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Lecture 1
Francisco J. Trujillo
1. Introduction
What is fluid
mechanics?
Movement of fluids.
Well-developed body of
theory.
Describes the flow of
product through
equipment
So, how can we use
fluid mechanics in the
chemical industry?
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Two types of
problems
Micro - focus on specific details in
Example 1: Flow in a
tube
For simplicity, in engineering and applications it is
d
x
Example 2: heat
exchangers
Q& UATlm
& PTi
Q&i mc
& PTo
Q&o mc
& P To Ti
Q& UATlm mc
Example 2: heat
exchangers
2. Vector Analysis
will have gone a total of 7 kilometres, but you are not 7 kilometres from
where you set out.
3k
4k
5k
Vectors describe quantities like this , which evidently do not add in the
ordinary way.
Vectors have direction as well as magnitude (length) and is essential to
Vectors
Bold type or a bar over a variable indicates
a vector.
v v vxi v y j vz k vx v y
vx
vz vx , v y , vz v y
v
z
vectors
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13/76
Magnitude of a Vectors
A vector has magnitude or norm: which is the length of
the arrow 3 k
5k
4k
5k
4k
3k
v a 2 b2
In the example:
c 42 32 5
Direction of a Vectors
The direction of a vector can be calculated as:
c
5k
4k
3k
as:
a
tan
b
a
arc tan
b
Unit vector
The direction of the vector can also be given as a unit
Norm:
Unit vector:
vx
v vx i v y j vz k v y
v
z
v vx2 v 2j vx2
vx v
) vx v y vz
u i
j k v y v
v
v
v
v v
z
v 3i 4 j
the vector below
4
5k
v 32 42 5
4k
) 3 4 3 5
u i j
4
5
5
5
3k
)
3 4
u
5 5
)
u
9 16
25
1
25 25
25
v1 3i 4 j
For instance lets assume that v is the velocity vector:
4
3 5 3 15
v2 5v1 5
4
5
4 20
v1 32 4 2 5
v 2 152 202 25
a
)
v ai bj ck b
c
scalar
m a
)
mv m ai m bj m ck m b
m c
Vector
result to be a scalar.
For instance the mass flow trough a pipeline can be calculated as:
m& vA
density
area
flow
velocity
This example is one dimensional as the velocity is perpendicular to
the area.
But what happens in a 3D example?
vector of air.
The black arrow is the unit vector that indicates the direction of the window
(perpendicular direction to the plane):
b)
a)
air
c)
air
air
On which arrangement there will be a bigger mass flow entering the window?
On a) then b) and finally on c) where air cannot pass through the window
b)
a)
air
c)
air
air
u1
v1
u u2 v v2
u.v u1v1 u2 v2 u3v3
u
v
The dot product can be used to give the correct
mass
3
3 flow (scalar) passing through
the window
a)
u Area
1
0
0
air
b)
c)
air
air
u Area
1
0
0
3
0
u Area
1
0
0
v 52 0 0 5
v 42 32 0 5
m& u.v 1 5 0 0 5
v 0 52 0 5
The velocity has changes direction but the norm is the same.
The dot product is given the right mass flow entering the window
The dot product multiply two vectors and the result is a scalar:
u1
u u2
u
3
v1
v2
v
3
u v u v cos
So the dot product is:
zero for perpendicular
vectors
Maximum for parallel vectors
u1
u u2
u
3
v1
v2
v
3
i j
u v u1 u2
v1 v2
k
u3
v3
a b a b sin
ij 0 if
i j
ijk 1
ijk 1
0
ijk
i j
instead of
1 1 2
1 2 2
2 3 3
3 3 1
1
0
1 1 2 2 3 3 0
1 2 3 ; 2 1 3
2 3 1; 3 2 1
3 1 2 ; 1 3 2
i, j, k
i, j, k
Tensors
Tensors have 9 components (e.g. stress):
xx xy xz
yx yy yz
zx zy zz
vx
ij
y
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Nomenclature
s
v=
several kinds
possible such as the single dot the double dot and
the cross .
Those special multiplications can produce a scalar, a vector or
Scalar
a tensor,
so for clarification we enclose these special
multiplications
= Vector in different kinds of parenthesis to indicate
the type of result:
Second order tensor
Nomenclature
No special significance is attached to the kind of
parenthesis if the only operation enclosed are addition and
:
in which , and do
subtraction, or a multiplication
not appear.
Hence:
v w Scalar
: v Scalar
v = Vector
v Vector
v Second order tensor
Nomenclature
Scalars can be regarded as zero-order tensors
Vectors as first-order tensors
The multiplication signs may be interpreted as:
Multiplication sign
none
In which
represents the sum of the order of the
quantities being multiplied
s
vw =
1 2
Is order 0 + 2 = 2
Is order 1 + 1 = 2
Is order 1 + 1 = 2
v w Is order 1 + 1 -1 = 1
:
Is order 2 + 2 - 4 = 0
Is order 2 + 2 - 2 = 2
Nomenclature
Appendix A of the textbook show all the
possible operations between scalars vectors
and tensors
Multiplication of a tensor by a
scalar
Multiplication of a tensor by a scalar
s xx s xy s xz
s s yx s yy s yz
s zx s zy s zz
Addition of tensors
The sum of two tensors is a tensor whose
components are the sum of the corresponding
components of the two tensors
xx xy xz
yx yy yz
zx zy zz
xx xy xz
yx yy yz
zx zy zz
xx xx xy xy xz xz
yx yx yy yy yz yz
zx zx zy zy zz zz
For a long time we only considered that two vectors could only be
multiplied as a dot product to yield a scalar, or a cross product to
yield a vector. Having been introduced to a tensor, the third way to
multiply the two vectors is to obtain a tensor - a dyadic product.
Having,
u
w
x
v u y
u
z
vx
vw vwT v y wx
v
z
wy
w wy
wz
vx wx
wz v y wx
vz wx
v x wy
v y wy
v z wy
vx wz
v y wz
vz wz
xx xy xz
yx yy yz
zx zy zz
xx xy xz
yx yy yz
zx zy zz
xx xx xy xy xz xz
yx yx yy yy yz yz
zx zx zy zy zz zz
: i j ij ji
: 11 11 12 21 13 31 21 12 22 22 23 32 31 13 32 23 33 33
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v
i
11 12 13
21 22 23
31 32 33
j ij
v1
v2
v
3
k k
v
21 1 22 2 23 3
v v v
31 1
32 2 33 3
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v i j i j ji k k vk
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Useful identities
uv w u v w
w uv w u v
uv : wz uw : vz u z v w
: uv u v
uv: u v
is a unit vector
(A.3-21)
(A.3-22)
(A.3-23)
(A.3-24)
(A.3-25)
Differential
calculus
Ordinary derivatives:
The derivative df/dx tell us how
rapidly the function f(x) varies
when we change the argument x
by a tiny amount dx:
df
dx
dx
df
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The operator
The operator
is called del:
i j k
x
y
z
x
y
z
Gradient:
Suppose now that we
have a function of 3
variables. For instance
the temperature T(x, y,
z) in a room. We want
to generalize the notion
of derivative to
functions like T, which
depends not on one but
three spatial variables.
A derivative is supposed to tell us how fast the
function varies. What in which direction?
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Gradient
The gradient, has the formal appearance of a
vector
, multiplying a scalar T:
T i j k T
y
z
x
T
x
T
T
y
T
z
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Gradient:
The gradient, which is defined as:
T T T
T
i
j
k
x
y
z
It is a vector quantity, with 3 components. It is the generalized
derivative that we were looking for.
The gradient has a magnitude and direction as any vector.
T
The gradient
the function T.
Gradient - utility
So when we see a collection of terms like this:
)
i
j k
x
y
z
it is quick and easy to instead write:
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Gradient
Example:
f ( x, y, z ) xy yz 2
f yi x z 2 j 2 yzk
f y, x z , 2 yz
2
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Divergence
v i j k vxi v y j vz k
y
z
x
vx v y vz
v
x y z
Divergence Geometrical
interpretation
The name divergence is well chosen. The divergence of a
vector is a measure of how much the vector spreads out
(diverges) from the point in question. It is a type of
derivative of a vector.
Figure (a) has a large positive divergence (if the arrows point
in, it will be a large negative divergence)
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Figure (b) has zero divergence
Divergence Geometrical
interpretation
Notice how the divergence is not just a change of direction,
but as you can see on figures a) and c) the vectors are
becoming bigger as if there were source that augments the
vector field.
Divergence - utility
So when we see a collection of terms like this:
vx v y vz
x y z
it is quick and easy to instead write:
v
with the same meaning.
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Divergence Example
g 3xyi 7 j ( 2 z 3 y )k (3xy, 7, 2 z 3 y)
g 3 y 0 2 3 y 2
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The Curl
From the definition
of
i
v
x y z
vx
v
v
y
z
vz v y vz vx v y vx
v
i
j
k
x z x y
y z
and v.
like any cross product, the curl is a vector.
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Curl - example
g 3xyi 7 j (2 z 3 y )k (3xy, 7, 2 z 3 y)
i
g
x
3xy
y
z
7 2 z 3 y
The gradient of a
Vector field
Is the dyadic product
of
and v. It yields a
tensor
x
T
v v v x
y
z
vy
vz
vx
x
vx
y
vx
z
vy
x
vy
y
vy
z
vz
x
vz
y
vz
z
i i j k j k jk
x i
x
y
z
11 12 13
21 22 23
31 32 33
11 21 31
x y z
12 22 32
z
x y
13 23 33
z
x y
xx
x
xy
x
xz
x
yx zx
y
z
yy zy
y
z
yz zz
y
z
x
2
s s
y
z
Where
s
x
s
y
s
z
s s s
2 2 2
x y z
2
The laplacian operator
2
x
2
y
z
x
y
z
2 2 2s
2 2 2
x y z
Summary
GRAD:
(rate of change of a scalar
with direction and magnitude)
T T T
T
i
j
k
x
y
z
DIV:
(spread of the vector function
Measure of change of the vector field v
As it is expanding (source) or
Diminishing (sink) )
CURL:
(rotation, curl of the function)
vx v y vz
x y z
i
j
k
v
x y z
vx
vy
vz
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Summary
grad v
(tensor produced of the dyadic product of
Del operator and the vector v)
x vx
v
vx
y
z vx
vy
x
vy
y
vy
z
vz
x
vz
y
vz
z
Divergence of a tensor
(This is a dot product between del operator
and a tensor yielding a vector )
xx yx zx
x y z
xy yy zy
y
z
xz yz zz
y
z
x
Laplacian:
(It is the divergence of the gradient of the scalar s)
2s 2s 2s
s 2 2 2
x y z
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rs rs sr
sv s v s v
v w w v v w
sv s v s v
v v v
1
v v v v v v
2
is a unit vector
(A.4-18)
(A.4-19)
(A.4-20)
(A.4-21)
(A.4-22)
(A.4-23)
Useful differential
relations -II
Useful identities numbered as in the Appendix A of the
textbook:
(A.4-24)
vw v
w w v
s : v s v
s s
s s s
v w v w
w
(A.4-25)
(A.4-26)
(A.4-27)
(A.4-28)
(A.4-29)
Surface
integral
A surface integral is an expression of the form:
v.da
s
v.da
s
65/76
Volume
integral
A volume integral is an expression of the form:
d dx dy dx
v
v d
v da
v
67/76
3. Viscosity
Most important concept in fluids flow
Lower viscosity
Higher viscosity
Viscosity
Higher viscosity
Resistance to flow
Fluid initially at rest:
t<0
70/76
t=0
v
F
71/76
t small
vx(y,t)
TRANSIENT
v
F
72/76
t large
vx(y)
STEADY STATE
v
F
73/76
Viscosity
Common sense suggests that
F
V
A
Y
(3.1)
vf profile
(3.3)
y
Direction (shear or shearing force)
(3.2)
Where yx is the force per unit are
is understood that this force is excerpted by the
(stress) in the x direction on a un
uid of lesser y on the fluid of greater y (for the figure).
area in the y direction
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We also replace V/Y by -dv /dy
Viscosity
yx
vx
y
(3.3)
vf profile
x
STEADY STATE
Therefore:
yx
vx
y
Meaning of the
subscripts
yx
vf profile
x
STEADY STATE
Stress and
strain
Some definitions:
Shear stress
Force applied to an area
The direction of the force
caused by stress
Fluid cannot permanently
resist shear stresses
Note on Newtons
second law
Second law: the net force on a particle is equal to the time rate
of change of its linear momentum p (mass x velocity):
dp d mv
F p&
dt
dt
d v
F m
ma
dt
yx
vf profile
x
STEADY STATE
yx as flux of xmomentum
y
vf profile
yx
vx
y
(3.3)
x
STEADY STATE
vf profile
High viscosity
F
V
A
Y
Y
yx
vx
y
STEADY STATEv
Lower Viscosity
Lower Force F
Lower stress needed to
vf profile
STEADY STATEv
Higher Viscosity
Higher Force F
Higher stress needed to
overcome the friction
(viscosity) opposed to the
movement of the fluid layers.
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Higher viscous heat produced
Shear
strain
We call dvx/dy the rate of strain:
dvx
&yx
dy
If viscosity is not constant with stress, define
an instantaneous viscosity :
yx / &
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Newtonian
Flow
If is constant with fluid stress, then the fluid
is called Newtonian.
Many fluids are not Newtonian
83/76
Non-Newtonian
Behaviour
Bingham
(plastic)
pseudoplastic
Newtonian
dilatant
vx
y
84/76
Models:
Bingham
Model:
yx
dvx
o
o
dy
dvx
0
dy
yx
yx
Bingham
(plastic)
o
o
paints
85/76
vx
y
Models: Power
Law
Power law
yx
n
&
m
dilatant
vv
xx
yy
86/76
Structural
Models
Newtonian at very low and very high shear
1 &
where (4 constants):
o is low shear limiting viscosity
is high shear limiting viscosity
is a time constant
P is a shear thinning index.
vx
y
Examples:
polymer solutions, latex emulsions, mud (sediment)
87/76
yx
1 dvx
A sinh
B dy
Newtonian as o 0.
Many other models in literature.
88/76
Kinematic
viscosity
For convenience, define the kinematic viscosity as:
Using
viscosity
The stress terms are defined in terms of viscosity and
velocity gradients.
We derived a one-dimensional equation for shear for a
newtonian fluid:
vx
xy
y
92/74
Pressure
Viscous forces
Viscous forces come into play when there are velocity gradients.
They come with an angle to the surface.
Pressure is isotropic and only acts perpendicular to surfaces
.
Viscous
forces
x is a force per unit
area applied on the x
shaded area
x xx , xy , xz
y yx , yy , yz
z zx , zy , zz
Viscous
forces
x is a force per unit
area applied on the x
shaded area
x xx , yx , zx
Instead of
Because the second subscript indicates the force while the first
subscript indicates the area on which the force acts
96/74
97/74
Meaning of the
subscripts
yx
vf profile
x
STEADY STATE
98/76
xx xy
yx yy
zx zy
xz
yz
zz
99/74
v j
vx v y vz
vi
2
ij
3
ij
x x
x y z
i
j
Equations
To solve for the velocity distribution, we need
v v
Divergence of the
velocity vector
Transpose of the
velocity gradient tensor
23 v
Unit tensor with
components ij
102/74
Convective momentum
transfer
Momentum can also be transported by the bulk flow of fluid
In the figure lets consider that at the centre of the cube the velocity
vector is v.
Lets ask what the flux of momentum through each shaded plane
is(momentum / m2 s)
103/74
Convective momentum
transfer
First remember that the mass flow (kg/s) rate of the red
velocity vector passing through the yellow window is:
air
momentum _ flux vx v
Convective momentum
transfer
momentum _ flux x vx v
momentum _ flux y v y v
momentum _ flux z vz v
105/74
Convective momentum
transfer
l the convective momentum flux components form a tensor that can be simplify
Where
momentum _ flux vv
isvv
the dyadic products between the vectors and it forms a tensor
v x vx
vv v y vx
v z vx
vx v y
vyvy
vz v y
vx vz
v y vz
vz vz
106/74
107/74
Cylindrical
coordinates
109/74
Spherical coordinates
111/74
Prediction of
Viscosity
Gases and liquids
separately
Viscosity models
Viscosity is the characteristic property of a
113/76
114/76
Speed relates to
energy
From the kinetic theory of gases,
uT
0.5
T = absolute temperature
u = speed
sectional area:
115/76
Resistance to
flow
If there is a velocity gradient in the gas, then
Thus assume:
dvx
yx u
dy
116/76
Compare to viscosity
equation
Maxwell (1860) derived:
yx
dvx
u
dy
1
3
yx
dvx
dy
13 u
2
3
3 2
mkT
d2
117/76
How good?
This model works OK for low densities except
118/76
Potential
Well
PE
Based on Lennard-Jones
potential function:
12
PE 4
repel attract
is energy of interaction
r
between molecules.
is called collision diameter.
and measured at critical
points empirically (BS&L).
119/76
T = absolute temperature, K
= diameter,
M = molecular weight
= viscosity, g/cm.s
= constant
Example:
CO2
From BS&L: compute the viscosity of CO2 at
=3.996
MW=44 kg/kmol
/k=190 K
2.6693 10 5 44T
3.996
1.109 10 5 T
Finding and
122/76
Gas
Mixtures
For mixtures,
mix
i 1
x
j 1
where
M i
1
ij
1
M j
8
xi i
12
x = mole fraction
ij
M j
M i
123/76
Liquid
Viscosity
Theory not as well-developed.
Use Eyrings theory: energy to move in fluid
Limits: rough approximation based on
N A h Go / RTK
%e
V
NA = Avogadros number
h = Plancks constant
R = molar gas constant
Go = molar free energy
of activation
V = molar volume
124/76
Simplified
form
The energy to move in the liquid (bond
N A h 3.8Tbp /TK
%e
V
see textbook example, 1.5-1
125/76
Use of model
Eyrings model is not accurate (approx 30%).
But it shows the effect of T on viscosity of a
liquid.
Does liquid viscosity increase or decrease
with T?
Who was Arrhenius?
Can this model be used with non-Newtonian
materials?
126/76
Density
Density decrease with T (liquids and gases).
Prediction equation, liquids:
vap T
vap 15.6o C
Tc T
Tc 288.70
4.00
3.45
Organics
3.23
Inorganics
3.03
127/76