0 0 0 0 0
calculation 0 #DIV/0! 0 #DIV/0! 0 #DIV/0!
8.42 17.72 #DIV/0! 13.51 #DIV/0! 13.03 #DIV/0!
25.53 7.50 #DIV/0! 9.91 #DIV/0! 9.81 #DIV/0!
25.66 0.00 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0!
29.40 32.74 #DIV/0! 38.89 #DIV/0! 40.33 #DIV/0!
42.13 5.88 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0!
42.98 16.62 #DIV/0! 15.51 #DIV/0! 16.82 #DIV/0!
51.25 5.20 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0!
53.31 4.37 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0!
TCD
4.40 78.47 #DIV/0! 92.46 #DIV/0! 101.74 #DIV/0!
power 48.00 49.00 50.00

RMS 67.56 66.06 66.59
integration
3rd
FID 105.47 106.11 104.67 105.16 117.05 120.52
8.42 1362.24 1070.21 1329.94 1062.81 1358.6 1079.62
25.53 17.78 16.29 23.45
25.66
29.40 95.57 101.06 102.63
42.13
42.98 48.91 42.08 42.20
43.77
51.25
53.31 11.69
TCD
4.40 133.49 149.43 140.95
8.39 246.40 192.88 240.66 190.17 243.69 191.94
power (RMS)
V (kV) 2.60 2.86 2.62
I (mA) 21.50 15.18 23.93
total mol
FID 0 0 0 0 0 0
calculation 0 #DIV/0! 0 #DIV/0! 0 #DIV/0!
8.42 20.96 #DIV/0! 19.71 #DIV/0! 18.18 #DIV/0!
25.53 6.78 #DIV/0! 6.76 #DIV/0! 10.58 #DIV/0!
25.66 0.00 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0!
29.40 34.50 #DIV/0! 39.69 #DIV/0! 43.84 #DIV/0!
42.13 0.00 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0!
42.98 18.65 #DIV/0! 17.45 #DIV/0! 19.04 #DIV/0!
51.25 0.00 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0!
53.31 0.00 #DIV/0! 0.00 #DIV/0! 5.69 #DIV/0!
TCD
4.40 114.13 #DIV/0! 138.97 #DIV/0! 142.61 #DIV/0!
power 50.00 50.00 50.00

RMS 55.92 43.46 62.72
integration
report
< 10% empty Al2O3 ZSM5
CH4 conv. #DIV/0! #DIV/0! #DIV/0!
H2 #DIV/0! #DIV/0! #DIV/0!
C2H2 #DIV/0! #DIV/0! #DIV/0!
C2H6 #DIV/0! #DIV/0! #DIV/0!
C3H8 #DIV/0! #DIV/0! #DIV/0!
C4 #DIV/0! #DIV/0! #DIV/0!
10-20%
H2 #DIV/0! #DIV/0! #DIV/0!
C2H2 #DIV/0! #DIV/0! #DIV/0!
C2H6 #DIV/0! #DIV/0! #DIV/0!
C3H8 #DIV/0! #DIV/0! #DIV/0!
C4 #DIV/0! #DIV/0! #DIV/0!
> 20% 0.4 #DIV/0! 0.33

H2 #DIV/0! #DIV/0! #DIV/0!
C2H2 #DIV/0! #DIV/0! #DIV/0!
C2H6 #DIV/0! #DIV/0! #DIV/0!
C3H8 #DIV/0! #DIV/0! #DIV/0!
C4 #DIV/0! #DIV/0! #DIV/0!
e Kinetic Conversion
flowrate @ 30 mL/min
1st trial
3% Fe/Al2O3 3% Fe/ZSM5 3% Cu/Al2O3 3% Cu/ZSM5
before after before after before after before
59.94 59.48 29.14
1539.94 1462.41 1654.38
51.25
30.82
280.81 265.69 314.29
2.61
24.02
0 0 0 0 0 0 0
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0
FID TCD FID TCD FID TCD FID
5.76 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 8.42
35.00 51.00
62.60 0.00 0.00

2nd trial
55.49 55.79 383.61 386.32 62.14 58.16
1525.45 1337.47 772.02 648.66 1596.97 1384.14
18.89 16.31 17.97
78.17 45.70 88.63
5.63
26.66 19.07 32.35
4.88
5.55
85.64 58.61 92.82

278.71 242.95 128.98 108.83 278.40 240.07
2.77 2.89 2.75

24.14 24.21 23.45
0 0 0 0 0 0 0
0 #DIV/0! 0 #DIV/0! 0 #DIV/0! #DIV/0!
11.85 #DIV/0! 15.39 #DIV/0! 18.89 #DIV/0! #DIV/0!
11.37 #DIV/0! 14.97 #DIV/0! 6.04 #DIV/0! #DIV/0!
0.00 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0! #DIV/0!
44.54 #DIV/0! 39.70 #DIV/0! 28.18 #DIV/0! #DIV/0!
0.00 #DIV/0! 5.22 #DIV/0! 0.00 #DIV/0! #DIV/0!
16.04 #DIV/0! 17.50 #DIV/0! 10.87 #DIV/0! #DIV/0!
0.00 #DIV/0! 4.85 #DIV/0! 0.00 #DIV/0! #DIV/0!
0.00 #DIV/0! 5.49 #DIV/0! 0.00 #DIV/0! #DIV/0!
115.56 #DIV/0! 120.60 #DIV/0! 69.90 #DIV/0! #DIV/0!
49.00 48.00 51.00

66.87 69.85 64.51

3rd trial
20.04 20.1 28.2 24.61 118.43 115.26
1714.32 1289.47 1683.23 1485.66 1390.88 1077.8
36.67 20.88
163.43 74.57 94.80
72.16 28.78 37.85
23.48
18.19
192.57 82.68 139.72

294.93 218.64 310.54 280.90 254.30 195.28
2.80 2.85 2.52

24.37 25.42 24.14
0 0 0 0 0 0 0
0 #DIV/0! 0 #DIV/0! 0 #DIV/0! #DIV/0!
24.56 #DIV/0! 22.97 #DIV/0! 24.58 #DIV/0! #DIV/0!
9.46 #DIV/0! 0.00 #DIV/0! 6.43 #DIV/0! #DIV/0!
0.00 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0! #DIV/0!
39.90 #DIV/0! 17.25 #DIV/0! 27.65 #DIV/0! #DIV/0!
0.00 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0! #DIV/0!
18.61 #DIV/0! 7.03 #DIV/0! 11.66 #DIV/0! #DIV/0!
6.56 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0! #DIV/0!
5.06 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0! #DIV/0!
111.34 #DIV/0! 45.29 #DIV/0! 96.52 #DIV/0! #DIV/0!
50.00 50.00 49.00

68.33 72.50 60.88


#DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0!

#DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0!
3% Cu/ZSM5 1% Pt/Al2O3 5% Mn/Al2O3 3% Ru/Al2O3
after before after before after before after
29.89 60.65 60.65 29.55 29.72 65.02 65.11
1477.27 1520.66 1368.15 1668.01 1491.99 1709.93 1545.33
20.17 19.45 21.46
80.16 68.45 65.21 91.60
31.96 26.93 27.49 39.66
93.07 73.14 70.44 96.01

277.73 278.04 250.81 311.80 276.97 300.80 271.58
2.77 2.38 2.77 2.79

24.88 24.64 24.27 23.38
0 0 0 0 0 0 0
#DIV/0! 0 #DIV/0! 0 #DIV/0! 0 #DIV/0!
TCD FID TCD FID TCD FID TCD
#DIV/0! 10.03 #DIV/0! 10.04 #DIV/0! 9.49 #DIV/0!
#DIV/0! 14.32 #DIV/0! 12.64 #DIV/0! 14.33 #DIV/0!
#DIV/0! 0.00 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0!
#DIV/0! 45.99 #DIV/0! 40.11 #DIV/0! 57.91 #DIV/0!
#DIV/0! 0.00 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0!
#DIV/0! 19.11 #DIV/0! 17.86 #DIV/0! 26.49 #DIV/0!
#DIV/0! 0.00 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0!
#DIV/0! 0.00 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0!
#DIV/0! 116.40 #DIV/0! 102.62 #DIV/0! 143.77 #DIV/0!
50.00 36.00 50.00 50.00

68.79 58.64 67.11 65.16


59.12 61.34
1506.64 1262.63
23.31
94.62
35.16
109.34
274.31 227.18
2.47
24.31
0 0 0 0 0 0 0
#DIV/0! 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! 13.06 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
48.00 52.00
0.00 60.12 0.00 0.00


67.1 66.98 118.56 119.22 117.19 118.21
1427.66 1125.36 1357.72 871.94 1357.71 843.19
13.01 31.77 28.02
118.99 146.47 152.37
44.78 57.06 63.38
19.09 19.61
11.09 16.03 15.91
152.81 253.82 282.6

245.04 194.45 245.09 156.39 246.22 148.79
2.72 2.29 2.38

21.88 23.59 24.50
0 0 0 0 0 0 0
#DIV/0! 0 #DIV/0! 0 #DIV/0! 0 #DIV/0!
#DIV/0! 21.32 #DIV/0! 35.42 #DIV/0! 37.36 #DIV/0!
#DIV/0! 4.62 #DIV/0! 7.19 #DIV/0! 6.03 #DIV/0!
#DIV/0! 0.00 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0!
#DIV/0! 39.99 #DIV/0! 31.38 #DIV/0! 31.05 #DIV/0!
#DIV/0! 0.00 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0!
#DIV/0! 15.90 #DIV/0! 12.91 #DIV/0! 13.64 #DIV/0!
#DIV/0! 0.00 #DIV/0! 4.68 #DIV/0! 4.57 #DIV/0!
#DIV/0! 4.25 #DIV/0! 3.91 #DIV/0! 3.69 #DIV/0!
#DIV/0! 121.63 #DIV/0! 128.80 #DIV/0! 136.39 #DIV/0!
50.00 50.00 51.00

0.00 59.51 54.07 58.26


#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0!

#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0!

#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0!
ZnCr2O4
before after
0 0
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
FID TCD
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
0.00
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
ZnCr2O4
before after
0 0
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
FID TCD
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
0.00
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
ZnCr2O4
before after
18.9 18.03
1645.59 1219.48
30.69
164.47
68.42
22.72
20.04
211.27
309.46 226.62
2.66
23.93
0 0
#DIV/0! #DIV/0!
0 #DIV/0!
FID TCD
29.29 #DIV/0!
6.58 #DIV/0!
0.00 #DIV/0!
33.37 #DIV/0!
0.00 #DIV/0!
14.66 #DIV/0!
#DIV/0! #DIV/0!
5.27 #DIV/0!
4.63 #DIV/0!
101.51 #DIV/0!
50.00
63.65
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
ZnCr2O4
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
Experiment of Meth
power @ 60 and 80W a

6
reactan CH4 C2H2 C2H4
FID (flow rate) 27.61 28.3 27.83 26.13
CH4 232.25 195.31 13.28
C2H2 0.58 230
C2H4 0.37 6490.51 5828.42
C2H6 4.00 50.18
C3H6 39.66
C3H8 4.93 69.69
iC4H10 2.18 86.85
nC4H10 1.53 236.21
TCD
H2 98.08
conv. 13.80 15.70
power
V (kV) 2.83 3.54
I (mA) 40.23 28.55
total mol
FID 0 0 0 0 0 0
TCD
calculation 0 #DIV/0! 0
CH4 13.80 #DIV/0! 1.12
C2H2 2.51 #DIV/0! 21.06
C2H4 2.14 #DIV/0! 15.70
C2H6 19.37 #DIV/0! 4.35
C3H6 0.00 #DIV/0! 3.67
C3H8 33.32 #DIV/0! 6.38
iC4H10 19.03 #DIV/0! 8.57
nC4H10 12.50 #DIV/0! 23.43
TCD
4.40 50.00 #DIV/0! 0.00
power (Watt) 60.00 60.00 60.00

RMS 113.77 0.00 100.95
integration
C total 88.87 #DIV/0! 68.58
H total 102.59 #DIV/0! 39.96
8
FID 27.61 28.4 30.54 30.07 23.49 21.36
CH4 232.25 178.6 216.17 5.21
C2H2 0.63 6531.64 5834.66 20.75
C2H4 0.71 3.80 146.98 90.34
C2H6 5.10 3.09
C3H6 0.45 13.48 3.25
C3H8 3.76 5.50
iC4H10 1.41 61.68 3.39
nC4H10 1.28 95.58 12.65
TCD
4.40 106.56 22.79 86.89
conv. 20.90 12.05 44.11
power (RMS)
V (kV) 2.85 3.74 2.79
I (mA) 23.74 35.40 23.90
total mol
FID 0 0 0 0 0 0
TCD
calculation 0 0 0 0
8.42 2.09 24.99 2.02
25.53 1.80 12.05 21.82
25.66 2.70 12.02 44.11
29.40 16.38 0.00 3.65
42.13 1.89 1.70 5.03
42.98 16.86 0.00 9.08
43.77 8.16 8.32 7.22
51.25 6.92 12.95 25.21
TCD
4.40 36.01 12.79 21.62
power 80.00 80.00 80.00

RMS 67.56 132.43 66.59
integration
C total 54.71 59.99 74.03
H total 69.32 33.53 78.60
report
60 W CH4 C2H2 C2H4
Conversion 13.80 15.70
H2 50.00 0.00
C2H2 2.51 21.06
C2H4 2.14 15.70
C2H6 19.37 4.35
C3H6 0.00 3.67
C3H8 33.32 6.38
iC4H10 19.03 8.57
nC4H10 12.50 23.43
80 W
Conversion 20.90 12.05 44.11
H2 36.01 12.79 21.62
C2H2 1.80 12.05 21.82
C2H4 2.70 12.02 44.11
C2H6 16.38 0.00 3.65
C3H6 1.89 1.70 5.03
C3H8 16.86 0.00 9.08
iC4H10 8.16 8.32 7.22
nC4H10 6.92 12.95 25.21
13.85 50
C2H4 14.72 2.70 12.02
C2H6 16.38 3.38 19.76
40
C3H6 3.60 1.89 1.70
Selectivity (%)
C3H8 16.86 1.86 18.72
i-C4H10 16.48 4.16 20.64 30
n-C4H10 19.87 3.92 15.95
87.91 88.80 20
10
0
H4 H6 H6 H8
C2 C2 C3 C3
Compounds
60 Watt
C2H6 C3H6 C3H8 iC4H10
27.68 28.39 29.49 29.29 28.98 32.5 28.21
33.16 24.89 9.62
4.28 5.56 1.45
5.30 6.46 4.69
6901.19 6094.11 32.30 2.61
15.46 9706.08 8810.13 7.97
84.93 220.01 215.22 169.36
6.25 120.77 0.26 259.06
99.47 69.81 0.00
42.34 44 70
9.43 9.84 11.73 16.67
3.08 3.28 3.39

31.28 33.84 49.55
0 0 0 0 0 0 0
0 0 0 0
FID FID TCD FID TCD FID
5.10 2.37 10.04 4.64
13.51 10.85 4.11 9.26
22.31 16.81 17.70 15.83
9.43 3.15 8.30 6.50
2.60 9.84 33.19 18.83
14.14 22.65 11.73 8.20
1.12 13.41 1.52 16.67
17.94 7.79 0.00 46.82
31.61 30.47 70.35 81.99
60.00 60.00 51.00

96.31 111.03 167.97
76.71 77.03 74.85 110.08

75.53 73.32 111.37 146.79
80 Watt
C2H6 C3H6 C3H8 iC4
27.33 28.58 30.04 29.46 30.6 34.68 29.68
112.22 52.38 13.15
5.81 9.73 2.66
9.76 11.12 9.58
6901.19 5448.36 56.52 3.74
32.64 9706.08 8041.06 10.24
172.20 258.56 215.00 165.22
26.81 171.47 0.45 259.06
199.70 106.11 0.27
78.36 44 92.82
17.45 18.75 12.90 15.23
3.26 3.61 2.75

32.36 34.60 23.45
0 0 0 0 0 0 0
0 0 0 0
FID FID TCD FID TCD FID
9.51 2.58 12.63 4.77
10.10 9.84 6.93 2.36
22.63 15.00 33.27 4.67
17.45 2.86 10.96 4.04
3.02 18.75 39.23 18.42
15.80 13.80 12.90 7.00
2.65 9.87 2.36 15.23
19.85 6.13 1.34 34.47
32.23 15.79 85.81 0.00
80.00 80.00 80.00

105.33 124.84 64.51
91.50 76.25 106.71 75.73

84.49 53.59 142.23 46.45

9.43 9.84 11.73 16.67
31.61 30.47 70.35 81.99
13.51 10.85 4.11 9.26
22.31 16.81 17.70 15.83
9.43 3.15 8.30 6.50
2.60 9.84 33.19 18.83
14.14 22.65 11.73 8.20
1.12 13.41 1.52 16.67
17.94 7.79 0.00 46.82
17.45 18.75 12.90 15.23
32.23 15.79 85.81 0.00
10.10 9.84 6.93 2.36
22.63 15.00 33.27 4.67
17.45 2.86 10.96 4.04
3.02 18.75 39.23 18.42
15.80 13.80 12.90 7.00
2.65 9.87 2.36 15.23
19.85 6.13 1.34 34.47
Column B
Column D
H6 H6 H8 10 10
C2 C3 C3 4H 4H
i-C n-C
Compounds
iC4H10 nC4H10
after before after
37.48 27.35 29.17
8.3 5.56
6.10 3.50
7.82 5.56
3.81 3.67
8.44 4.48
3.45 4.50
162.49 7.42
16.28 245.85 211.26
114.15
190.58 8.37
2.77
24.88
0 0 0
0 0
TCD FID TCD
5.61
9.57
20.27
11.29
18.01
19.31
41.13
8.37
0.00
60.00 60.00
68.79 0.00
125.19
61.82
iC4H10 nC4H10
after before after
31.83 27.35 29.17
9.64 5.56
1.76 3.50
2.61 5.56
2.68 3.67
9.33 4.48
3.33 4.50
204.79 7.42
13.56 245.85 211.21
8.39
2.47
24.31
0 0 0
0
TCD FID TCD
5.59
9.55
20.22
11.26
17.96
19.26
41.01
8.39
0.00
80.00 80.00
0.00 60.12
124.84
61.67
iC4H10 nC4H10
8.37
0.00
9.57
20.27
11.29
18.01
19.31
41.13
8.37
8.39
0.00
9.55
20.22
11.26
17.96
19.26
41.01
8.39
Experiment of Meth
power @ 60 and 80W a

6
FID (flow rate) 27.61 28.3 27.83 26.13
CH4 232.25 195.31 13.28
C2H2 0.58 230
C2H4 0.37 6490.51 5828.42
C2H6 4.00 50.18
C3H6 39.66
C3H8 4.93 69.69
iC4H10 2.18 86.85
nC4H10 1.53 236.21
TCD
H2 98.08
conv. 13.80 15.70
power
V (kV) 2.83 3.54
I (mA) 40.23 28.55
total mol
FID 0 0 0 0 0 0
TCD
calculation 0 #DIV/0! 0
FID FID concentration FID concentration FID concentration
CH4 13.80 86.20 #DIV/0! 1.12 2.67
C2H2 2.51 0.17 #DIV/0! 21.06 3.31
C2H4 2.14 0.15 #DIV/0! 15.70 84.30
C2H6 19.37 1.34 #DIV/0! 4.35 0.68
C3H6 0.00 0.00 #DIV/0! 3.67 0.38
C3H8 33.32 1.53 #DIV/0! 6.38 0.67
iC4H10 19.03 0.66 #DIV/0! 8.57 0.67
nC4H10 12.50 0.43 #DIV/0! 23.43 1.84
TCD
4.40 50.00 13.80 #DIV/0! 0.00 0.00
power (Watt) 60.00 60.00 60.00

RMS 113.77 0.00 100.95
integration
C total 88.87 90.48 #DIV/0! 0.00 68.58 94.52
H total 102.59 101.12 #DIV/0! 0.00 39.96 97.84
8
FID 27.61 28.4 30.54 30.07 23.49 24.36
CH4 232.25 178.6 216.17 5.21
C2H2 0.63 6531.64 5834.66 20.75
C2H4 0.71 3.80 146.98 90.34
C2H6 5.10 3.09
C3H6 0.45 13.48 3.25
C3H8 3.76 5.50
iC4H10 1.41 61.68 3.39
nC4H10 1.28 95.58 12.65
TCD
4.40 106.56 22.79 86.89
conv. 20.90 12.05 36.26
power (RMS)
V (kV) 2.85 3.74 2.79
I (mA) 23.74 35.40 23.90
total mol
FID 0 0 0 0 0 0
TCD
calculation 0 0 0 0
FID FID concentration FID concentration FID concentration
8.42 2.09 79.10 24.99 6.02 2.80 1.16
25.53 1.80 0.19 12.05 87.95 30.27 6.24
25.66 2.70 0.28 12.02 1.45 36.26 63.74
29.40 16.38 1.71 0.00 0.00 5.07 1.05
42.13 1.89 0.13 1.70 0.14 6.98 0.96
42.98 16.86 1.17 0.00 0.00 12.60 1.73
43.77 8.16 0.43 8.32 0.50 10.02 1.03
51.25 6.92 0.36 12.95 0.78 34.97 3.61
TCD
4.40 36.01 15.05 12.79 3.08 29.99 12.37
power 80.00 80.00 80.00

RMS 67.56 132.43 66.59
integration
C total 54.71 83.38 59.99 96.84 102.71 79.51
H total 69.32 94.09 33.53 112.79 96.58 92.27
report
60 W CH4 C2H2 C2H4
Conversion 13.80 86.20 0.00 15.70 2.67
H2 50.00 13.80 0.00 0.00 0.00
C2H2 2.51 0.17 0.00 21.06 3.31
C2H4 2.14 0.15 0.00 15.70 84.30
C2H6 19.37 1.34 0.00 4.35 0.68
C3H6 0.00 0.00 0.00 3.67 0.38
C3H8 33.32 1.53 0.00 6.38 0.67
iC4H10 19.03 0.66 0.00 8.57 0.67
nC4H10 12.50 0.43 0.00 23.43 1.84
80 W
Conversion 20.90 79.10 12.05 6.02 36.26 1.16
H2 36.01 15.05 12.79 3.08 29.99 12.37
C2H2 1.80 0.19 12.05 87.95 30.27 6.24
C2H4 2.70 0.28 12.02 1.45 36.26 63.74
C2H6 16.38 1.71 0.00 0.00 5.07 1.05
C3H6 1.89 0.13 1.70 0.14 6.98 0.96
C3H8 16.86 1.17 0.00 0.00 12.60 1.73
iC4H10 8.16 0.43 8.32 0.50 10.02 1.03
nC4H10 6.92 0.36 12.95 0.78 34.97 3.61
Products concentration [%]

Reactan
CH4 C2H2 C2H4 C2H6 C3H6 C3H8
CH4 86.20 0.17 0.45 2.04 0.00 0.93
C2H2 3.03 81.95 1.45 0.00 0.14 0.00
C2H4 2.67 3.31 84.30 0.68 0.38 0.67
C2H6 0.96 1.27 2.10 90.57 0.16 0.89
C3H6 0.70 1.60 2.48 0.46 80.16 2.23
C3H8 2.31 0.47 2.03 0.95 2.54 88.27
iC4H10 2.36 2.35 4.02 1.65 3.19 1.39
nC4H10 1.27 1.08 2.29 1.28 1.36 1.46
4.0 10.5 47.6 0.0 21.7

61.9 29.6 0.0 2.8 0.0
26.1 32.4 6.7 3.8 6.5
15.3 20.2 33.4 2.6 14.1
7.7 17.7 27.5 5.1 24.7
27.5 5.6 24.2 11.4 30.3
11.3 11.2 19.2 7.9 15.3 6.6
11.5 9.8 20.7 11.5 12.3 13.2
0.35 0.9 4.08 0 2.79

3.03 2.9 0 0.41 0
2.67 6.61 1.37 1.15 2
0.96 2.55 4.21 0.49 2.67
0.70 3.2 4.97 0.93 6.69
2.31 0.94 4.07 1.91 7.63
2.36 4.7 8.04 3.3 9.56 4.17
1.27 2.17 4.59 2.55 4.07 4.37
3.2 8.3 37.5 0.0 25.6

40.6 38.8 0.0 5.5 0.0
11.2 27.7 5.7 4.8 8.4
6.6 17.6 29.1 3.4 18.4
3.1 14.1 21.8 4.1 29.4
13.4 5.5 23.6 11.1 44.3
4.2 8.4 14.4 5.9 17.1 7.5
4.5 7.6 16.2 9.0 14.4 15.4
Conversion Products concentration [%]
Reactan
[%] CH4 C2H2 C2H4 C2H6 C3H6
CH4 13.8 86.20 0.17 0.45 2.04 0.00
C2H2 12.0 3.03 81.95 1.45 0.00 0.14
C2H4 15.7 2.67 3.31 84.30 0.68 0.38
C2H6 9.4 0.96 1.27 2.10 90.57 0.16
C3H6 9.8 0.70 1.60 2.48 0.46 80.16
C3H8 11.7 2.31 0.47 2.03 0.95 2.54
iC4H10 16.7 2.36 2.35 4.02 1.65 3.19
nC4H10 8.4 1.27 1.08 2.29 1.28 1.36
60 Watt
27.68 28.39 29.49 29.29 28.98 32.5 28.21
33.16 24.89 9.62
4.28 5.56 1.45
5.30 6.46 4.69
6901.19 6094.11 32.30 2.61
15.46 9706.08 8810.13 7.97
84.93 220.01 215.22 169.36
6.25 120.77 0.26 259.06
99.47 69.81 0.00
42.34 44 70
9.43 9.84 11.73 16.67
3.08 3.28 3.39

31.28 33.84 49.55
0 0 0 0 0 0 0
0 0 0 0
FID concentration FID concentration FID concentration FID
5.10 0.96 2.37 0.70 10.04 2.31 4.64
13.51 1.27 10.85 1.60 4.11 0.47 9.26
22.31 2.10 16.81 2.48 17.70 2.03 15.83
9.43 90.57 3.15 0.46 8.30 0.95 6.50
2.60 0.16 9.84 90.16 33.19 2.54 18.83
14.14 0.89 22.65 2.23 11.73 88.27 8.20
1.12 0.05 13.41 0.99 1.52 0.09 16.67
17.94 0.85 7.79 0.57 0.00 0.00 46.82
31.61 5.96 30.47 6.00 70.35 10.78 81.99
60.00 60.00 51.00

96.31 111.03 167.97
76.71 96.86 77.03 99.20 74.85 96.66 110.08

75.53 97.87 73.32 100.86 111.37 95.98 146.79
80 Watt
C2H6 C3H6 C3H8 iC4
27.33 28.58 30.04 29.46 30.6 34.68 29.68
112.22 52.38 13.15
5.81 9.73 2.66
9.76 11.12 9.58
6901.19 5448.36 56.52 3.74
32.64 9706.08 8041.06 10.24
172.20 258.56 215.00 165.22
26.81 171.47 0.45 259.06
199.70 106.11 0.27
78.36 44 92.82
17.45 18.75 12.90 15.23
3.26 3.61 2.75

32.36 34.60 23.45
0 0 0 0 0 0 0
0 0 0 0
FID concentration FID concentration FID concentration FID
9.51 3.32 2.58 1.45 12.63 3.19 4.77
10.10 1.76 9.84 2.77 6.93 0.87 2.36
22.63 3.95 15.00 4.22 33.27 4.20 4.67
17.45 82.55 2.86 0.80 10.96 1.38 4.04
3.02 0.35 18.75 81.25 39.23 3.30 18.42
15.80 1.84 13.80 2.59 12.90 87.10 7.00
2.65 0.23 9.87 1.39 2.36 0.15 15.23
19.85 1.73 6.13 0.86 1.34 0.08 34.47
32.23 11.25 15.79 5.92 85.81 14.44 0.00
80.00 80.00 80.00

105.33 124.84 64.51
91.50 95.74 76.25 95.33 106.71 100.28 75.73

84.49 97.81 53.59 95.93 142.23 98.43 46.45

9.43 0.96 9.84 0.70 11.73 2.31 16.67
31.61 5.96 30.47 6.00 70.35 10.78 81.99
13.51 1.27 10.85 1.60 4.11 0.47 9.26
22.31 2.10 16.81 2.48 17.70 2.03 15.83
9.43 90.57 3.15 0.46 8.30 0.95 6.50
2.60 0.16 9.84 90.16 33.19 2.54 18.83
14.14 0.89 22.65 2.23 11.73 88.27 8.20
1.12 0.05 13.41 0.99 1.52 0.09 16.67
17.94 0.85 7.79 0.57 0.00 0.00 46.82
17.45 3.32 18.75 1.45 12.90 3.19 15.23
32.23 11.25 15.79 5.92 85.81 14.44 0.00
10.10 1.76 9.84 2.77 6.93 0.87 2.36
22.63 3.95 15.00 4.22 33.27 4.20 4.67
17.45 82.55 2.86 0.80 10.96 1.38 4.04
3.02 0.35 18.75 81.25 39.23 3.30 18.42
15.80 1.84 13.80 2.59 12.90 87.10 7.00
2.65 0.23 9.87 1.39 2.36 0.15 15.23
19.85 1.73 6.13 0.86 1.34 0.08 34.47
Atom balance
iC4H10 nC4H10 Cout/Cin Hout/Hin
0.26 0.43 0.95 1.01
0.00 0.28 0.87 1.13
0.67 1.84 0.95 0.98
0.05 0.85 0.97 0.98
0.99 0.57 0.89 1.01
0.09 0.00 0.97 0.96
83.33 5.94 1.04 1.00
2.33 91.63 1.03 0.98
6.1 10.1
0.0 5.7
6.6 18.0
0.8 13.4
10.9 6.4
1.0 0.0
28.4
21.0
1.04 1.73
0 1.12
2.69 7.35
0.21 3.38
3.96 2.3
0.35 0
0 23.78
9.3 0
9.6 15.9
0.0 15.0
11.3 30.8
1.5 23.4
17.4 10.1
2.0 0.0
42.5
32.9
ntration [%] Atom balance
C3H8 iC4H10 nC4H10 Cout/Cin Hout/Hin [1]
0.93 0.26 0.43 0.95 1.01
0.00 0.00 0.28 0.87 1.13
0.67 0.67 1.84 0.95 0.98
0.89 0.05 0.85 0.97 0.98
2.23 0.99 0.57 0.89 1.01
88.27 0.09 0.00 0.97 0.96
1.39 83.33 5.94 1.04 1.00
1.46 2.33 91.63 1.03 0.98
iC4H10 nC4H10
after before after
37.48 27.35 29.17
8.3 5.56
6.10 3.50
7.82 5.56
3.81 3.67
8.44 4.48
3.45 4.50
162.49 7.42
16.28 245.85 211.26
114.15
190.58 8.37
2.77
24.88
0 0 0
0
concentration FID concentration
2.36 5.61 1.27
2.35 9.57 1.08
4.02 20.27 2.29
1.65 11.29 1.28
3.19 18.01 1.36
1.39 19.31 1.46
83.33 41.13 2.33
5.94 8.37 91.63
20.82 0.00 0.00
60.00 60.00
68.79 0.00
104.23 125.19 102.69

100.47 61.82 98.34
iC4H10 nC4H10
after before after
31.83 27.35 29.17
9.64 5.56
1.76 3.50
2.61 5.56
2.68 3.67
9.33 4.48
3.33 4.50
204.79 7.42
13.56 245.85 211.21
8.39
2.47
24.31
0 0 0
0
concentration FID concentration
2.21 5.59 1.27
0.55 9.55 1.08
1.08 20.22 2.29
0.94 11.26 1.28
2.85 17.96 1.36
1.08 19.26 1.46
84.77 41.01 2.33
4.00 8.39 91.61
0.00 0.00 0.00
80.00 80.00
0.00 60.12
97.48 124.84 102.67

93.33 61.67 98.32
iC4H10 nC4H10
2.36 8.37 1.27
20.82 0.00 0.00
2.35 9.57 1.08
4.02 20.27 2.29
1.65 11.29 1.28
3.19 18.01 1.36
1.39 19.31 1.46
83.33 41.13 2.33
5.94 8.37 91.63
2.21 8.39 1.27
0.00 0.00 0.00
0.55 9.55 1.08
1.08 20.22 2.29
0.94 11.26 1.28
2.85 17.96 1.36
1.08 19.26 1.46
84.77 41.01 2.33
4.00 8.39 91.61
60W
0 0.06 0.18 0.5 0.02 0.3 0.13
1.31 0 0.17 0.18 0.31 0.06 0.14
0.08 1.79 0 0.01 0.22 0.02 0.25
0.11 0.3 1.03 0 0.07 0.67 0.15
0.09 0.23 0.33 0.14 0 0.53 0.54
0.06 0.97 0.16 0.49 0.48 0 0.7
0.06 0.67 1.28 0.89 1.28 1.45 0
0.74 1.07 2.27 0.39 1.05 0.33 1.38
CH4
0 0.11 0.01 0.17 0.05 0.22 0.03
0 0 4.29 3.86 2.39 0.82 5.84
0.03 0.49 0 0.05 0.01 0.09 0.02
4.33 0.04 0.13 0 2.96 0.43 0.05
5.24 0.39 0.12 0.16 0 1.85 0.84
0.04 0.37 0.41 0.14 1.04 0 0.42
1.44 0.95 1.71 5.28 0.04 0.88 0
0.63 6.79 0.6 0.73 0.14 2.25 0.79
C2H4
0 0.08 0.42 0.2 0.01 0.55 0.13
0.42 0 2.57 0.43 0.97 3.03 0.77
0.07 0.24 0 0 0.14 0.03 0.26
2.87 0.35 0.61 0 1.72 4.21 0.25
0.79 1.31 0.83 1.1 0 0.76 0.49
1.96 2.02 1 0.68 0.97 0 1.65
0.68 1.93 2.82 1.21 0.89 1.01 0
0.19 0.24 2.9 0.93 2.02 0.01 1.09
C2H6
0 0.1 0.57 0.2 0.01 0.92 0.34

1.82 0 2.54 0.54 1.82 0.59 0.59
0.08 0.12 0 0 0.21 0 0.6
0 0.16 0 0 0 0.01 0.21
0.15 2.01 0.6 2.53 0 0.08 0.99
1.06 1.3 0.89 0.12 1.2 0 1.06
0.79 2.11 2.47 2.55 0.48 3.34 0
0.61 0.24 1.78 0.47 1.52 0 0.14
C3H6
0 0.03 0.4 0.17 0.01 0.6 0.33

0.32 0 0.61 1.03 0.6 0.4 1.09
0.1 0.29 0 0 0.15 0 5.29
0 0.18 0 0 0 0 0.17
0.02 0 0.17 0 0 0.13 0
0.03 3.02 0.2 0.19 0.02 0 1.21
0.88 6.68 0.75 2.02 0.14 1.9 0
1.02 0.08 4 0.29 2.72 0 0.2
C3H8
0 0.05 0.19 0.26 0.01 0.29 0.01

0.3 0 0.53 0.45 1.89 0.61 1.29
0.23 0.17 0 0 0.45 0 1.87
0 0.26 0 0 0 0 0.21
0.03 0 0.12 0 0 0.22 0
0.05 0.04 0.11 0 0.07 0 0.19
2.75 0.01 0.88 2.03 0.28 2.87 0
1.76 0.03 4.2 0.1 5.2 0.01 0.17
iC4H10
0 0.02 0.32 0.19 0.02 0.38 0.02
0.07 0 0.67 0.71 0.8 0.6 0.41
0.02 0.23 0 0 0.37 0 2.56
0 0.5 0 0 0 0 0.09
0.02 0 0.2 0 0 0.38 0
0.04 0.03 0.46 0 0.01 0 0.19
0.07 0.01 0.15 0.06 0.05 0.05 0
0.92 0.06 2.35 0.19 2.69 0.01 0.23
n-C4H10
0 0.03 0.17 0.08 0.02 0.52 0.02
0.06 0 0.72 1.26 0.7 0.71 0.35
0.02 0.18 0 0 0.2 0 1.94
0 0.6 0 0 0 0 0.09
0.05 0 0.26 0 0 0.29 0
0.03 0.02 0.35 0 0.02 0 0.2
0.08 0 0.21 0.08 0.06 0.11 0
0.05 0.06 0.08 0.02 0.04 0.01 0.05
1 2 3 4 5
0.29 1 0.0 5.3 11.6 6.5 7.5
1.47 2 8.1 0.0 12.0 8.4 38.6
1.01 3 8.5 8.6 0.0 18.9 6.2
0.94 4 17.3 6.1 9.2 0.0 18.0
0.53 5 21.8 35.1 7.8 7.0 0.0
0.97 6 13.5 11.3 28.2 8.1 10.8
2.45 7 20.6 36.2 7.7 21.7 8.2
0 8 7.2 21.8 6.4 8.0 18.3
0
0.47
0.03
3.53
0.13
2.39
6.18
0
0.4
0.13
0.02
0.25
0.59
3.28
4.14
0
0.6
0.1
0.01
0
0.4
0.03
3.86
0
0.89
0.06
0.02
0
0.04
0.02
2.18
0
0.04
0.08
0.01
0
0.04
0.02
0.26
0
0.06
0.04
0
0
0.14
0.07
0.32
0
0.04
0.07
0
0
0.1
0.05
0.23
0
6 7 8
kij
9.8 10.7 11.1 (1) CH4 (2) C2H2
20.7 16.1 9.1 (1) CH4 0 ( 0.0 ) 0.06 ( 5.3 )
15.6 9.1 9.9 (2) C2H2 1.31 ( 8.1 ) 0 ( 0.0 )
21.7 4.7 13.7 (3) C2H4 0.08 ( 8.5 ) 1.79 ( 8.6 )
10.9 8.5 7.1 (4) C2H6 0.11 ( 17.3 ) 0.3 ( 6.1 )
i
0.0 7.9 13.3 (5) C3H6 0.09 ( 21.8 ) 0.23 ( 35.1 )
8.3 0.0 8.9 (6) C3H8 0.06 ( 13.5 ) 0.97 ( 11.3 )
23.8 7.7 0.0 (7) i-C4H10 0.06 ( 20.6 ) 0.67 ( 36.2 )
(8) n-C4H10 0.74 ( 7.2 ) 1.07 ( 21.8 )
j
(3) C2H4 (4) C2H6 (5) C3H6 (6) C3H8 (7) i-C4H10 (8) n-C
0.18 ( 11.6 ) 0.5 ( 6.5 ) 0.02 ( 7.5 ) 0.3 ( 9.8 ) 0.13 ( 10.7 ) 0.29
0.17 ( 12.0 ) 0.18 ( 8.4 ) 0.31 ( 38.6 ) 0.06 ( 20.7 ) 0.14 ( 16.1 ) 1.47
0 ( 0.0 ) 0.01 ( 18.9 ) 0.22 ( 6.2 ) 0.02 ( 15.6 ) 0.25 ( 9.1 ) 1.01
1.03 ( 9.2 ) 0 ( 0.0 ) 0.07 ( 18.0 ) 0.67 ( 21.7 ) 0.15 ( 4.7 ) 0.94
0.33 ( 7.8 ) 0.14 ( 7.0 ) 0 ( 0.0 ) 0.53 ( 10.9 ) 0.54 ( 8.5 ) 0.53
0.16 ( 28.2 ) 0.49 ( 8.1 ) 0.48 ( 10.8 ) 0 ( 0.0 ) 0.7 ( 7.9 ) 0.97
1.28 ( 7.7 ) 0.89 ( 21.7 ) 1.28 ( 8.2 ) 1.45 ( 8.3 ) 0 ( 0.0 ) 2.45
2.27 ( 6.4 ) 0.39 ( 8.0 ) 1.05 ( 18.3 ) 0.33 ( 23.8 ) 1.38 ( 7.7 ) 0
(8) n-C4H10
( 11.1 )
( 9.1 )
( 9.9 )
( 13.7 )
( 7.1 )
( 13.3 )
( 8.9 )
( 0.0 )

Methane 1

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Methane 1

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tR (min) FID (area) tR (min) TCD tR (min) FID (height)

H2 1.99 0 4.4 1169.95

calibration data (area method)

CH4 1640.98 1640.69 1640.61 1639.77 1640.38 1640.49

C2H2 3006.26 3075.96 3086.79 3056.34

C3H8 4193.32 4327.03 4327.72 4080.38 4232.11

iC4H10 5660.91 5647.6 5654.26

calibration data (height method)

calibration data (area method)

iC4H10 12070.94 12163.77 12117.36

reactant CH4 Al2O3 ZSM5

power (Watt) 50.00

power 48.00 49.00 50.00

power 50.00 50.00 50.00

> 20% 0.4 #DIV/0! 0.33

83.70 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 166.40

#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!

85.64 58.61 92.82

2.77 2.89 2.75

115.56 #DIV/0! 120.60 #DIV/0! 69.90 #DIV/0! #DIV/0!

49.00 48.00 51.00

#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!

163.43 74.57 94.80

72.16 28.78 37.85

192.57 82.68 139.72

2.80 2.85 2.52

111.34 #DIV/0! 45.29 #DIV/0! 96.52 #DIV/0! #DIV/0!

50.00 50.00 49.00

#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!

3% Fe/Al2O3 3% Fe/ZSM5 3% Cu/Al2O3 3% Cu/ZSM5

#DIV/0! #DIV/0! #DIV/0! #DIV/0!

80.16 68.45 65.21 91.60

31.96 26.93 27.49 39.66

93.07 73.14 70.44 96.01

2.77 2.38 2.77 2.79

#DIV/0! 116.40 #DIV/0! 102.62 #DIV/0! 143.77 #DIV/0!

50.00 36.00 50.00 50.00

#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!

3% Cu/ZSM5 1% Pt/Al2O3 5% Mn/Al2O3 3% Ru/Al2O3

#DIV/0! 139.97 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!

#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!

3% Cu/ZSM5 1% Pt/Al2O3 5% Mn/Al2O3 3% Ru/Al2O3

118.99 146.47 152.37

44.78 57.06 63.38

152.81 253.82 282.6

2.72 2.29 2.38

#DIV/0! 121.63 #DIV/0! 128.80 #DIV/0! 136.39 #DIV/0!

50.00 50.00 51.00

#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!

3% Cu/ZSM5 1% Pt/Al2O3 5% Mn/Al2O3 3% Ru/Al2O3

#DIV/0! #DIV/0! #DIV/0!

#DIV/0! #DIV/0! #DIV/0!

frequency 20 kHz sample volume 500 uL

power (Watt) 60.00 60.00 60.00

power 80.00 80.00 80.00

3.08 3.28 3.39

31.61 30.47 70.35 81.99

60.00 60.00 51.00

76.71 77.03 74.85 110.08

3.26 3.61 2.75

32.23 15.79 85.81 0.00

80.00 80.00 80.00

91.50 76.25 106.71 75.73

C2H6 C3H6 C3H8 iC4H10