INFLUENCES OF TEMPERATURE ON ION EXCHANGE

PROPERTIES
2019
HYDROMETALLURGY

BY :
ALFIANSYAH DARMAWAN / 20
MUHAMMAD IRFAN / 37
OUTLINE

1 URANIUM 2 ION EXCHANGE

THERMODYNAMIC ASPECT
3 4 KINETIC ASPECT

INFLUENCES OF CONCLUSION
TEMPERATURE ON ION &
5 EXCHANGE 6 REFERENCES
2
 HYDROMETALLURGY

URANIUM ?

3
 HYDROMETALLURGY
URANIUM

Member of the actinide series of elements

Has an atomic number of 92

Has an atomic mass of 238

Melting Point : 1,132° C (2,070° F)

Nuclear Fuels
Weppi.gtk.fi>foregsatlas>text>U.pdf 4
Commercial Uranium Production HYDROMETALLURGY

Uranium 2003: Resources, Production and Demand. A joint report by the OECD Nuclear Energy Agency and the International Atomic Energy
Agency. OECD 2004. 5
 Unit Processes in
Hydrometallurgy ORE HYDROMETALLURGY

ORE PREPARATION

LEACHING

SOLID/LIQUID SEPARATION

OUR FOCUS !
LEACH/LIQUOR

ADSORPTION ON
SOLVENT EXTRACTION ION EXCHANGE
CHARCOAL

C. K. Gupta, T. K. Mukherjee. Hydrometallurgy in Extraction Processes. CRC

Press. 1990. 6
 Unit Processes in
Hydrometallurgy HYDROMETALLURGY

PURIFIED SOLUTION

IONIC REDUCTION WITH ELECTROCHEMICAL ELECTROLYTIC

CRYZTALLIZATION
PRECIPITATION GAS REDUCTION REDUCTION

PURE METAL METAL COMPOUND METAL OR ITS OXIDE IMPURE METAL PURE METAL
COMPOUND

C. K. Gupta, T. K. Mukherjee. Hydrometallurgy in Extraction

Processes. CRC Press. 1990. 7
 Flow Of Ores in
Leaching Practice HYDROMETALLURGY

MINERAL DEPOSIT

LOW GRADE ORES AT MINES (U, Cu)

RECYCLED SOLUTION INSITU LEACHING

LEACH/LIQUOR

SEPARATION

METAL

C. K. Gupta, T. K. Mukherjee. Hydrometallurgy in Extraction

Processes. CRC Press. 1990. 8
 HYDROMETALLURGY

ION EXCHANGE ?
9
 HYDROMETALLURGY

Process in which ions of one

substance are replaced by similarly
charged ions of another substance

ION EXCHANGE

http://www.businessdictionary.com/definition/ion-exchange.html
10
 HYDROMETALLURGY

Why does Uranium have

to go through Ion
Exchange process ?

1 Uranium ores are not easily concentrated by ore-

dressing methods

2 For the low grade ore had to be treated by leaching

Acid & Alkaline leaching may be used, but Acid

Rosenqvist, T. 1983. Principles of Extractive 3
Leaching is most common
Metallurgy. Second Edition. McGraw-Hill
International Book Company : London. 11
 HYDROMETALLURGY

THIS IS AN EXCHANGE REACTION

4R+X- + UO2(SO4)34- ↔ (R+)4UO2(SO4)34- + 4X-

R+ = RESIN CATION

X- = ANION
Rosenqvist, T. 1983. Principles of Extractive Metallurgy. Second Edition. McGraw-
Hill International Book Company : London. 12
13
KINETICS ASPECT

Semnani, F., Asadi, Z., Samadfam, M., & Sepehrian, H. (2012).
Uranium(VI) sorption behavior onto amberlite CG-400 anion
exchange resin: Effects of pH, contact time, temperature and
presence of phosphate. Annals of Nuclear Energy, 48, 21–24.
https://doi.org/10.1016/j.anucene.2012.05.010
Where :
m = mass of adsorbent (g)
V = volume of uranium aqueous
solution contacted with adsorbent (mL)
Ci = initial concentration of uranium (mg L-1)
Cf = equilibrium concentration (mg L-1) of ura-
nium after sorption
14
THERMODYNAMICS ASPECT

Where :
ΔG° = standard free energy
ΔH° = standard enthalpy
ΔS° = standard free entropy
T = Temperature
Semnani, F., Asadi, Z., Samadfam, M., & Sepehrian, H. (2012).
Uranium(VI) sorption behavior onto amberlite CG-400 anion
exchange resin: Effects of pH, contact time, temperature and
presence of phosphate. Annals of Nuclear Energy, 48, 21–24.
https://doi.org/10.1016/j.anucene.2012.05.010
 HYDROMETALLURGY

INFLUENCES OF TEMPERATURE ON ION EXCHANGE PROPERTIES

15
 INFLUENCES OF TEMPERATURE ON ION EXCHANGE HYDROMETALLURGY
PROPERTIES

Semnani, F., Asadi, Z., Samadfam, M., & Sepehrian, H. (2012). Uranium(VI) sorption behavior onto
amberlite CG-400 anion exchange resin: Effects of pH, contact time, temperature and presence
of phosphate. Annals of Nuclear Energy, 48, 21–24.
https://doi.org/10.1016/j.anucene.2012.05.010 16
 HYDROMETALLURGY
ION EXCHANGE
CAPACITY

An increase temperature will be decrease the

sorption capacity of ion exchange.

L. A. Shelkovnikova, O. T. Gavlina, V. A. Ivanov, and V. I. Gorshkov, “The

influence of temperature on the ion exchange properties of
phenolformaldehyde sorbents,” Russ. J. Phys. Chem. A, vol. 83, no. 12, pp.
2122–2126, 2010. 17
 HYDROMETALLURGY
ION EXCHANGE
CAPACITY

An increase temperature will be decrease the

sorption capacity of ion exchange.

A. Matsha, “INFLUENCE OF TEMPERATURE ON THE ION-EXCHANGE

PROPERTIES OF STANNIC ARSENATE,” vol. 5075.
18
 HYDROMETALLURGY
ION EXCHANGE
SWELLING

A decrease in sorption as the temperature

increases is likely related to a decrease in the
swellability of ion exchangers

L. A. Shelkovnikova, O. T. Gavlina, V. A. Ivanov, and V. I. Gorshkov, “The

influence of temperature on the ion exchange properties of
phenolformaldehyde sorbents,” Russ. J. Phys. Chem. A, vol. 83, no. 12, pp.
2122–2126, 2010. 19
 HYDROMETALLURGY
ION EXCHANGE
SELECTIVITY

An increase temperature will

be decrease a selectivity of
ion exchange

L. A. Shelkovnikova, O. T. Gavlina, V. A. Ivanov, and V. I. Gorshkov, “The

influence of temperature on the ion exchange properties of
phenolformaldehyde sorbents,” Russ. J. Phys. Chem. A, vol. 83, no. 12, pp.
2122–2126, 2010. 20
VIDEO

21
 CONCLUSION
The leaching method that we use for Uranium recovery is In Situ Leaching

An increase temperature will be decrease the sorption capacity, swellability and

selectivity of ion exchange.

The reaction is easier at high temperature

23
 REFERENCES
Weppi.gtk.fi>foregsatlas>text>U.pdf

Uranium 2003: Resources, Production and Demand. A joint report by the OECD Nuclear Energy Agency and the International
Atomic Energy Agency. OECD 2004.

Rosenqvist, T. 1983. Principles of Extractive Metallurgy. Second Edition. McGraw-Hill International Book Company : London.

http://www.businessdictionary.com/definition/ion-exchange.html

C. K. Gupta, T. K. Mukherjee. Hydrometallurgy in Extraction Processes. CRC Press. 1990.

L. A. Shelkovnikova, O. T. Gavlina, V. A. Ivanov, and V. I. Gorshkov, “The influence of temperature on the ion exchange
properties of phenolformaldehyde sorbents,” Russ. J. Phys. Chem. A, vol. 83, no. 12, pp. 2122–2126, 2010.
24
 REFERENCES
A. Matsha, “INFLUENCE OF TEMPERATURE ON THE ION-EXCHANGE PROPERTIES OF STANNIC ARSENATE,” vol. 5075.

25
THANK YOU
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