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NON-IDEAL RHEOLOGICAL BEHAVIOR
FLUID (VISCOUS BEHAVIOR) SOLID (ELASTIC BEHAVIOR)
Newtonian Non-Newtonian Non-Hookean Hookean
FLUID-SOLID
Time-Dependent
Rheopectic Thixotropic
Structural Models
Time-Independent
Power Law Bingham Herschel-Bulkley Other Models
Non-Linear Elastic
Viscoelastic
Maxwell Burgers Kelvin
Dilatant Pseudoplastic
q =
t
=
shear stress
shear rate
According to
Newton
NON-NEWTONIAN FLUIDS
Fluid systems may be non-ideal in two ways:
1. The viscosity may depend on shear rate
2. The viscosity may depend on time
Some (many) may have both
http://youtube.com/watch?v=f2XQ97XHjVw
Newtonian fluids, viscosity does not depend on
the shear rate. Fluid begins to flow when ever
a shear stress is applied
FLUID q (mPa.s)
Water 1
Coffee cream 10
Vegetable oil 100
Honey 10,000
Asphalt 100,000
Shear Rate (s
-1
)
.
Shear Stress
t (Pa)
Honey
Oil
Water
q = slope of
this line
SHEAR-DEPENDENT FLUIDS
Plastic (Bingham Plastic): some finite
shear stress must be applied before the
material will flow. This minimum stress
required is known as the yield stress.
Examples include margarine, whipped
toppings, mayonnaise, or catsup.
Shear Rate (s
-1
)
.
Shear Stress
t (Pa)
True Bingham
Yield stress
Apparent viscosity
q
A
=t/ given by
slope of this line
Shear Rate (s
-1
)
.
Apparent
Viscosity
q
A
Pseudoplastic (shear thinning): An increasing
shear force gives a more than proportional
increase in shear rate.
The material seems less viscous at higher
shear rates.
Examples include some salad dressings,
concentrated fruit juices, and French mustard.
Shear Rate (s
-1
)
.
Shear Stress
t (Pa)
q
A
Shear Rate (s
-1
)
.
Apparent
Viscosity
q
A
Dilatant (shear thickening): Increasing shear
force gives a less than proportional increase
in shear rate; the material seems to be more
viscous at higher shear rates.
Dilatant food systems are not common.
Examples are some cooked starch
suspensions.
Wet sand
Wet starch at
40-70% solids
Shear Rate (s
-1
)
.
Shear Stress
t (Pa)
q
A
Shear Rate (s
-1
)
.
Apparent
Viscosity
q
A
Herschel-Bulkley: these fluids exhibit
both a yield stress and pseudoplastic
behavior
Shear Rate (s
-1
)
.
Shear Stress
t (Pa)
MODELS FOR SHEAR
DEPENDENT FLUIDS
Power Law model: shear stress varies
as the shear rate to some power
where K is the consistency index, and n is
the flow behavior index.
t = K
n
Bingham model: model of Newtonian
fluid, but includes a yield stress term,
and the plastic viscosity q
t = t
o
+q'
Herschel-Bulkley model: power law but
includes a yield stress term to.
t = t
o
+ K
n
Casson model: used to estimate yield
stress. Official method for interpreting
chocolate flow data. The Casson plastic
viscosity is given by q
c
=K
c
2
, and the
Casson yield stress by t
c
=K
oc
2
.
t = t
o
+q
a
Powell-Eyring model:
t =q
+
q
o
q
|
sinh
1
(|
)
where o and | are constants, q
o
is the limiting viscosity
at zero shear rate, and q