public of the Philippines DAVAO ORIENTAL STATE COLLEGE OF SCIENCE AND TECHNOLOGY San Isidro Campus, Davao Oriental

set b. Chem 11 Final Examination Instruction. Encircle the letter that corresponds with your answer Multiple Choice. 1. This is a result of changes in electron distribution; and formed when atoms combine. a. b. c. d. Chemical symbols Chemical bonds Periodic table Lewis symbol

2. The difference between a family and a group in the periodic table is that: a. Families are columns and groups are rows b. Families are rows and groups are columns c. Families determine the energy level of an element and groups determine the number of valence electrons d. None of the above 3. Which guideline shows that atoms tend to gain, lose, or share electrons until they are surrounded by eight valence electrons. a. b. c. d. Octet Rule Hunds Rule Lewis Rule Formal charge

4. Select the term best describing the series of elements: Mn, Fe, Co, Ni, Cu. a. d-transition metals b. representative elements c. mettaloids d. alkaline earth metals

5. Which of the following properties of the alkali earth metals decreases with increasing atomic weight? a. ionic radii b. ionization energy c. atomic radii d. atomic number

6. Which statement is wrong? a. The atomic weight of carbon is about 12. b. The most stable ion of lithium is Li+. c. A phosphorous atom is larger than an antimony atom. d. The radius of a sodium atom is larger than that of a sodium ion. 7. Which element would have the higher electron affinity? a. Cl b. Br c. Both should have the same electron affinity because they are in the same group of the periodic table and both will gain only one electron. e. They have the same electron affinity.

8. Which of the following elements has the greatest attraction for electrons in a covalent bond? a. Ge b. As c. Se d. Br 9. Which of the following ions has the smallest diameter? a. O2 b. Na+ c. F d. Al3+

10. Which of the following elements has the greatest electronegativity? a. Si b. P c. N d. O

11. All of the following properties of the alkali metals increase going down the group EXCEPT: a. atomic radius b. first ionization energy c. ionic radius d. atomic mass

12. Which of the following correctly describes the trend in electronegativity? a. b. c. d. increases across a period and decreases down a group decreases across a period and decreases down a group increases across a period and increases down a group decreases across a period and increases down a group

13. Which one of the following is not a form of chemical bonding? a. covalent bonding c. ionic bonding b. hydrogen bonding d. metallic bonding

14. Covalent bonds are least likely to be formed a. b. c. d. between atoms of the same element between atoms of the different elements on the right of the periodic table by head of the group element with high ionization energies between an element in Group IA and an element in Group VIIA

15. The smallest possible unit of a covalent bond is usually considered to be a/an a. atom b. cation c. molecule d. polyatomic ion

16. A triple bond exists when two atoms share ______ electrons. a. two b. three c. four d. six

17. Which one of the following statements about positive ions is incorrect? a. b. c. d. they they they they are are are are also known as cations formed when electrons are removed from atoms larger than the atom from which they are formed smaller than the atom from which they are formed d. AsF5

18. Which one of the following violates the octet rule? a. PCl3 b. CBr4 c. NF3 19. Which combination of atoms can form a polar covalent bond?

a. H and H b. H and Br c. N and N d. Na and Br 20. Which of the following four molecules are polar: PH3, OF2, HF, SO3?

a. all except SO3 b. only HF

c. only HF and OF2 d. all are polar molecules

21. Which of the following molecules is the most polar? a. hydrogen chloride, HCl b. hydrogen iodide, HI c. hydrogen molecule, H2 d. chlorine molecule, Cl2

22. The neutral atoms of all of the isotopes of the same element have a. different numbers of protons d. the same mass numbers b. equal numbers of neutrons e. the same masses c. the same number of electrons 23. Molecules are made up from two or more ... a. electrons b. atoms c. . substances d. mixtures 24. Pick the correct statement: a. Atomic number is the sum of the number of protons and neutrons. b. Atomic number is the number of protons. c. The number of electrons is the atomic number of an atom. d. Atomic number is the same as the mass number. 25. Which statement is correct? a. Mass number is the sum of protons, neutrons and electrons in an atom. b. Mass number is the sum of protons and electrons in an atom. c. Mass number is the sum of protons and neutrons in an atom. d. Mass number is the same as the atomic number. 26. Chemistry is the study of: a. substances b. mixtures c. elements e. all of the above are included in the study of chemistry 27. Water is an example of a. an element above b. an ion c. a compound

d. only a and c

d. a mixture e. all of the

28. The first step of the scientific method involves: a. forming a hypothesis b. making observations d. predicting the result of an experiment

c. performing an experiment e. formulating a hypothesis

29. A liquid is considered a. an element b. a compound c. a state of matter d. a metal e. a nonmetal 30. Which answer includes all the following that are chemical changes and not physical changes? I. freezing of water II. rusting of iron III. dropping a piece of iron into hydrochloric acid (H2 is produced) IV. burning a piece of wood V. emission of light by a kerosene oil lamp a. III and IV b. II and V b. an ion c. I ,II, II, IV and V c. a compound d. II, III, and V e. II, III, IV, and V e. all of

31. Iron is an example of a. an element the above

d. a mixture

32. Which type of change occurs when the size, shape, appearance, or volume of a substance is changed without changing its composition? a. chemical b. physical c. nuclear d. none of them 33. Dissolving salt in water is an example of which type of change? a .chemical b. physical c. nuclear d. none of them d. solubility e. temperature

34. An example of a chemical property is a. density b. mass c. acidity

35. Which of the following is not a pure substance? a. molten sodium chloride b. sodium chloride solution c. sodium chloride solid d. sodium chloride vapor e. none of them 36. A pattern or relationship that has been established based on a large amount of experimental data is a. theory b. hypothesis c. law c. sodium d. model d. manganese e. Ar e. scientific method e. molybdenum

37. The element with symbol Mn is called a. metal b. magnesium

38. Which of the following is classified as a metal? a. Ge b. As c. F d. V

39. Which element best characterizes an organic compound? a. Oxygen b. Carbon c. Hydrogen d. Nitrogen e. Sulfur

40. Identify the INCORRECT statement. a. Helium in a balloon: an element d. Mercury in a barometer: an element

b. Paint: a mixture c. Tap water: a compound e. Polluted air: a homogenous mixture

41. The number 10.00 has how many significant figures? a. 1 b. 2 c. 3 d. 4 e. 5 42. The molecule below that is an acid is a. NaCl b. KCl c. CCl4 d. HCl e. MgCl2 43. The element below which is a nonmetal is a. silicon b. sodium c. carbon d. both a and c e. a, b and c are all nonmetals 44. 20 m/s is the same as: a. 0.02 km/s b. 2000 mm/s c. 200 cm/s d. 0.002 mm/s e. 6 e. 20 cm/s

45. The number 0.005436 has how many significant figures? a. 7 b. 3 c. 4 d. 5

46. Two students, Joshua and NJ, determined the mass of an object on two different balances. The accepted mass of the object was 2.355 g. Joshua obtained values of 2.531g, 2.537 g, 2.535 g and 2.533 g. NJ obtained values o 2.350 g, 2.404 g, 2.296 g and 2.370 g. Which statement best describes the results that were obtained by Joshua and NJ?

a. Joshua obtained the better accuracy. b. NJ obtained the better accuracy. c. Joshua obtained the better precision. d. NJ obtained the better precision. e. Both Joshua and NJ obtained accuracy and precision. 47. The correct dimensional analysis for the conversion of 6.30 kilometers to miles is: kilometers meters miles a. 6.30 b. 6.30 c. 6.30 miles kilometers kilometers centimeter s miles d. 6.30 e. 6.30 miles miles 48. What is the appropriate SI unit for distance? a. centimeters b. inches c. meters d. kilometers d. 0.00002 mg d. electron e. atom e. miles e. 2 mg

49. How many milligrams are in 0.2 decigrams? a. 20 mg b. 2000 mg c. 0.002 mg 50. Which of the following has a positive charge? a. proton b. neutron c. anion

51. According to Daltons atomic theory, a compound is a unique collection of a. like atoms b. atoms with the same atomic number c. atoms in varying proportions d. different atom types in whole number ratios e. all of them 52. Consider the species 72 Zn , 75 As , 74 G . These species have the: e a. same number of electrons b. same number of protons c. same number of neutrons d. same number of protons and neutrons e. same mass number 53. The neutral atoms of all of the isotopes of the same element have a. different numbers of protons b. equal numbers of neutrons d. the same mass numbers e. the same number of electrons 54. Which atom contains exactly 15 protons? a. P 32 b. O 15 c. N 15 d. only a and b e. only b and c c. the same masses

55. An ion with 5 protons, 6 neutrons, and a charge of 3+ has an atomic number of a. 5 b. 6 c. 8 d. 11 e. 2

56. The neutral atomic particle that resides in the nucleus is the a. electron b. proton c. neutron d. nucleus e. both b and c are correct answers 57.
31

P + has _____ protons, _____ neutrons, and _____ electrons.

a.31, 15, 30 b.15, 31, 15 c. 15, 31, 14

d. 15, 16, 14

e. 15, 16, 16

58. The number of neutrons in an atoms nucleus is given by: a. atomic number (Z) b. mass number (A) c. atomic particles in the nucleus d. the electrons in the nucleus e. mass number atomic number 59. With regard to the species 16 O 2 , 19 F and 20 N , which of the following statements is correct? e a. All three species contain 10 electrons. b. The sum of the neutrons in all three species is 27. c. The sum of the protons in all three species is 28. d. Both 19 F and 20 Ne contain 20 neutrons.

e. none of the above 60. Which name/formula combination is WRONG? a. phosphorous acid/H3PO4 b. nitrogen monoxide/NOc. acetate ion/CH3COOd. sodium chromate/Na2CrO4 e. calcium hypobromite/Ca(BrO)2 61. An unused flashbulb contains magnesium and oxygen. After use, the contents are changed to magnesium oxide but the total mass does not change. This observation can best be explained by the a. Law of Constant Composition b. Law of Multiple Proportions c. Avogadros Law d. Law of Conservation of Mass e. Boyles Law 62. Which of the following choices provides the best description of an isotope? a. Atoms with the same number of protons but differing numbers of electrons. b. Atoms with the same mass number but differing atomic numbers. c. Atoms with the same mass numbers and the same atomic numbers. d. Atoms with the same atomic numbers but differing mass numbers. e. none of the above 63. The cation Cu 2 + is best named as a. copper (I) b. cesium (I) c. copper (II)

d. copper (III)

e. cesium (III)

64. What is the oxidation number for carbon in CaC 2 O4 ? a. 0 b. +2 c. +3 d. +4 e. +6 54. The identity of an element is determined by a. the number of its protons b. the number of its neutrons d. its atomic mass e. all of the above c. the number of its electrons

66. Determine the oxidation number of carbon in K 2 CO 3 . a. 0 b. +2 c. +4 d. -2 e. some other value 67. The charge on the lead atom in the compound Pb ( SO 4 ) 2 is a. 0 b. +1 c. +2 c. +3 e. +4 68. Which one of the formulas for ionic compounds below is incorrect? a. SrCl2 b. Cs2S c. AlCl3 d. Al3P2 e. CaSe

69. Which name/formula combination is WRONG? a. chlorous acid/HClO2 b. dinitrogen tetroxide/N2O4 c. ammonium nitrate/NH4NO3 d. copper (II) periodate/CuIO4 e. potassium permanganate/KMnO4 70. Of the following name/symbol combination of elements, which one is WRONG? a. uranium/U b. sulfur/S c. nitrogen/N d. potassium/K 71. Aluminum is in Group III. Its oxide will have the formula Al3O2 e. AL2O3 a. AlO b. AlO2 e. iron/I c. Al2O3 d.

72. Which of the following choices is the correct name for H2CO3? a.dihydrogen carbon b. carbonic acid carbon e. dihydrogen carbonate c. hydrogen carbon oxide d. hydrogen

73. A student wrote the following formulas for various compounds: I. copper (I) chloride CuCl III. lead (II) hydroxide Pb(OH)2 II. sodium chlorate NaClO3 IV. magnesium nitrate Mg(NO3)2

Which of the following statements is true? a. All of the formulas are correct. b. Only formulas I, III and IV are correct. c. Only formulas I, II and III are correct.d. Only formulas II, III and IV are correct. 74. Balance the molecular equation for the following redox reaction. What is the sum of the coefficients? Do not forget coefficients of one (1). Use the smallest whole number coefficients possible. H2SO4(aq) + HI(aq) I2(s) + SO2(g)

a. 7 b. 9 c. 11 d. 13 e. 5 75. When iron pyrite (FeS2) is heated in air, the process known as "roasting" forms sulfur dioxide and iron(III) oxide. When the equation for this process is completed and balanced, using the smallest whole number coefficients, what is the coefficient for "O2"? ___ FeS2 a. 2 b. 4 + ___ O2 d. 8 ___ SO2 + ___ Fe2O3

c. 7

e. 11 c. monocarbon monoxide

76. The correct name of the molecule CO2 is a. carbon oxide b. carbon dioxide d. monocarbon dioxide e. carbonate

77. Which one of the sets below represents the correct values for the coefficients w, x, y, and z in the following equation? (w) Fe(NO3)3 a. b. c. d. w 2 2 4 4 x 1 2 2 2 y 6 6 3 12 z 3 3 3 3 (x) Fe2O3 + (y) NO2 + (z) O2

78. The number of sulfur atoms in the molecule Al2(SO4)3 is a. 0 b. 1 c. 2 d. 3 e. 4 79. Which one of the following could be an empirical formula? a. C9H15N3O6 b. C14H10CuO4 c. C17H25NO3 d. C8H18O3 e. All of these could be empirical formulas 80. When barium sulfate is formed from the reaction of barium and sulfur trioxide, it is a/n _________ reaction. a. Combination b. Decomposition c. Single replacement d. Double displacement e. Neutralization 81. Analysis of a sample of a covalent compound showed that it contained 14.4% hydrogen and 85.6% carbon by mass. What is the empirical formula for the compound? a. CH b. CH2 c. CH3 d. C2H3 e. none of these 82. A compound contains, by mass, 40.0% carbon, 6.71% hydrogen, and 53.3% oxygen. A 0.320 mole sample of this compound weighs 28.8 g. The molecular formula of this compound is: a. C2H4O2 b. C3H6O3 c. C2H4O d. CH2O e. C4H7O2

83. Guanidin, HNC(NH2)2, is a fertilizer. To three significant figures, what is the percent by mass of nitrogen in the fertilizer? a. 45.2% b. 49.4% c. 54.8% d. 65.1% e. 71.1% 84. How many atoms are in one mole of CH3OH? a. 6 b. 6.0 1023 c. 12.0 1023 d. 3.6 1024 e. 3 e. 2.45 1022

85. How many aluminum atoms are there in 3.50 grams of Al2O3? a. 4.13 1022 b. 4.90 1022 c. 2.07 1022 d. 1.68 1022

86. What is the volume of a 2.50 gram block of metal whose density is 6.72 grams per cubic centimeter? a. 16.8 cubic centimeters b. 2.69 cubic centimeters c. 0.0595 cubic centimeters d. 0.372 cubic centimeters e. 1.60 cubic centimeters

87. How many moles of KBrO3 are required to prepare 0.0700 moles of Br2 according to the reaction: KBrO3 + 5KBr + 6HNO3 6KNO3 + 3Br2 + 3H2O

a. 0.210 b. 0.0732 c. 0.0704 d. 0.220 e. 0.0233 88. Calculate the mass of hydrogen formed when 25 grams of aluminum reacts with excess hydrochloric acid. 2Al + 6HCl Al2Cl6 + 3H2 a. 0.41 g b. 1.2 g c. 1.8 g d. 2.8 g e. 0.92 g

89. When 12 g of methanol (CH3OH) was treated with excess oxidizing agent (MnO4-), 14 g of formic acid (HCOOH) was obtained. Using the following chemical equation, calculate the percent yield. (The reaction is much more complex than this; please ignore the fact that the charges do not balance.) 3CH3OH + 4MnO4 3HCOOH + 4MnO2 a. 100% b. 92% c. 82% d. 70% e. 55% 90. If 5.0 g of each reactant were used for the the following process, the limiting reactant would be: 2KMnO4 + 5Hg2Cl2 + 16HCl 10HgCl2 + 2MnCl2 + 2KCl + 8H2O a. KMnO4 b. HCl c. H2O d. Hg2Cl2 e. HgCl2

91. Silicon carbide, an abrasive, is made by the reaction of silicon dioxide with graphite. SiO2 + 3C SiC + 2CO If 100 g of SiO2 and 100 g of C are reacted as far as possible, which one of the following statements will be correct? a. 111 g of SiO2 will be left over. b. 44 g of SiO2 will be left over. c. 82 g of C will be left over. d. 40 g of C will be left over. e. Both reactants will be consumed completely, with none of either left over. 92. The limiting reagent in a chemical reaction is one that: a. has the largest molar mass (formula weight). b. has the smallest molar mass (formula weight). c. has the smallest coefficient. d. is consumed completely. e. is in excess. 93. What is the molarity of phosphoric acid in a solution labeled 20.0% phosphoric acid (H 3PO4) by weight with a density = 1.12 g/mL?

a. 0.98 M

b. 2.3 M

c. 2.7 M

d. 3.0 M

e. 3.6 M

94 . What Kelvin temperature is equal to 25C? a. 248 K b. 298 K c. 100 K d. 200 K e. 273 K

95. Thirty (30) mg is the same mass as: a. 300 dg b. 0.3 grams c. 0.0003 kg d. 0.03 g e. 3OO cg