that forms a layer about 800 – 1000 km around planet earth, it divided into four layers: Troposphere Stratosphere Mesosphere Thermosphere The Properties of Air Pollutants The major air pollutants are those produced in significant amounts and those having documented health or other environmental effects. Oxides of Sulfur – Oxides of Nitrogen – Gaseous Hydrocarbons and Other Volatile Organic Compounds – Carbon Monoxide – Carbon Dioxide – Photochemical Oxidants (Ozone) – Particulate Matter – Metals – Radioisotopes – Other Air Pollutants – Air Toxics. Oxides of Sulfur A number of oxides of sulfur have deleterious environmental effects. The most notable is sulfur dioxide (SO2). Coal-burning electrical power plants are blamed for producing most of the sulfur dioxide problem in USA. High fuel sulfur contents 5% & low fuel sulfur contents less than 1% Natural gas contains only trace amounts of sulfur. (switching from coal to natural gas. Continue
Sulfur dioxide is itself a poison, but it can
also react with other substances in the atmosphere to form Sulfuric acid – it is able to corrode limestone, metal, and clothing, and it has a devastating effect on delicate respiratory tissue. Sulfuric acid derived from sulfur- containing air pollutants is a major contributor to the acidity in acid rain. Oxides of Nitrogen
When air is fed into a combustion
mixture, particularly when combustion is occurring at a temperature above 2000 F°, the oxygen and nitrogen present in the air combine to form nitric oxide (NO) Nitric oxide is not thought to be very harmful and does not do much damage because it cannot readily dissolve in water or in tissue. Continue Through the action of sunlight, nitric oxide can combine with oxygen to form nitrogen dioxide, which is a reddish brown toxic gas that has considerable environmental impact. Nitrogen dioxide can form nitric acid which can do much harm to materials and to health and it is implicated in the formation of acid fogs (California). Nitrogen dioxide is produced in the combustion of coal, oil, natural gas, and motor vehicle fuel and wherever temperature are high enough to cause atmospheric nitrogen and oxygen to combine. Volatile Organic Compounds Some hydrocarbons-for instance, certain polycyclic hydrocarbons may have considerable direct effect on humans by virtue of chemical carcinogenicity (ability to cause cancer). Volatile organic compounds (VOC’s) which are emitted at the rate of 18 million metric tons per year in the United States, are a problem largely because they participate in the formation of ozone. Carbon Monoxide It comes mainly from the incomplete combustion of fuels – largely in the automobile. Naturally produced carbon monoxide comes mixed with methane and other substances in march gases and other gases emitted from decaying material. Carbon monoxide is the single most abundant pollutant known to affect human health that we vent into the atmosphere. Carbon Dioxide Carbon dioxide is produced in respiration and fermentation as sugars and other foods are oxidized. Relative to the other air pollutants, carbon dioxide is unreactive and is not really considered a pollutant because it has no direct health effects. The relationship between the facts that (1) carbon dioxide has been increasing for some time, at least partly as a result of fossil fuel combustion, (2) the earth does appear to be getting warmer, and (3) even slight warming might upset delicate energy balances, melt polar ice, and cause ocean levels to rise, inundating coastal cities, means that carbon dioxide is an air pollutant in every sense. Photochemical Oxidants (Ozone) Ozone is responsible of the presence of the family of photochemical oxidants that make up photochemical “smog”. This is because ozone may account for as much as 90% of the oxidant chemicals in smog. Nitrogen dioxide is a very efficient absorber of the ultraviolet light that does reach the earth’s surface. As NO2 absorbs such radiation, it is broken down (photolyzed – split by light) into NO and O. In a subsequent reaction, O combines with O2 to form O3 or ozone. Continue
Ozone would break down as quickly as it
is formed by reacting with NO. However, there are apparently two pathways other than one as shown in the above figure. By which NO can revert to NO2: RO2 + NO → NO2 + RO(1) Where R is a hydrocarbon or other organic radical and: 2NO + O2 →NO2(2) Ozone as a Problem
Some people feel the effects of ozone
when it is present at only 0.001 ppm. At 0.05 – 0.1 ppm, some people experience impaired eye muscles coordination and a drop in visual acuity. Pulmonary edema can be produced in human test subjects at less than 1 ppm. Outside Air Pollution Exposure Limits (microgram/cubic meter Substance Maximum Exposure Time of Exposure Level Sulfur Dioxide 350 One hour 150 24 hours 60 One year Carbon Monoxide 30 mg/m3 One hour 10 mg/m3 8 hours
Nitrogen Dioxide 400 One hour
150 24 hours
Ozone 200 One hour
120 8 hours Air Pollution Control There are obviously a number of very fundamental technological and non- technological approaches to the control of air pollution, all of which are being used to some degree. These might be enumerated as follows: Alternatives – Reduction – Remove – Keep pollutants from escaping – Remove the pollutants from ambient air – Change the affected receptors. Alternatives
A number of kinds of alternatives could be
used: (a) We could change our lifestyles to require less of the energy that brings pollution with it. (b) we could find alternative ways to achieve our desired lifestyle by finding different technologies that are less pollution, or (c) we could use alternative sources of energy that do not have as much pollution as a by- product. Reduction
We could continue to do the same sorts
of things but less of them. For instance, we could switch to still smaller cars, modify our technology to make cars still more efficient, or make our overall expenditure of energy more efficient by insulating houses. Remove Pollutants Generating Materials Remove pollutant-generating materials from fuels. An example of this kind of technological fix would be to remove sulfur from coal before it is burned. Keep Pollutants from Escaping into the Air Keep pollutants from escaping into the air as fuels are burned. This can be done by putting catalytic converters in automobiles and installing scrubbers. Remove the Pollutant from Ambient Air We include this absurd strategic element for the sake of completeness. It would be more efficient to approach the problem of minimizing air pollution by getting at the offending material before it is scattered throughout the environment. Change The affected Receptors to Protect Them Change the affected receptors to protect them. For example, we could coat status with protective materials, breed resistant plant species, and add lime to lakes. Mechanical Collector Scrubber Electrostatic Precipitator Fabric Filter Incineration of Flammable Emissions Implemented and planned approaches involving the automobile, for example, have included the following: 1. Reduction in size, horsepower, and compression ratios of the internal combustion engine. 2. Improvements in the technology of controlling the emission of pollutants from automobiles. 3. Reduction of the number of automobiles by improving mass transit, encouraging carpooling, restricting downtown parking, and establishing bicycle paths. 4. Periodic inspections of automobiles. 5. Replacement of the gasoline engine with electric or steam engines. Strategies for reducing sulfur dioxide pollution by power plants have included the following: 1. Substituting low-sulfur fuels for high-sulfur fuels. 2. Using smokestacks high enough to poke through inversion layers. 3. Chemically scrubbing sulfur dioxide and other compounds of sulfur from the effluent going up stacks. 4. Removing sulfur from coal and oil and gas before it is burned-in addition to reducing the demand for electric power.