KIMIA ANALISIS

Base
Calcium can be precipitate as Calcium Oxalate
with slightly base pH condition. Because of
CaO is unstable, after the ashing process, the
ash should become Calcium Sulfate which is
stable.
Purpose
The Purpose of this determination is to
determine the value of Calcium in CaCO
3
Reaction
1. CaCO
3
+ 2HCl CaCl
2
+ H
2
O + CO
2
2. CaCl
2
+ (NH
4
)
2
C
2
O
4
+ H
2
O CaC
2
O
4
.H
2
O +
NH
4
Cl
3. CaC
2
O
4
.H
2
O CaC
2
O
4
+ H
2
O
4. CaC
2
O
4
CaCO
3
+ H
2
O
5. CaCO
3
CaO + CO
2

6. CaO + H
2
SO
4
CaSO
4
+ H
2
O
Equipment and Materials
1. Watch Glass
2. Beaker Glass 400ml
3. Stirring Rod
4. Wash Bottle
5. Bunsen
6. Wire Gauze
7. Measuring Cylinder 50ml dan 250ml
8. Thermometer
9. Funnel
10. Funnel Holder
11. Beaker Glass 800ml
12. Pippete
13. Test Tube
14. Rubber Policemen
15. Meker Burner
16. Porcelain Triangle
17. Crucible
18. Steel Tongs
19. Decikator
20. Oven
21. Steam Bath
22. Googles
23. Cover Glass
24. Three Pod





1. HCl 4N
2. (NH
4
)
2
C
2
O
4
4%
dan (NH
4
)
2
C
2
O
4

0,1 %
3. NH
4
OH 4N
4. H
2
SO
4
4N
5. Aqua De
6. Methyl Red
indicator
7. Filter Paper 42



Procedure
Enter the sample into 400ml
beaker glass and dilute it with
25 ml aquadest




















Larutkan dengan 15 ml HCl 4N,
Panaskan sampai larut sempurna
Dilute the rest of the undissolved sample with
15ml Cloride Acid 4N and the heat it until
perfectly diluted.















Encerkan larutan dengan air suling sampai 100 ml
Add aquadest until reach 100 ml total solution
Panaskan larutan hingga 90C
Heat the solution until 90
o
C















Tambahkan 5 tetes indikator MM
Add 5 drops of Methyl Red indicator















Tambahkan (NH)CO 4% (hitung dulu jumlah yang diperlukan
Add Ammonium Oxalate 4%(Firstly, calculate the amount of
Ammounium Oxalate needed)
Netralkan larutan dengan NH
4
OH hingga larutan berwarna sindur
Netralize the solution by adding the Ammonium Hydroxide until
the solutions colour change into orange.
Taruh diatas Penangas Air 1 Jam
Put the solution on the water bath 1 hour.
Testing the complete precipitation by
drops little amount of (NH
4
)
2
C
2
O
4
Filter the solution with Filter Paper
number 42
Dry the precipitate into oven
After the precipite dry, put it in the
crucible and burn it until white ash
form
After Ashing process, let the crucible cool
down and drop little amount of aquadest
Add 2ml H
2
SO
4
4N
Steamed the crucible in the fumehood
until the white smoke is dissapear
After all white smoke is not form anymore,
repet the ashing process until get the
stable process
Finish