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ANDHRA PRADESH
Name : A.Vinay Kumar
Designation : H.O.D
Branch : Applied Electronics and Instrumentation
Institute : Q.Q.GPT, Hyderabad
Subject : Analytical Instrumentation
Code No : AEI-603
Major Topic : Mass spectroscopy & Chromatography
• Applications
• Detectors
• Advantages
• Disadvantages
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Recap
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Applications
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Applications
approaches
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Applications……
• In inorganic analysis
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Applications……
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Applications……
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Applications……
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Space application
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The Mass Spectrum
Masses are graphed or tabulated according to their
relative abundance.
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Mass Spectrum with Sulfur
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Mass Spectrum with Chlorine
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Mass Spectrum with Bromine
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Mass Spectra of Alkanes
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Molecules with Heteroatom
• Isotopes: present in their usual abundance.
• Hydrocarbons contain 1.1% C-13, so there will be a small
M+1 peak.
• If Br is present, M+2 is equal to M+.
• If Cl is present, M+2 is one-third of M+.
• If iodine is present, peak at 127, large gap.
• If N is present, M+ will be an odd number.
• If S is present, M+2 will be 4% of M+
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Isotopic Abundance
81
Br
=>
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The GC-MS
A mixture of compounds is separated by gas
chromatography, then identified by mass
spectrometry.
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The GC-MS
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Detectors
detector
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Different types of detectors
• Farady cups
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Detector
Continuous dynode particle multiplier detector
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Advantages
• High sensitivity
with result
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Disadvantages
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Summary
• Applications
• Advantages
• Detectors
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Quiz
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Frequently Asked Questions
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