Professional Documents
Culture Documents
Fertilizer Co.Ltd
( Aniline-TDI complex)
WEST
GATE
Water Cooling Control AN Aniline
sump Tower room substation Plant
Tech. Sub ETP
Building station
PFB
Canteen Utility TDI MTD DNT
Plant pump/Bunker
CPP PHOSGENE NB SAC
Plant unit
Pond
Incinerator
Flare OHC Chlorine Chlorine Acid &
stack Scrubber tonner DNT Aniline
and plant T/F
Fire Bullet CO
station TDI, HCL Tank farm
N
MAIN
LAY OUT PLAN OF GNFC GATE NH No. 8
(Ani-TDI complex)
Aniline Plant
Conc. Nitric
Benzene Acid Hydrogen
Conc. Nitro
Aniline
Sulphuric Acid Benzene Purification
Reactor
Plant
CO Evaporator
CO From A.A Cl2
SA
OTD Crude TDI TDI
Aniline
By Products formation : Tar
Reaction Chemistry
(1) Nitration of Toluene to Di- Nitro toluene
H2SO4
C6H5 CH3 +2 HNO3 C6H3-CH3-(NO2) 2 +2H20+Heat
DNT
(2) Hydrogenation of Di Nitro toluene to Meta Toluene Di Amine (MTD)
Catalyst PdCl2
C6H3-CH3-(NO2) 2 + 6H2 C6H3-CH3-(NH2)2+ 4H20 + Heat
MTD
(3) Phosgene Gas Synthesis
CO + CL2 COCL2
Phosgene
(4) Phosgenation of (MTD) to Toluene Di Isocyanate (TDI)