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Chapter Overview
Learning Objectives
1. To introduce the basic properties of chemical
engineering thermodynamics
2. To introduce the concepts of equilibrium
Learning Outcomes
Students will be able to:
1. Define the basic terminology of thermodynamics, such
as internal energy, potential energy, kinetic energy,
system, and phase
2. Understand the general concepts of equilibrium, which
is very important in the application of thermodynamics
in chemical engineering
Introduction
Internal energy The energy of a substance associated
with the motions, interactions, and bonding of its
constituent molecules
External energy Associated with the velocity and
location of its centre of mass, which is of primary interest
in mechanics
System The region under study, which may be a
specified volume in space or a quantity of matter
Surrounding The rest of the universe
Phase The state of agglomeration of the system, that
is whether it is a gas, liquid, or solid
Introduction contd
Adiabatic system A well-insulated system in which there are no
heat flows in or out.
Closed system A system in which there are no mass flows in or
out.
Isolated system A system that is closed to the flow of mass and
energy in the form of work flows and heat flows (i.e. is
adiabatic)
Open/Steady-flow system A system in which flows of mass,
heat, and work may be present but in such a way the system
properties do not change over time
Cyclic process A process that follows a periodic path so that
the system has the same properties at any point in the cycle
as it did at that point in any preceding or succeding cycle
Last Updated: 9/8/15
A System of Units
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Figure 1.3-1 Blocks in states (a) and (b) are stable to small mechanical
disturbances; the delicately balanced block in state (c) is not
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Equations of State
^
P P(T, V)
^
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References
S.I. Sandler (2006). Chemical, Biochemical, and
Engineering Thermodynamics. John Wiley.
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