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Atoms, Molecules, and Ions > History of Atomic Structure

History of Atomic Structure

Early Ideas about Atoms


The Law of Conservation of Mass
The Law of Definite Composition
The Law of Multiple Proportions
John Dalton and Atomic Theory

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Atoms, Molecules, and Ions > History of Atomic Structure

Early Ideas about Atoms


The ancient Greek philosophers Democritus and Leucippus recorded the concept
of the <em>atomos</em>, an indivisible building block of matter, as early as the
5th century BCE.
The idea of an indivisible particle was further elaborated upon and explored by a
number of scientists and philosophers, including Galileo, Newton, Boyle,
Lavoisier, and Dalton.
John Dalton, an English chemist and meteorologist, is credited with the first
modern atomic theory based on his experiments with atmospheric gases.

John Dalton's <em>A New System of Chemical


Philosophy</em>
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Atoms, Molecules, and Ions > History of Atomic Structure

The Law of Conservation of Mass


The law of conservation of mass states that mass in an isolated system is neither
created nor destroyed by chemical reactions or physical transformations.
According to the law of conservation of mass, the mass of the products in a
chemical reaction must equal the mass of the reactants.
The law of conservation of mass is useful for a number of calculations and can
be used to solve for unknown masses, such the amount of gas consumed or
produced during a reaction.

Antoine Lavoisier
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Atoms, Molecules, and Ions > History of Atomic Structure

The Law of Definite Composition


The law of definite composition was proposed by Joseph Proust based on his
observations on the composition of chemical compounds.
Proust proposed that a compound is always composed of the same proportions
of elements by mass.
Though initially controversial, the law of definite composition was supported by
Dalton's atomic theory.

Joseph Proust
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Atoms, Molecules, and Ions > History of Atomic Structure

The Law of Multiple Proportions


The law of multiple proportions is a rule of stoichiometry.
John Dalton formulated the law of multiple proportions as part of his theory that
atoms formed the basic indivisible building block of matter.
The law of multiple proportions says that when elements form compounds, the
proportions of the elements in those chemical compounds can be expressed in
small whole number ratios.
The law of multiple proportions is an extension of the law of definite composition,
which states that compounds will consist of defined ratios of elements.

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iple-proportions-196-4703

Atoms, Molecules, and Ions > History of Atomic Structure

John Dalton and Atomic Theory


Dalton's atomic theory proposed that all matter was composed of atoms,
indivisible and indestructible building blocks.While all atoms of an element were
identical, different elements had atoms of differing size and mass.
Dalton's atomic theory also stated that all compounds were composed of
combinations of these atoms in defined ratios.
Dalton also postulated that chemical reactions resulted in the rearrangement of
the reacting atoms.

John Dalton's<em> A New System of Chemical


Philosophy</em>
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d-atomic-theory-197-6138

Appendix
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Atoms, Molecules, and Ions

Key terms
atom The smallest possible amount of matter that still retains its identity as a chemical element, now known to consist of a
nucleus surrounded by electrons.
atom The smallest possible amount of matter that still retains its identity as a chemical element, now known to consist of a
nucleus surrounded by electrons.
atom The smallest possible amount of matter that still retains its identity as a chemical element, now known to consist of a
nucleus surrounded by electrons.
atomic mass unit The standard unit that is used for indicating mass of an atom.
element Any one of the simplest chemical substances that cannot be decomposed in a chemical reaction or by any chemical
means, and are made up of atoms all having the same number of protons.
law of conservation of mass A law that states that mass cannot be created or destroyed; it is merely rearranged.
law of definite composition A law that states that chemical compounds are formed of constant and defined ratios of elements
as determined by mass.
law of multiple proportions The law stating that reactants will always combine in set whole number ratios.
law of multiple proportions A law stating that if two elements form a compound, then the ratio of the mass of the second
element and the mass of the first element will be small whole number ratios.
product A chemical substance formed as a result of a chemical reaction.
reactant Any of the participants present at the start of a chemical reaction.Also, a molecule before it undergoes a chemical
change.

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Atoms, Molecules, and Ions

Models of the Atom Timeline - YouTube


This video is about the different ways that scientists have pictured the atoms over the years.It starts with Democritus and Leucippus, the first
philosophers to discuss atoms.The video also covers the work of Dalton, Thompson, Rutherford, Niels Bohr, and Schrodinger.

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Atoms, Molecules, and Ions

John Dalton's <em>A New System of Chemical Philosophy</em>


Chemical structures from Dalton's A New System of Chemical Philosophy.

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Wikipedia. "Atomic theory." GNU FDL http://en.wikipedia.org/wiki/Atomic_theory View on Boundless.com

Atoms, Molecules, and Ions

Conservation of Atoms - YouTube


This video explains how atoms are conserved in a chemical reaction.

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Atoms, Molecules, and Ions

Antoine Lavoisier
A portrait of Antoine Lavoisier, the scientist credited with the discovery of the law of conservation of mass.

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Atoms, Molecules, and Ions

John Dalton and the Law of Definite Proportions - YouTube


This video examines the law of definite proportions and the law of multiple proportions.

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Atoms, Molecules, and Ions

Joseph Proust
Portrait of Joseph Proust

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Atoms, Molecules, and Ions

John Dalton's<em> A New System of Chemical Philosophy</em>


This image from Dalton's A New System of Chemical Philosophy, published in 1808, depicts various atoms and molecules.

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Atoms, Molecules, and Ions

All of the following are examples of Dalton's theories of atomic


structure and reactivity EXCEPT:
A) The fundamental structure of atoms can change during chemical
reactions.
B) All atoms of a given element are identical.

C) The atoms of different elements differ in mass and size.

D) Atoms are indestructible.

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Atoms, Molecules, and Ions

All of the following are examples of Dalton's theories of atomic


structure and reactivity EXCEPT:
A) The fundamental structure of atoms can change during chemical
reactions.
B) All atoms of a given element are identical.

C) The atoms of different elements differ in mass and size.

D) Atoms are indestructible.

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Atoms, Molecules, and Ions

Which of the following is the correct definition for the Law of


Conservation of Mass as expressed by Lavoisier in 1789?
A) The mass that is lost during a chemical reaction is a result of phase
changes during the reaction.
B) Despite chemical reactions or physical transformations, mass is
conserved within an isolated system.
C) Mass is conserved during a chemical reaction except when a gas is
produced.
D) Mass is conserved within an isolated system except during chemical
reactions.

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Atoms, Molecules, and Ions

Which of the following is the correct definition for the Law of


Conservation of Mass as expressed by Lavoisier in 1789?
A) The mass that is lost during a chemical reaction is a result of phase
changes during the reaction.
B) Despite chemical reactions or physical transformations, mass is
conserved within an isolated system.
C) Mass is conserved during a chemical reaction except when a gas is
produced.
D) Mass is conserved within an isolated system except during chemical
reactions.

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Atoms, Molecules, and Ions

Which of the following is the correct definition for the Law of


Definite Composition?
A) Elements can mix in any ratio to form chemical compounds.
B) Chemical compounds are formed of constant and defined ratios of
elements, as determined by mass.
C) Atoms always combine in the same constant and defined ratio when
forming compounds.
D) The composition of a compound can always be explicitly defined.

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Atoms, Molecules, and Ions

Which of the following is the correct definition for the Law of


Definite Composition?
A) Elements can mix in any ratio to form chemical compounds.
B) Chemical compounds are formed of constant and defined ratios of
elements, as determined by mass.
C) Atoms always combine in the same constant and defined ratio when
forming compounds.
D) The composition of a compound can always be explicitly defined.

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Atoms, Molecules, and Ions

Which of the following is the correct definition of the law of


multiple proportions?
A) The same compound can be formed by the combination of the same
atoms in multiple different proportions, which can be expressed as a ratio
of two small whole numbers.
B) If two elements can form multiple compounds, the ratios of the masses
of the two elements in those compounds can be expressed as a ratio of
two small whole numbers.
C) The same atoms cannot combine in multiple proportions.
D) In any given reaction, the ratio of the masses of the two reacting
components can always be expressed as a small whole number.

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Atoms, Molecules, and Ions

Which of the following is the correct definition of the law of


multiple proportions?
A) The same compound can be formed by the combination of the same
atoms in multiple different proportions, which can be expressed as a ratio
of two small whole numbers.
B) If two elements can form multiple compounds, the ratios of the masses
of the two elements in those compounds can be expressed as a ratio of
two small whole numbers.
C) The same atoms cannot combine in multiple proportions.
D) In any given reaction, the ratio of the masses of the two reacting
components can always be expressed as a small whole number.

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Atoms, Molecules, and Ions

All of the following are main points of Dalton's Atomic Theory


EXCEPT:
A) Equal mass quantities of two different compounds should have the
same number of atoms.
B) All atoms of an element are identical.

C) The atoms of different elements differ in size and mass.


D) Compound are produced through different whole-number
combinations of atoms.

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Atoms, Molecules, and Ions

All of the following are main points of Dalton's Atomic Theory


EXCEPT:
A) Equal mass quantities of two different compounds should have the
same number of atoms.
B) All atoms of an element are identical.

C) The atoms of different elements differ in size and mass.


D) Compound are produced through different whole-number
combinations of atoms.

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Atoms, Molecules, and Ions

Attribution
Wikipedia. "Atomic theory." CC BY-SA 3.0 http://en.wikipedia.org/wiki/Atomic_theory
Wiktionary. "atom." CC BY-SA 3.0 http://en.wiktionary.org/wiki/atom
Wikipedia. "Conservation of mass." CC BY-SA 3.0 http://en.wikipedia.org/wiki/Conservation_of_mass
Wiktionary. "product." CC BY-SA 3.0 http://en.wiktionary.org/wiki/product
Wiktionary. "reactant." CC BY-SA 3.0 http://en.wiktionary.org/wiki/reactant
Wikipedia. "Law of definite proportions." CC BY-SA 3.0 http://en.wikipedia.org/wiki/Law_of_definite_proportions
Wiktionary. "ratio." CC BY-SA 3.0 http://en.wiktionary.org/wiki/ratio
Wiktionary. "carbonate." CC BY-SA 3.0 http://en.wiktionary.org/wiki/carbonate
Wiktionary. "element." CC BY-SA 3.0 http://en.wiktionary.org/wiki/element
Wikipedia. "Law of multiple proportions." CC BY-SA 3.0 http://en.wikipedia.org/wiki/Law_of_multiple_proportions
Wikipedia. "Coulomb's law." CC BY-SA 3.0 http://en.wikipedia.org/wiki/Coulomb%2527s_law
Boundless Learning. "Boundless." CC BY-SA 3.0 http://www.boundless.com//chemistry/definition/law-of-multiple-proportions
Wiktionary. "atom." CC BY-SA 3.0 http://en.wiktionary.org/wiki/atom
Wikipedia. "Atomic theory." CC BY-SA 3.0 http://en.wikipedia.org/wiki/Atomic_theory
Wikipedia. "John Dalton." CC BY-SA 3.0 http://en.wikipedia.org/wiki/John_Dalton
Boundless Learning. "Boundless." CC BY-SA 3.0 http://www.boundless.com//chemistry/definition/atomic-mass-unit
Wiktionary. "atom." CC BY-SA 3.0 http://en.wiktionary.org/wiki/atom

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