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Postulate 1
Matter is made of particles containing mass. 1 AMU = 1.66054 x 10-24 g
Proton1 AMU (1.0073) Neutron1 AMU (1.0087) ElectronWithout Mass (5.486 x 10-4 AMU)
Postulate 2
Particles of substances are in constant, rapid, and random motion.
Motion has 3 characteristics
Constant Rapid Random
Postulate 3
Collisions are either elastic or inelastic.
1. Inelasticloses energy (p. 421) 2. Elasticdoesnt lose energy (p. 421)
Postulate 4
4. Temperature measures average kinetic energy.
Temp., Temp., Kinetic Energy Kinetic Energy
Quick Question
After testing two unknown substances A and B, you find the boiling temperature for substance A to be 20C. Substance Bs boiling point is 34C. Which substance, A or B, has stronger intermolecular forces? Why?
Postulate 5
5. Particles exert intermolecular forces.
These forces are non-existent in gases. These forces are strong in liquids and solids.
Dispersion Forces (London Dispersion) Dipole-Dipole Forces
Ion-Dipole
Hydrogen Bonding
Postulate 5Dispersion
Dispersion Forces
Shape-induced charge (due to asymmetry) Weakest force Exists on all molecules
Postulate 5Dipole-Dipole
Dipole-Dipole Forces
Permanent dispersion force (Causes asymmetry, which gives rise to partial charges (-, +) Causes some molecules to be polar
Affects solubility
Hydrogen Bonds
Most important biologically (induces protein folding) Assists in solubility Responsible for properties of water Strongest force
Boyles Law
P, P, V V
Charles Law
T, T, V V
Avogadros Law
If V, T, and P are held constant for 2 gases, then they contain an equal number of particles.
Daltons Law
If more than one gas is present, then the sum of the pressures of all the different gasses equals the total pressure. Pt = p1 + p2 + p3 + + pn