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Robin Smith
Law):
Where
Here, sign(r) = 1 if r > 0
and
sign(r) = 1 if r < 0.
Example 4.1
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vapor-phase fugacity
coefficient, V
Moderate pressure, V
=1
Raoults law
If liquid ideal , = 1;
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gases
noncondensable
approximated by
Henrys Law
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b. NRTL equation
gij and gji are the energies of interactions between Molecules i and
j . ij characterizes the tendency of Molecule i and Molecule j to be
distributed in a random fashion, depends on molecular properties
and usually lies in the range 0.2 to 0.5
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c. UNIQUAC
equation
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Lever Rule
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Example 4.3 A mixture of ethane, propane, n-butane, npentane and n-hexane is given in the Table 4.3. For this
calculation, it can be assumed that the K-values are ideal. For
the mixture in Table 4.3, an equation of state method might
have been a more appropriate choice. However, this makes the
calculation of the
K-values much more complex. The ideal K-values for the
mixture can be expressed in terms of the Antoine Equation as:
where P is the pressure (bar), T the
absolute temperature (K) and Ai , Bi
and Ci are constants given in the Table
4.3:
a. For a pressure of 5 bar, calculate
the bubble point.
b. For a pressure of 5 bar, calculate
the dew point.
c. Calculate the pressure needed for
total condensation at 313 K.
d. At a pressure of 6 bar and a
temperature of 313 K, how much
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