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RAMEES HASSANAR
Definitions
A calorimeter measures the heat into or out of a sample. A differential calorimeter measures the heat of a sample relative to a reference. A differential scanning calorimeter does all of the above and heats the sample with a linear temperature ramp. Endothermic heat flows into the sample. Exothermic heat flows out of the sample.
Conventional DSC
Sample
Metal 1 Metal Metal 2 1
Empty
Metal 2
Sample Temperature
Reference Temperature
DSC Thermogram
Crystallisation
Cross-Linking (Cure)
Oxidation
Glass Transition
Melting
Temperature
6
DSC
File: C:...\DSC\Melt Mixed1\PET80PC20_MM1.001 Operator : SAC Run Date : 05-Apr-2006 15:34 Instrument : DSC Q1000 V9.4 Build 287
Tm
245.24C
1.0
Tg
Heat Flow(W/g)
0.5
79.70C(I) 75.41C 81.80C
Tc
137.58C 20.30J/g 228.80C 22.48J/g
Cycle 1
0.0
144.72C
-0.5
Exo Down
50
100
150
200
250
300
Universal V 4.2E TA Instruments
Temperature (C)
Sample mass
Processing errors
99
Good for:
Poor for: Accuracy: transitions can be shifted by as much as 40oC Repeatabiliy: Very sensitive to thermal lag.